Elastic anomalies and anelastic dissipation mechanisms associated with phase transitions in minerals.
Lead Research Organisation:
University of Cambridge
Department Name: Earth Sciences
Abstract
The elastic properties of minerals have long been investigated for their relevance to the seismic properties of the earth. Interest has largely focussed on discontinuities associated with changes in mineral assemblages and these have led to our present understanding of the layered nature of the mantle and core. It has been recognised, however, that almost any change in the structure of a mineral can give rise to changes in elastic constants and that, for structural transitions driven by displacements of atoms, magnetic ordering and electronic effects, changes in elastic constants can give be as much as tens of percent. Substantial improvements in geophysical methods have also allowed attenuation effects to be investigated more systematically, and a number of models of the variation in attenuation with depth have recently been published. The present project will contribute to this new direction by providing fundamental information on the diversity of mechanisms by which attenuation can occur. The specific focus is on elastic and dissipative processes associated with phase transitions in minerals and their synthetic analogues. The objectives of the project are (a) to measure elastic constants and attenuation parameters for selected oxides and silicates in situ at high and low temperatures using Resonant Ultrasound Spectroscopy (RUS), (b) to test the influence of frequency and applied stress on dissipation phenomena, and (c) to develop further the RUS facility in Cambridge for measurements of highly dissipating samples and for iron bearing minerals at high temperatures.
People |
ORCID iD |
Michael Carpenter (Principal Investigator) |
Publications
Manchado J
(2009)
Dielectric, calorimetric and elastic anomalies associated with the first order [Formula: see text] phase transition in (Ca, Sr)TiO(3) perovskites.
in Journal of physics. Condensed matter : an Institute of Physics journal
McKnight RE
(2009)
Elastic anomalies associated with transformation sequences in perovskites: I. Strontium zirconate, SrZrO(3).
in Journal of physics. Condensed matter : an Institute of Physics journal
McKnight RE
(2009)
Elastic anomalies associated with transformation sequences in perovskites: II. The strontium zirconate-titanate Sr(Zr,Ti)O(3) solid solution series.
in Journal of physics. Condensed matter : an Institute of Physics journal
Carpenter MA
(2010)
Elastic relaxations associated with the Pm3m-R3c transition in LaAlO(3): III. Superattenuation of acoustic resonances.
in Journal of physics. Condensed matter : an Institute of Physics journal
Carpenter M
(2010)
Elastic and anelastic relaxations associated with the incommensurate structure of Pr 0.48 Ca 0.52 MnO 3
in Physical Review B
Thomson R
(2010)
Ferroelastic phase transitions and anelastic dissipation in the LaAlO 3 -PrAlO 3 solid solution series
in Physical Review B
Zhang Z
(2010)
Anelastic loss behaviour of mobile microstructures in SrZr 1 - x Ti x O 3 perovskites
in Journal of Physics: Condensed Matter
Carpenter M
(2010)
Pseudoproper ferroelastic softening behaviour and dynamic microstructure of monoclinic PrAlO 3 perovskite
in Phase Transitions
Carpenter MA
(2010)
Elastic relaxations associated with the Pm3m-R3c transition in LaAlO(3): I. Single crystal elastic moduli at room temperature.
in Journal of physics. Condensed matter : an Institute of Physics journal
Carpenter M
(2010)
Elastic anomalies due to structural phase transitions in mechanoluminescent SrAl2O4:Eu
in Journal of Applied Physics
Carpenter MA
(2010)
Elastic relaxations associated with the Pm3m-R3c transition in LaAlO(3): IV. An incipient instability below room temperature.
in Journal of physics. Condensed matter : an Institute of Physics journal
Zhang Z
(2010)
Microstructure dynamics in orthorhombic perovskites
in Physical Review B
Carpenter MA
(2010)
Elastic relaxations associated with the Pm3m-R3c transition in LaAlO(3): II. Mechanisms of static and dynamical softening.
in Journal of physics. Condensed matter : an Institute of Physics journal
Jones S
(2011)
Phase diagram and phase transitions in ferroelectric tris -sarcosine calcium chloride and its brominated isomorphs
in Physical Review B
Farnsworth S
(2011)
Elastic softening and polarization memory in PZN-PT relaxor ferroelectrics
in Physical Review B
Salje EK
(2011)
Thermally activated proton hopping in lawsonite, the ferroelectric transition at 125 K, and the co-elastic phase transition at 270 K.
