RONOCO (ROle of Nighttime chemistry in controlling the Oxidising Capacity of the AtmOsphere)
Lead Research Organisation:
University of Leeds
Department Name: Sch of Chemistry
Abstract
There is now a significant and increasing body of evidence that night time chemistry, driven primarily by the nitrate radical NO3, plays a significant role in governing the composition of the troposphere. Recent findings show that very high concentrations of NO3 are present away from the Earth's surface. In polluted environments, the main sinks are abundant but this is also where its formation may be most rapid and hence the NO3 turnover time is very fast. The importance of this behaviour is not as yet clearly understood, yet it may have a very large impact on atmospheric chemistry and ozone formation, regional transport and transformation of oxidised nitrogen and hence acidification and eutrophication, and may also significantly add to the regional burden of ammonium nitrate particulate, which has increasing climatic importance. To understand and predict these phenomena correctly there is a need to quantify the basic chemical processes controlling NO3 and its removal from the atmosphere; the impact of NO3 chemistry on volatile organic carbon chemistry and as a pathway for radical formation and propagation; its heterogeneous chemistry and its impact on the aerosol burden and composition; its influence on ozone formation on regional and global scales and its mediation of the atmospheric lifecycle of oxidised nitrogen. A consortium project is proposed that addresses these coupled questions using a combined programme of instrument development, airborne measurement, detailed process modelling, and regional and global modelling. The principal deliverables will be: - Enhancements to the instrumental capability of the FAAM aircraft to include measurements of NO3 and N2O5. - Comprehensive measurements of night time radicals, their sources and sinks, and aerosol composition in the boundary layer and free troposphere in a range of conditions. - Quantification of the key processes which control night-time chemical processes. - Assessment of the impacts of night-time chemistry on regional scales. - An assessment of the global impacts of night-time chemistry in the current and future atmospheres.
Organisations
Publications
Aruffo E
(2014)
Aircraft observations of the lower troposphere above a megacity: Alkyl nitrate and ozone chemistry
in Atmospheric Environment
Stone D
(2014)
Radical chemistry at night: comparisons between observed and modelled HO<sub>x</sub>, NO<sub>3</sub> and N<sub>2</sub>O<sub>5</sub> during the RONOCO project
in Atmospheric Chemistry and Physics
Walker H
(2015)
Night-time measurements of HO<sub><i>x</i></sub> during the RONOCO project and analysis of the sources of HO<sub>2</sub>
in Atmospheric Chemistry and Physics
| Description | We measured significant concentrations of HO2 during the nightime aboard the BAe146 during the RONOCO project. These results were interpreted and compared to model calculations in Walker et al., and Stone et al. The ozonlysis of alkenes, and also reactions of the nitrate radical are involved in the production of HO2 radicals. This chemistry is not included routinely in models. More recently (2019) further analysis was done by a collaborator on RONOCO, and a paper submitted to a journal regarding nitrate radical chemistry. |
| Exploitation Route | Organic peroxy radicals (RO2) are important to measure at night, particularly in the polluted boundary layer and residual layer. It is important to realise that NO3 and RO2 chemistry are linked. |
| Sectors | Environment |