PRINTEG - Advanced manufacturing for low-cost Thermo-electric device fabrication

Lead Research Organisation: Queen Mary University of London
Department Name: School of Engineering & Materials Scienc

Abstract

For an automotive combustion engine only 35% of the energy produced is harnessed for motive power, with 65% of the
energy being effectively 'lost' to the environment - 25% of that lost energy is transferred into the exhaust gases. For a
typical 100hp (75kW) engine, the waste heat energy is up to 50kW. As a result, automotive OEMS are looking to increase
fuel efficiency through waste exhaust heat power recovery - one very attractive approach for this is the use of Thermo-
Electric Generators (TEGs). To date these approaches have been too expensive due to labour intensive material
consolidation,machining and hand assembly. As the market for these TEGs grows, it is becoming clear that unless
automated, cost-effective manufacturing technologies are developed then mass production will be exported to low-cost
economies. The PRINTEG project will directly address this by developing advance automated technologies for: TE powder
handling and consolidation; Surface mounted pick and place and interconnect deposition and laser sintering. This will
enable cost-effective manufacture in the UK to produce TEGs at a sales price of £490/kW. By achieving this, our
consortium of research capable partners will not only safeguard TEG manufacture in the UK but will also commercialise the
results of our existing Thermo-electric research activities that are already producing globally competitive materials and processes.

Planned Impact

The current market for thermoelectric devices is ~£360 million p.a. Thermoelectric generators constitute approximately 40%
of this market (£144 million). This market is predicted to grow rapidly as the cost per Watt of power output falls below
1euro/W. Eneco forecast that the global market for thermoelectric technology will reach 56 billion euros by 2025, 7.5 billion euros for transportation waste heat recovery. The automotive sector manufactured 53 million cars globally in 2009, with
17.5 million within the EU. Voice of customer work with OEM automotive manufacturers suggests that a TEG module price
of between 0.20-1.40euro/W would be favourable. However, whilst the upper value may be acceptable for a market entry
product for the premium executive saloons, the automotive market is characterised by price competition and economies of
scale will need to be identified. Automotive OEMs are driven by cost efficiencies and employ highly automated
manufacturing processes to achieve these. In addition, increasing fuel costs and concerns about the environment are
driving OEMs to invest in low carbon and green technologies such as waste exhaust heat energy recovery. We have
conservatively estimated a market penetration within the automotive sector of 1.5% by 2018, leading to total sales of
automotive TEG's of 262,000 units per annum. With an indicative target sales price of £490/ 1kW TEG module, the
PRINTEG project will generate in excess of £128 million of sales per year in 5 years and generate a ROI of 1:265
(£875k:£232 million cumulative sales).
However, the current methods of manufacture will not allow this to be achieved cost effectively, where manufacture in the
UK for large-scale production could invariably be lost to the Far East. Therefore UK PLC runs the risk that much of the
intellectual capital we have invested in the development of these technologies will be lost. By achieving enhanced
manufacturing technologies that can achieve high volume, low-cost and high quality, the PRINTEG consortium will enable
competitive manufacture of these technologies in the UK.
The PRINTEG project will exploit their intellectual capital relating to thermo-electric materials, production methods and
applications and accelerate the commercialisation step. This will allow our consortium and supply chain partners to further
develop and commercialise knowledge-based technologies, increasing turn-over and increasing (skilled) employment
opportunities. The PRINTEG technologies will ensure the future manufacture of TEG's will be undertaken within the UK.
The technology will provide the consortium partners with cost effective manufacturing solutions to enable market
penetration and will offer Jaguar a differentiator in terms of automotive performance. Outside of the consortium, PRINTEG
will reduce the cost of transportation and motoring, manufacturing costs and reduce the commercialisation time,
maximising the benefits that can be achieved by application of the thermo-electric technologies to multiple applications for
transport (e.g. automotive, marine and aerospace) as well as for renewable energy applications. Application to each of
these sectors will reduce energy usage, cost and emissions as well as reducing reliance of fossil based fuel imports. These
benefits are fully in-line with UK and EU legislation and policies. The total growth in European GDP as a direct result of our
project is estimated to be £128 m p.a. after 5 years post project by direct sales alone. Based on an average turnover per
employee of £130,000 per annum, this will equate to creating/saving up to 98 jobs mainly within the SME partners.