in Journal of physics. Condensed matter : an Institute of Physics journal
Carpenter M
(2011)
Anelasticity maps for acoustic dissipation associated with phase transitions in minerals Anelasticity maps for acoustic dissipation
in Geophysical Journal International
Zhang Z
(2011)
Strain coupling mechanisms and elastic relaxation associated with spin state transitions in LaCoO 3
in Journal of Physics: Condensed Matter
Scott JF
(2011)
Elastic and anelastic properties of ferroelectric SrTi(18)O3 in the kHz-MHz regime.
in Physical review letters
Carpenter MA
(2012)
Elastic and anelastic relaxations in the relaxor ferroelectric Pb(Mg1/3Nb2/3)O3: II. Strain-order parameter coupling and dynamic softening mechanisms.
in Journal of physics. Condensed matter : an Institute of Physics journal
Carpenter M
(2012)
Magnetoelastic coupling and multiferroic ferroelastic/magnetic phase transitions in the perovskite KMnF 3
in Physical Review B
Salje E
(2012)
Local Symmetry Breaking in the Bulk and in Domain Boundaries: Breit-Wigner Damping of Phonons and Acoustic Resonances
in Ferroelectrics
Scott JF
(2012)
Domain wall damping and elastic softening in SrTiO3: evidence for polar twin walls.
in Physical review letters
Zhang Z
(2012)
Variations in elastic and anelastic properties of Co3O4 due to magnetic and spin-state transitions
in American Mineralogist
Zhang Z
(2012)
Elastic and anelastic anomalies due to spin-state transitions in orthorhombic perovskite from isoelectronic behavior of Co3+ and Fe2+
in American Mineralogist
Zhang Z
(2012)
Acoustic attenuation due to transformation twins in CaCl2: Analogue behaviour for stishovite
in Physics of the Earth and Planetary Interiors
Carpenter MA
(2012)
A linear-quadratic order parameter coupling model for magnetoelastic phase transitions in Fe(1-x)O and MnO.
in Journal of physics. Condensed matter : an Institute of Physics journal
Zhang Z
(2012)
Elastic and anelastic anomalies associated with the antiferromagnetic ordering transition in wüstite, FexO.
in Journal of physics. Condensed matter : an Institute of Physics journal
Thomson R
(2012)
Elastic relaxation behavior, magnetoelastic coupling, and order-disorder processes in multiferroic metal-organic frameworks
in Physical Review B
Schiemer J
(2012)
Temperature-dependent electrical, elastic and magnetic properties of sol-gel synthesized Bi(0.9)Ln(0.1)FeO3 (Ln = Nd, Sm).
in Journal of physics. Condensed matter : an Institute of Physics journal
Oravova L
(2013)
Elastic and anelastic relaxations accompanying magnetic ordering and spin-flop transitions in hematite, Fe2O3.
in Journal of physics. Condensed matter : an Institute of Physics journal
Nataf G
(2013)
Ferroelastic aspects of relaxor ferroelectric behaviour in Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 perovskite
in Journal of Applied Physics
Aktas O
(2013)
Ferroelectric precursor behavior in PbSc 0.5 Ta 0.5 O 3 detected by field-induced resonant piezoelectric spectroscopy
in Physical Review B
Schiemer J
(2013)
Strain coupling in multiferroic phase transitions of samarium yttrium manganite Sm 0.6 Y 0.4 MnO 3
in Physical Review B
Aktas O
(2013)
Resonant ultrasonic spectroscopy and resonant piezoelectric spectroscopy in ferroelastic lead phosphate, Pb3(PO4)2.
in Journal of physics. Condensed matter : an Institute of Physics journal
Li W
(2013)
Ferroelasticity in a metal-organic framework perovskite; towards a new class of multiferroics
in Acta Materialia
Aktas O
(2013)
Polar precursor ordering in BaTiO3 detected by resonant piezoelectric spectroscopy
in Applied Physics Letters
Perks NJ
(2014)
Strain relaxation mechanisms of elastic softening and twin wall freezing associated with structural phase transitions in (Ca,Sr)TiO3 perovskites.
