Electron and energy transfer in two-dimensional covalent organic frameworks

Lead Research Organisation: UNIVERSITY COLLEGE LONDON
Department Name: Chemistry

Abstract

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Publications

10 25 50

Studentship Projects

Project Reference Relationship Related To Start End Student Name
EP/N509577/1 30/09/2016 24/03/2022
1785167 Studentship EP/N509577/1 30/09/2016 29/09/2019 Caroline Nowicka-Dylag
 
Description I have been working on improvements in the synthesis of covalent organic frameworks (COFs), which have shown interesting photophysical properties. In improving the reaction process, I have been able to study the photophysical properties of the thin film COFs I have made. The photophysical properties of the COFs have been compared to the porphyrins from which they have been made and distinct differences in their absorbances have been seen. Work is still being carried out to determine which photophysical processes have changed. More interestingly, I am going on to compare different porphyrins (i.e. changing metal centres) and also go on to compare these metallated COFs.
Exploitation Route The COF films I have made and investigated can vary dramatically due to the synthesis process, the thickness of the film, the precursors etc... so I have only looked into certain parameters. Ideally, in the future, thinner films can be investigated to determine how the different morphology changes the photophysical properties.
Depending on the photophysical properties, these films can have an interesting effect on solar cell development.
Sectors Chemicals

Energy