Publications

10 25 50
 
Description The aim of our research is to reduce the consolidation temperature of silicide powder to increase the production efficiency and to reduce the manufacturing cost of thermoelectric legs, without deteriorating their thermoelectric properties. We tried the consolidation of the chemical doped and ball-milled n and p type thermoelectric powders and found the compactability under hydraulic pressing was improved compared with raw powders. The Spark plasma sintering (SPS) on these materials also showed improved densification behaviours. Both n and p type silicides can be compacted to a complete disk with higher densities after ball milling and chemical doping. For SPS, the densification temperatures of both the n and p type powders were decreased after ball milling and chemical doping. Thermoelectric properties measurement shows good ZT values for the doped and ball milled samples. A programmable processing method using an automatic hydraulic press in this research has increased the efficiency of densification compared to the manual operation. Also, to facilitate the copper joining process at high temperature, both tin-containing and tin-free material were fabricated using SPS and hydraulic press methods. Feedback form collaborated SMEs showed that tin-free MgSi2 and HMS materials are the most promising match for potential commercial application.
Exploitation Route The materials scientist may use this technique to study the densification or sintering of powders, especially if they want to densify their powder materials at room temperature or to lower the sintering temperatures.

Manufacturing companies working on the fabrication of the thermoelectric devices may want to use this technique to increase the production efficiency and reduce the materials and labour cost.
Sectors Aerospace, Defence and Marine,Chemicals,Electronics,Energy,Environment,Government, Democracy and Justice,Manufacturing, including Industrial Biotechology,Transport

URL http://www.europeanthermodynamics.com/research/manufacturing
 
Description Thermoelectric materials have a great potential to alleviate the increasing global energy crisis and environmental problems due to their ability to convert between heat and electricity energy. However, there is a growing concern regarding the toxicity of traditionally used lead and tellurium based materials. Silicides materials have attracted a lot of attentions as good thermoelectric candidates due to their many advantages over lead and tellurium based thermoelectrics. They have widely abundant constituent elements, low cost and low density, and hence meet with large scale production requirements. The high melting points (above 1000 K) enable them to be used for high temperature applications. Their high ZT make them comparable to lead based thermoelectrics. Moreover, they are non-toxic, lead-free and environment-friendly. We developed an automated high pressure high strain compaction process using powder processing technologies. The technique used in this research enables densification at lower temperature, which will save energy, materials and labour cost. The automatic production of the n and p thermoelectric legs will further increase the efficiency and production output of thermoelectric devices. The project also provide contribution to reduce the cost of transportation and motoring, manufacturing costs and reduce the commercialisation time, maximising the benefits that can be achieved by application of the thermo-electric technologies to multiple applications for transport (e.g. automotive, marine and aerospace) as well as for renewable energy applications. Application to each of these sectors will reduce energy usage, cost and emissions as well as reducing reliance of fossil based fuel imports. These benefits are fully in-line with UK and EU legislation and policies. The developed technology provides cost effective manufacturing solutions to make thermoelectrics with improved properties, which is related to a joint project on thermoelectrics funded by Royal Society and Chinese NSFC. Moreover, this project is also related to a workshop organized in 2018: the 2018 Sino-UK Symposium on Advanced Materials and structures thermoelectric & clean energy forum in Xi'an China November 2018, which was funded by UK foreign office. Furthermore, the developed spark plasma sintering method has been used to make texture structured ceramics for dielectric applications. Recently, the developed sintering method has been used to prepare transparent ceramics for different applications.
First Year Of Impact 2018
Sector Aerospace, Defence and Marine,Digital/Communication/Information Technologies (including Software),Electronics,Energy,Environment,Government, Democracy and Justice,Manufacturing, including Industrial Biotechology
Impact Types Economic