in Journal of physics. Condensed matter : an Institute of Physics journal
Thomson RI
(2014)
CoF2: a model system for magnetoelastic coupling and elastic softening mechanisms associated with paramagnetic ? antiferromagnetic phase transitions.
in Journal of physics. Condensed matter : an Institute of Physics journal
Aktas O
(2014)
Polar correlations and defect-induced ferroelectricity in cryogenic KTaO 3
in Physical Review B
Spalek L
(2014)
Elastic and anelastic relaxations associated with phase transitions in EuTiO 3
in Physical Review B
Thomson RI
(2014)
Elastic anomalies associated with structural and magnetic phase transitions in single crystal hexagonal YMnO3.
in Journal of physics. Condensed matter : an Institute of Physics journal
Driver SL
(2014)
Multiferroic (ferroelastic/ferromagnetic/ferrimagnetic) aspects of phase transitions in RCo2 Laves phases.
in Journal of physics. Condensed matter : an Institute of Physics journal
Aktas O
(2015)
Elastic softening of leucite and the lack of polar domain boundaries
in American Mineralogist
Carpenter MA
(2015)
Static and dynamic strain coupling behaviour of ferroic and multiferroic perovskites from resonant ultrasound spectroscopy.
in Journal of physics. Condensed matter : an Institute of Physics journal
Ketov SV
(2015)
Rejuvenation of metallic glasses by non-affine thermal strain.
in Nature
Driver S
(2016)
On the effect of hydrogen on the elastic moduli and acoustic loss behaviour of Ti-6Al-4V
in Philosophical Magazine
Description | We developed a method for analysing elastic and anelastic properties of crystalline materials in order to understand the effects that changes in crystal structure or magnetic structure can have on their physical properties. In particular, any change in structure results in a change in the elastic properties and these can influence the velocity of seismic waves in the earth. In particular, we have demonstrated that minerals which might occur in the earth's lower mantle (such as CaSiO3 perovskite) or the earth's crust (such as stishovite and quartz) can cause significant changes in seismic velocities and attenuation. These changes would be signatures for the pressure/temperature conditions at depth. The principles involved in the understanding of effects which depend ultimately on strain apply equally to materials with complex structures and properties that might be used in device applications. |
Exploitation Route | We publish our results in leading Earth Sciences and Physics journals for easy access by scientists and non-academic users. |
Sectors | Electronics |
Description | Research carried out under the auspices led to the development of improvement of research infrastructure in the UK (Resonant Ultrasound Spectroscopy), 8 papers in leading journals relating to the elastic properties of minerals, and a substantial advance in our understanding of how elastic properties of materials, more generally, are highly sensitive to structural and magnetic changes. The layered structure of the earth is understood largely from studies of seismic velocities which, in turn, depend on the elastic properties of minerals. Most significant are discontinuities and the present work has added another class of effects, namely structural phase transitions, which can give rise to these. At the same time, ferroelastic transitions can cause substantial changes in attenuation and, at present, the geophysical analysis and interpretation of these holds promise for providing new insights into the variations of temperature and composition. The science involved in understanding elastic effects of this type applies equally to technological materials which are used in devices, such as for memories and switching. |
First Year Of Impact | 2010 |
Sector | Cultural |
Description | Elasticity of ferroic and multiferroic materials: a UK facility for Resonant Ultrasound Spectroscopy with applied magnetic field up to 14 Teslas |
Amount | £653,681 (GBP) |
Funding ID | EP/I036079/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 10/2011 |
End | 12/2015 |
Description | Research Project Grant |
Amount | £219,851 (GBP) |
Funding ID | RPG-2016-298 |
Organisation | The Leverhulme Trust |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start | 06/2017 |
End | 05/2021 |
Description | Anelasticity of minerals and ferroic materials |
Organisation | University of Vienna |
Country | Austria |
Sector | Academic/University |
PI Contribution | This collaboration with Prof Schranz in the Dept. of Physics in Vienna was a key part of the NERC funded project, and will continue into the future. |
Start Year | 2000 |