Gelled Electrolyte Thermoelectrochemistry: An Investigation Into Waste Human Body Heat Harvesting

Lead Research Organisation: King's College London
Department Name: Chemistry

Abstract

The question:
Can human body heat energy be harvested and scaled up to possibly generate large quantities of green energy sustainably?

The method / outline:
To investigate gelled electrolyte thermoelectrochemistry, firstly, optimising the gels for best performance for our needs, and then investigating new redox pairs for heat energy harvesting around the temperature difference between the human body and the environment (around 20 degrees). This will allow us to generate electricity from the range at which human body heat is different to the temperature of the outside environment using the seebeck effect (Se = dV/dT). This effect has been known for a long time in thermoelectrics, but due to expensive and rare metals has been only used in select applications, whereas the possibility of using redox pairs to harvest this difference in temperature could potentially generate orders of magnitude more volts per kelvin than thermoelectrics. This idea has been looked at non-extensively already in liquid and ionic liquid media, but gelled electrolytes have scarcely been examined as yet and some of the literature has many problems, so this investigation undertaken is of importance and value to green energy harvesting if done properly. As using redox pairs to generate electricity is a relatively new area of green energy generation, our plan is to use iron-based redox pairs as iron is an earth-abundant metal. We have the potential using this 4 year Ph.D. to make a meaningful contribution to this field.

Publications

10 25 50

Studentship Projects

Project Reference Relationship Related To Start End Student Name
EP/N509498/1 01/10/2016 30/09/2021
1949888 Studentship EP/N509498/1 01/10/2017 30/09/2021 Mark Buckingham
 
Description We have led very detailed fundamental studies of Iron salts dissolved in water for their usage to convert thermal to electrical energy. Our main findings so far have been regarding the enhancement of both the thermodynamic and kinetic aspects of this energy conversion. And the limitations of conversion, we have published three papers (in collaboration with other members of the research group) thus far and our fundamental research will produce further publishable results.
Exploitation Route Low-temperature thermal energy could be harvested to power low-power consuming electronics (such as medical devices), this research could also be used more generally in harvesting various sources of thermal energy (from vehicles, human body heat, industry etc.)
Sectors Energy,Pharmaceuticals and Medical Biotechnology

URL https://pubs.rsc.org/en/content/articlelanding/2018/SE/C8SE00416A#!divAbstract