 
Description Enhancement of thermoelectric performance of MgAgSb-based composites including ferroelectric ordering
Amount £12,000 (GBP)
Funding ID IEC\NSFC\170290 
Organisation The Royal Society 
Sector Charity/Non Profit
Country United Kingdom
Start 04/2018 
End 03/2021
 
Description Lead-free ferroelectrics for piezoelectric sensors or high power energy storage
Amount £74,000 (GBP)
Funding ID NAF\R1\201126 
Organisation The Royal Society 
Sector Charity/Non Profit
Country United Kingdom
Start 03/2020 
End 03/2022
 
Description PRINTEG collaborations and partnership 
Organisation European Thermodynamics
Country United Kingdom 
Sector Private 
PI Contribution We receive raw materials from Intrinsiq Materials Ltd and process them into densified disks and then send samples to ETL for futher processing. We also characterise the thermoelectric properties of the samples.
Collaborator Contribution Intrinsiq Materials Ltd provides powders of thermoelectric materials and also develops interconnect deposition and laser sintering. European Thermodynamics Ltd works on system specification and design, and also machine the sintered disks to thermoelectric legs. TWI develops suitable brazing technologies. Together with ETL they design and develop an automated system fo the assembly of TEGs. JCR works on the validation of the TEG system from an end-user prespective.
Impact Some high temperature materials for thermoelectric devices application have been created based on this collaboration. This collaboration is multi-disciplinary including materials, chemisty, engineering and electronics.
Start Year 2013
 
Description PRINTEG collaborations and partnership 
Organisation Intrinsiq Materials Ltd
Country United States 
Sector Private 
PI Contribution We receive raw materials from Intrinsiq Materials Ltd and process them into densified disks and then send samples to ETL for futher processing. We also characterise the thermoelectric properties of the samples.
Collaborator Contribution Intrinsiq Materials Ltd provides powders of thermoelectric materials and also develops interconnect deposition and laser sintering. European Thermodynamics Ltd works on system specification and design, and also machine the sintered disks to thermoelectric legs. TWI develops suitable brazing technologies. Together with ETL they design and develop an automated system fo the assembly of TEGs. JCR works on the validation of the TEG system from an end-user prespective.
Impact Some high temperature materials for thermoelectric devices application have been created based on this collaboration. This collaboration is multi-disciplinary including materials, chemisty, engineering and electronics.
Start Year 2013
 
Description PRINTEG collaborations and partnership 
Organisation Jaguar Land Rover Automotive PLC
Department Jaguar Land Rover
Country United Kingdom 
Sector Private 
PI Contribution We receive raw materials from Intrinsiq Materials Ltd and process them into densified disks and then send samples to ETL for futher processing. We also characterise the thermoelectric properties of the samples.
Collaborator Contribution Intrinsiq Materials Ltd provides powders of thermoelectric materials and also develops interconnect deposition and laser sintering. European Thermodynamics Ltd works on system specification and design, and also machine the sintered disks to thermoelectric legs. TWI develops suitable brazing technologies. Together with ETL they design and develop an automated system fo the assembly of TEGs. JCR works on the validation of the TEG system from an end-user prespective.
Impact Some high temperature materials for thermoelectric devices application have been created based on this collaboration. This collaboration is multi-disciplinary including materials, chemisty, engineering and electronics.
Start Year 2013
 
Description PRINTEG collaborations and partnership 
Organisation TWI The Welding Institue
Country United Kingdom 
Sector Private 
PI Contribution We receive raw materials from Intrinsiq Materials Ltd and process them into densified disks and then send samples to ETL for futher processing. We also characterise the thermoelectric properties of the samples.
Collaborator Contribution Intrinsiq Materials Ltd provides powders of thermoelectric materials and also develops interconnect deposition and laser sintering. European Thermodynamics Ltd works on system specification and design, and also machine the sintered disks to thermoelectric legs. TWI develops suitable brazing technologies. Together with ETL they design and develop an automated system fo the assembly of TEGs. JCR works on the validation of the TEG system from an end-user prespective.
Impact Some high temperature materials for thermoelectric devices application have been created based on this collaboration. This collaboration is multi-disciplinary including materials, chemisty, engineering and electronics.
Start Year 2013