Pre-commercial technology validation of a clean cold renewable syngas production plant.

Lead Research Organisation: CRANFIELD UNIVERSITY
Department Name: School of Water, Energy and Environment

Abstract

Domestic oil and gas production is declining and the deployment of fracking within the UK has stalled. Therefore the UK needs new enhanced sources of clean energy. In 2014, 2.6 million tonnes (Mt) of Refuse Derived Fuel (RDF) was exported from the UK and 14.7Mt of suitable input material was landfilled (source: Defra). In the same year, industrial energy consumption was 24Mt of oil equivalent (Mtoe), of this 8Mtoe was gas consumption (including blast furnace, coke oven, town and natural gas). (source: DECC - Energy consumption in the UK (2015)). Not all fossil gas burning industry uses the heat to generate steam, many industrial customers use the gas directly in their processes, and in contact with their product, and thus require the gas to be clean to avoid contaminating their product. Examples of some of these industrial applications would be; lime manufacture (kilns), brickwork manufacture (kilns), earthenware / potteries (kilns), grain drying and sugar beet drying. To enable these industries to prosper, a UK sourced low carbon clean alternative is needed.
Conventional pyrolysis and gasification of RDF produces a hot syngas that has tars and oils contained within the gas stream. These tars and oils prevent the syngas being used for many applications. This new technology produces a clean syngas which will reduce: emissions associated with the transportation of RDF abroad; the fossil gas carbon release with the substitution of the clean renewable syngas; the fossil gas carbon emissions associated with electrical network losses in transmitting the power generated back to the UK. The amount of waste exported from UK as RDF in 2014 was 2.6Mt. Assuming a net average electrical potential of 0.6 MWh per tonne (RDF with a CV around 10 MJ/kg) provides an estimate of 1,560 GWh of potential electrical energy exported. In heat terms, assuming a thermal capacity of 1.2 MWh per tonne, this would estimate a loss of potential heat source from England of 3,120 GWh (source: CIWM).
The development of the full scale integrated prototype pyrolysis and associated syngas clean-up system has demonstrated the concept of producing a clean contaminant free syngas. Through a 12 mth trial this project aims to exploit the technology development achieved to-date, and to demonstrate the robust, repeatable, and consistent production of syngas and substantiate the inputs to a financial model; to a degree of accuracy that technical assessors for funding, planning and permitting bodies will require; successful delivery of the project will enable the technology's commercialisation which will enable it to be part of the energy trilemma solution.
Although there are other large gasification plants, one of the unique selling points of this development is that this patented (feed input to gas generation) small scale modular system can be built alongside the gas customer.

Planned Impact

Locally sourced sustainable alternatives to fossil fuels are crucial as the UK seeks to develop more secure sources of energy, and in this proposal we aim to develop a commercially proven technique of doing so whilst also managing waste streams more sustainably.
Economic benefits business opportunities for companies to use the technology, and cost savings for Councils and businesses with high exposure to waste management costs. Diverse and localised resource supply bases will insulate clients from global commodity shocks and political delays eg to shale gas exploration in Scotland. Social costs include less landfill and incineration and value creation in new enterprises that will develop around syngas from waste pyrolysis sites.
There is a significant and current interest in resource recovery, based around a circular economy, and this project will have impacts on the UK economy and resource management industry. More secure and affordable means of obtaining value from wastes which are otherwise not practical to recycle is key, along with the substitution of fossil-derived energy sources. This emphasises the environmental benefits of the pyrolysis process; through this project the relatively unproven advanced thermal treatment technology will be enhanced and the commercial benefits demonstrated.
The key output of this project, further to the technical data obtained from the trials, will be the UK specific business case for the use of RDF and other waste feedstocks (potentially tyres, chicken litter, sewage sludges etc) for the production of high quality syngas.
 
