Predictive formulation of high solids content suspensions through understanding the statistics of flow-induced jamming

Lead Research Organisation: University of Strathclyde
Department Name: Chemical and Process Engineering

Abstract

When suspensions of solid particles in a fluid are transported at high particle concentration major problems often occur, such as catastrophic thickening or 'jamming' and highly erratic and apparently uncontrollable flow. In industries ranging from ceramics and paint manufacture to drilling muds in oil extraction, these problems mean unreliable product quality and unpredictable process failure. Recent work has shown that despite this apparent unpredictability, such erratic jamming flows do follow meaningful statistical 'rules' which could be used to design better processes and formulate better products. Improved understanding of the statistics of jamming is thus the focus of this PhD project, using novel experimental apparatus and theoretical analysis. The candidate will explore the fundamentals of how erratic flow and stress-driven transient jamming occur in high solids content particulate suspension flow, and thus how to develop engineering methods to improve flow reliability. The project will impact a very wide range of fields and processes, including powder flows and slurries in chemical processes, formulation and manufacture of particle-based products such as foods and ceramics, the stability of soils and sediments in geology, and even the flow of blood cells in arteries and pedestrians in crowded environments. Such systems present many common puzzles and challenges, such as jamming followed by catastrophic collapse (e.g., earthquakes, eruptions, landslides), erratic fluctuations (e.g., blood clots and strokes) and pattern formation (e.g., stratified sediments, segregation in powders). The project thus crosses many engineering and manufacturing sectors and academic disciplines.
The research will determine when 'solid' particle configurations appear, how this depends on flow geometry, on formulation (concentration, flow rate, particle interactions, fluid viscosity/viscoelasticity, etc) and how we can develop statistical analyses to interpret apparently unpredictable fluctuations and develop reliable predictive control methods and strategies.

Experiment: Using suspensions with controllable particle and fluid properties, statistical data on local stress fluctuations will be obtained via novel shear and pipe flow cells, varying particle interactions, size distributions, etc. Stress data will be linked to structural fluctuations through optical microscopy using high speed video.

Analysis: A key advance will be to analyse the statistics of the measured stress fluctuations to arrive at predictive methods based on jamming probabilities, which will allow optimisation of flow control, product formulation and process reliability for given processes and products.

Underlying fundamentals: The analysis will also allow us to draw analogies with related systems and phenomena such as earthquake magnitude distributions and pedestrian crowd safety design (for example how to design buildings to minimise probability of jamming during evacuations). Results already obtained show clear similarities, but also significant differences, across these different jamming scenarios, and this project promises a significant advance in our wider fundamental understanding of the role of fluctuations in 'crowded' interacting systems.

Engineering and design: Informed by the experimental and analysis results, we will go on to investigate how to manipulate geometry and product formulation, to reliably control jamming-prone flows in shear and channel flows, leading to novel ideas for design of such flows in applications.
Results will both maximise our understanding of the fundamentals, vital for future innovative engineering, and help identify potential strategies to improve efficiency and controllability of real processes involving suspensions.

Publications

10 25 50

Studentship Projects

Project Reference Relationship Related To Start End Student Name
EP/N509760/1 01/10/2016 30/09/2021
1859217 Studentship EP/N509760/1 01/02/2017 31/10/2020 Aditi Mukhopadhyay
 
Description The project thus far has allowed the generation of concrete data in order to justify the change in the physical surface environment, under which a shear thickening system resides in, actually has an overall effect on the (shear thickening) behaviour of a suspension. Through rheology (the study of flow and deformation of materials) and the implementation of rheological techniques, the influence of the surface boundary on a system has been shown to affect the onset critical stress at which shear thickening is observed. Through comparisons with rheological data performed without an adhered surface, preliminary results convey an evident shift in the onset stress.

Highlighting this shift in stress allows for the investigation of how to tackle the reduction of shear thickening and allowing for a decrease in handling such issues. Further studies are underway to identify this phenomenon through the use of other materials.

The project involves the use of a TA DHR-2 rheometer, which is one of the most reputable models on the market. Different surface materials (such as parafilm & neoprene foam) are adhered on to the geometry plates of the rheometer. As of yet, this is a new research method as there is an absence in literature regarding the physical surface boundary effects on shear thickening systems, as well as no methods by which this can be carried out. This novel approach also tests to identify whether the placement of a physical random object can be used with such high-tech equipment, and how the system reacts to a new environment and technically, a foreign object.

The next section in this project is the identification of fluctuations and possible occurrences of jamming within a system through the use of a syringe pump. The syringe pump is automated and retrofitted to ensure the operation is smoother and the device is more controllable (controllable in the sense that the data generated provides detailed real time information as the pump is in use. The pump has been electronically and mechanically modified from scratch by a fellow research group member. The purpose of this machine is to identify fluctuations in flow using samples of varying concentrations of cornstarch in solutions glycerol and water, in a syringe, which is inserted into the machine. The piston pushes the syringe plunger and move along the syringe at a desired flowrate, or in the presence of a jam, will/may stall. This enables the mimicking of the flow in a pipe containing varied concentrations, and based on the flowrate and concentration used, and the programming of the machine, the data will be generated according to this. The data could be processed and analyse such that it can mimic the act of a rheometer based on the output.

