Cascade Conversion of Biomass Platform Chemicals with Multifunctional Zeolitic Materials
Lead Research Organisation:
Durham University
Department Name: Chemistry
Abstract
The aim of the project is to develop well defined, multifunctional, zeolitic materials bearing Bronsted acid, Lewis acid and basic sites that are able to effect cascade reactions of biomass platform molecules. Elucidating how the nature and location of the differing catalytic components affects the overall catalytic function will provide structure function models for future catalyst design. The location of the disparate catalytic functionalities will be controlled via rationalised synthetic approaches such as organometallic grafting. The multistep conversion of selected bio-derived platform molecules, such as ethanol and acetic acid, will be explored using both batch and flow reactors.
Organisations
People |
ORCID iD |
Russell Taylor (Primary Supervisor) | |
Samuel Raynes (Student) |
Studentship Projects
Project Reference | Relationship | Related To | Start | End | Student Name |
---|---|---|---|---|---|
EP/N509462/1 | 01/10/2016 | 30/09/2021 | |||
1917892 | Studentship | EP/N509462/1 | 01/10/2017 | 30/04/2021 | Samuel Raynes |
Description | The reporting of zinc oxide supported on mordenite as a efficient catalyst for the dehydrogenation of ethanol to acetaldehyde. A versatile synthesis procedure for creating metal substituted zeolite materials. Knowledge of optimum metal species to be introduced into zeolite materials for ethanol conversion in flow conditions. Several multifunctional zeolite materials able to affect the cascade transformation of ethanol to butadiene. |
Exploitation Route | Developed zeolite synthesis and modification methods may find use in industrial catalyst preparation. Zinc oxide supported on mordenite may be used as part of a catalyst composite if ethanol dehydrogenation to acetaldehyde is required. |
Sectors | Chemicals |
Description | Presentation at UKCC 2020 |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Other audiences |
Results and Impact | Presented research findings at a national catalysis conference (UKCC 2020) Discussion following presentation led to research work being undertaken at a national research facility (diamond light source) |
Year(s) Of Engagement Activity | 2020 |