Description A simulation model has been developed in Aspen Plus to predict the products of pyrolysis (i.e., char, bio-oils and pyrolysis gas) considering an innovative approach by setting six different stages within the pyrolyser. This validated model allows forecasting the composition of the products and by-products of pyrolysis under a range of operating conditions and considering different types of feedstock. Previously to the development of the simulation model, a comprehensive study of the pyrolysis process and the chemistry involved was carried out to gain the knowledge necessary to select the optimal configuration of the modelling elements as well as conditions defined at different locations of the process. The analysis of the pyrolysis was made on the basis of the experimental data recorded from operation of the pilot facility. This model is an important research resource that will allow evaluating the possible products of pyrolysis when implementing a new feedstock without having to perform experimental trials. The use of this simulation model, will enable to select by modelling means those feedstocks that would generate the most energetically valuable products.

Even though an important understanding of the pyrolysis process has been gained during this project, there are still unknowns regarding the kinetic aspects related to pyrolysis reactions.
Exploitation Route The validation of the pyrolysis model developed in Aspen Plus means that an optimal configuration has been defined for the simulation of this process, resource that was not available to researchers and academics in this field until now. The novel approach of setting differentiated stages inside the pyrolyser to simulate, at enhanced accuracy, the reactions and chemical equilibriums reached in each of these stages has proved to generate a good prediction for the pyrolysis products and sub-products. Other researchers can benefit from the work developed in this project by implementing a similar multi-stage methodology for the simulation of their pyrolysis processes adapting the operating conditions (pressure, temperatures, and specific yields of reactions for the substances involved). The Cranfield University and Syngas Products teams are advancing this work through a follow-on Energy Catalyst Round 4 project, also in collaboration with WestAfricaENRG. This project is funded by Innovate UK and aims to understand the chemical processes involved in pyrolysis oil formation, with the overall aim being to convert this material into high-value commodities such as base chemicals for manufacturing or liquid fuels for transport.
Sectors Chemicals,Energy,Environment

URL http://www.vivis.de/phocadownload/Download/2017_wm/2017_WM_355-366_Pontes.pdf
 
Description The chemical knowledge of pyrolysis processes established during this project has enabled many non-academic impacts, including assisting Syngas Products furthering their demonstration plant in Canford (Dorset). Cranfield University and Syngas Products used the findings to apply for further funding under the Energy Catalyst Round 4 call, funded by Innovate UK, to further develop our understanding of pyrolysis oil formation, yield and composition. This project, in collaboration with WestAfricaENRG, completed in September 2018, sought to demonstrate the viability of producing substitute diesel for use in back-up generators in African countries where grid electricity supply is unreliable. Funding was secured from the Global Challenges Research Fund [GCRF] to establish the 1st Sustainable Waste Management in Africa symposium, which was launched in July 2019, hosted in Lagos (Nigeria) with over 250 delegates attending. The state government attended the event and a memorandum of understanding for a 25 MWe energy from waste facility to be constructed in Lagos. This has the potential to make a significant cultural and environment impact in a developing country where waste management infrastructure is considerably under-developed. The model developed during the initial project has enabled us to work in topical areas, applying the new science to seek alternative ways of managing plastic wastes and producing alternative low-carbon liquid fuels. Expertise in the pyrolysis of waste-derived fuels has been enhanced with new chemical knowledge being developed further in recent and emerging projects.
First Year Of Impact 2017
Sector Chemicals,Energy,Environment,Transport
Impact Types Cultural,Societal,Economic

 
Description Energy Catalyst Round 4
Amount £238,000 (GBP)
Funding ID 132942 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 09/2017 
End 09/2018
 
Title Chemistry of pyrolysis 
Description Innovative approach used to simulate a pyrolysis process, by defining 6 stages at different conditions of temperature and pressure. This method allows generating an accurate prediction of the pyrolysis products, in comparison to the available models in the related literature. This is due to the more similar simulation conditions to what occurs in reality of the method, for which the conditions observed experimentally in the pilot facility have been applied to the model. The impact of the method developed is the ability of forecasting in a realistic way the products generated - char, bio-oils and pyrolysis gas- when varying the feedstock into the pyrolyser. 
Type Of Material Improvements to research infrastructure 
Provided To Others? No  
Impact The impact of the method developed is the ability of forecasting in a realistic way the products generated - char, bio-oils and pyrolysis gas- when varying the feedstock into the pyrolyser. 
 