Via this project, there is integration of knowledge and laboratory resources between the chemical engineering and mechanical engineering departments. Through the work that has been carried out, the funding recipient was approached to test suspension materials of similar nature, carrying the theme of shear thickening, jamming and high particle concentration materials. Though, these tests were not successful (very early on, at the beginning of the test), the fact that the recipient was approached for this, shows that the project has helped gain knowledge and techniques that the recipient is capable and competent enough to be approached by academics. The syringe pump allows the additional electrical aspect to be explored. The syringe pump is connected to an arduino/raspberry pi computer and thus, needs to be wired for to use and control.

As well as this, the effect on the concentration/volume fraction/mass fraction on the shear thickening behaviour is also being analysed. These are the main parameters through which the surface influence is being tested through.

The project has allowed the funding recipient to attend conferences & workshops to allow for further enhancement and understanding of the project and the theme of shear thickening. A rheology workshop delivered by reputable company, Anton Paar, was attended; this helped pin down basic knowledge, become familiarised with a different brand of rheometer (compared to what the recipient is currently using) and learn new avenues and techniques that can be applied to the current project (e.g. oscillatory experiments). As well as this, networking and creating contacts were come of the highlights from this event, with possible use of a company's equipment being available to use. Attending conferences such as those held by the British Society of Rheology and UK Fluids Network, allowed research to be showcased and gain input and opinions on the recipients work from other researchers & professionals, some of which, will be implemented in the very near future.
Exploitation Route As previously mentioned, the purpose of this project is to determine the influence of modifying the surface on the shear thickening behaviour. The reason for this is particularly relevant for the useful observation to aid in the reduction of the phenomena, jamming. Jamming causes the hinderance of processes and may result in inadequate product quality, and thus, tackling this is of utmost importance. Jamming can represent a blockage, and through analysing the conditions under which jamming occurs in, can help to reduce the probability of it occurring. Understanding jamming with reference to pipes is useful, as the smooth environment may promote a smoother flow of materials, whereas, the rough pipes may portray different behaviour. The smooth behaviour is being analysed currently, however, the true nature of the behaviour, with respect to rough surface, has not been identified as of yet, however, is a potential experimental plan. The project involves the in-depth analysis of shear thickening & jamming, thus, will also be relevant to sectors such as foods, transports, and slurries. The data cultivated throughout the project will help provide a concrete reference point. The syringe pump will also bring about the practical view of a process, and it will be easy to witness jamming through this.
Sectors Agriculture, Food and Drink,Chemicals,Construction,Healthcare,Manufacturing, including Industrial Biotechology,Pharmaceuticals and Medical Biotechnology

 
Description The theme of the project (shear thickening & jamming) has contributed to the Chemical Engineering department at the University of Strathclyde's outreach group, as an activity for the successful Young Chemical Ambassador Programme, which has been funded by councils such as the Royal Academy of Engineering & the Royal Society of Chemistry. The programme is designed for 3rd year students to act as ambassadors of their science class and carry out a project, with a presentation to deliver at the end of this project. Within the first year of the award, the recipient was given the opportunity to submit an outreach project idea based on their research. This project looked at jamming and how "sludgy clay" effects the flow in an extruder. The extruder is essentially mimicking a pipe and creating varying concentrations of cornstarch in water/PVA, the ambassadors will be able to understand what causes jamming and try to solve the problems associated with it. As well as this, a primary school activity was created by the recipient, to highlight how jamming occurs. This involves pupils trying to pass through 2 cones placed on the floor of a certain distance apart, and gradually reducing that distance to create a narrow opening, leading to a build-up of pupils. This build up represents the build-up if particles within a suspension, and thus, causes jamming.
First Year Of Impact 2017
Impact Types Cultural,Societal

 
Description "Sludgy Clay" Activity for the Young Chemical Ambassador Programme 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact The theme of the project (shear thickening & jamming) has contributed to the Chemical Engineering department at the University of Strathclyde's outreach group, as an activity for the successful Young Chemical Ambassador Programme, which has been funded by councils such as the Royal Academy of Engineering & the Royal Society of Chemistry. The programme is designed for 3rd year students to act as ambassadors of their science class and carry out a project, with a presentation to deliver at the end of this project. Within the first year of the award, the recipient was given the opportunity to submit an outreach project idea based on their research. This project looked at jamming and how "sludgy clay" effects the flow in an extruder. The extruder is essentially mimicking a pipe and creating varying concentrations of cornstarch in water/PVA, the ambassadors will be able to understand what causes jamming and try to solve the problems associated with it. As well as this, a primary school activity was created by the recipient, to highlight how jamming occurs. This involves pupils trying to pass through 2 cones placed on the floor of a certain distance apart, and gradually reducing that distance to create a narrow opening, leading to a build-up of pupils. This build up represents the build-up if particles within a suspension, and thus, causes jamming.
Year(s) Of Engagement Activity 2017,2018,2019,2020
URL https://www.strath.ac.uk/engineering/chemicalprocessengineering/outreach/youngchemicalambassadorprog...