The development of salen-based artificial metalloenzymes for sustainable chemistry

Lead Research Organisation: University of Edinburgh
Department Name: Sch of Chemistry

Abstract

Artificial metalloenzymes (ArMs) combine transition metal reactivity with the selectivity of enzymes to introduce new catalytic reactions into the biocatalytic toolbox.1 A classic group of transition metal catalysts are the salen and salophen-type complexes that exhibit catalytic activity for a range of synthetic reactions, including epoxidation, C-H bond oxidation and amination, small molecule activation such as water splitting, and polymerisation reactions for green plastics.

Publications

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Studentship Projects

Project Reference Relationship Related To Start End Student Name
BB/T00875X/1 01/10/2020 30/09/2028
2879480 Studentship BB/T00875X/1 01/10/2023 30/09/2027