Title Experimental data acquired at multiple locations of a pyrolysis pilot facility 
Description Comprehensive database generated for a pyrolysis process during operation of a pilot facility for hundreds of hours. These data relate to different location within the process and they were logged for various operating conditions and feedstock used. 
Type Of Material Database/Collection of data 
Provided To Others? No  
Impact The main impact of having the new database of empirical information, is that it can be used to validate the simulation model developed. An additional positive consequence of having such an extended database for a pyrolysis process, it is that it will allow to analyse in a detailed way the possible mechanisms of reaction occurred. 
 
Title Simulation model for pyrolysis 
Description A simulation model for pyrolysis has been developed using the commercial software Aspen Plus. The result of this work is an optimised configuration of the elements available in Aspen, which permits to predict accurately the products of pyrolysis depending on the characteristics of the feedstock provided to the process. The simulation results have been validated by comparing them with the empirical measurements taken during operation of the pyrolysis pilot facility as regards to streams composition (i.e., char, bio-oils and pyrolysis gas), and operating conditions at different locations of the process (e.g., pressure and temperature). 
Type Of Material Computer model/algorithm 
Provided To Others? No  
Impact The main impact of the validated simulation model developed in Aspen Plus is its capability to predict accurately the products of pyrolysis generated depending of the feedstock composition and on the operating conditions defined for the process. 
 
Description Energy from Waste conference in Lagos (Nigeria) 
Organisation WestAfricaENRG
Country Nigeria 
Sector Private 
PI Contribution Following the Innovate UK project we collaborated with WestAfricaENRG to create the first Energy from Waste conference in Africa. This was in collaboration with WestAfricaENRG, the Lagos Waste Management Association [LAWMA] and the Lagos chapter of the Nigerian Environmental Engineering Society. The funding for Cranfield was sourced from an internal GCRF fund, with WestAfricaENRG covering the cost of the event. The event was free-to-attend and had over 250 delegates.
Collaborator Contribution Cranfield organised the conference, managed the scientific contributions and publicised this on various platforms.
Impact The conference promoted significant discussions among delegates and has accelerated the interest and willingness to improve waste management in Nigeria. WestAfricaENRG are developing plans to build the first energy from waste facility in West Africa, which will be located in Lagos.
Start Year 2019
 
Title Aspen Plus 
Description Aspen Plus is a software used for the design, operation, and optimization of chemical processes. It provides a wide array of tools to construct and optimize process models including physical properties, ability to handle solid, liquid, and gas processes, advanced electrolytes and equation oriented (E/O) modelling mode. Aspen Plus has the world's most extensive property database and handles solid, fluid and gas phase processes -making it one of the best choices for chemicals, polymers, specialty chemicals, pharmaceuticals and biotech, biofuels, power, carbon capture, minerals, metals and mining. 
Type Of Technology Software 
Year Produced 2017 
Impact The extensive database of Aspen Plus as regards to the properties of the substances,as well as the wide choice of simulation elements in its library to mimic the different steps that take place in any chemical process (for mass and energy aspects), made easy its selection for the development of the simulation model for pyrolysis. 
 
Title HSC Chemistry 
Description HSC Chemistry is a software for process simulation, reactions equations, heat and material balances, equilibrium calculations, electrochemical cell equilibriums, Eh-pH diagrams - Pourbaix diagram. This software can be used as add-in into Microsoft Excel to create a mathematical model with access to physical and chemical properties of the substances involved. 
Type Of Technology Software 
Year Produced 2016 
Impact HSC Chemistry was used to develop a preliminary model in Microsoft Excel to work out the mass and energy balances of the pyrolysis process studied for the present work. The previous evaluation of the process using HSC Chemistry permitted to speed up the later development of the simulation model in Aspen Plus.