Do volcanoes emit mercury? Understanding the behaviour of Hg in volcanic products.
Lead Research Organisation:
University of Oxford
Department Name: Earth Sciences
Abstract
This is a proposal to make some modern measurements of the quantities of volatile trace metals that are released to the atmosphere by volcanoes. Volcanic gases are often equated with sulphur. In fact, sulphur is just one component of volcanic gases; and in just the same way that sulphur from volcanoes can affect the atmosphere, so may other species. We wish to make measurements of mercury at volcanoes. Mercury is a curious element: in its elemental form (Hg(o)) it is very volatile, and is not usually very reactive. As a result, once it is in the atmosphere it will stay there for a long time (about a year), before eventually being removed. Mercury is of general interest because it is highly toxic [the cause, for example, of the condition described by the phrase 'mad as a hatter']. It has no 'useful' function for biological organisms, but becomes concentrated up the food chain. One of the big problems with the current understanding of natural mercury in the atmosphere is that the books don't balance: we don't know very well where mercury is released from; and we don't know where it ends up. It is possible that volcanoes contribute to this imbalance: some people think that volcanoes may release a large amount of mercury, perhaps as much as half of all natural emissions; others think that it is so small that it can be ignored. By making measurements close to the vent of two active volcanoes using some new and very sensitive equipment, we hope to resolve this problem: at the very least, we'll know how much mercury is released by steady, gentle activity at the world's persistently active volcanoes. These volcanoes might not hit the headlines, but our idea is that they are always there in the background, supplying gases and particles to the atmosphere. A second scientific problem that we want to look at is to understand how mercury escapes from molten lavas; in what forms it escapes (is it mainly in the gaseous form? or does some of it very quickly form very small particles? and if so , what happens to those particles?); and we want to use the way that mercury behaves to understand more about the extreme (hot, oxidising, chemically reactive) environment that is a volcanic plume. A third aspect that we also wish to study is to use the erupted rocks and minerals (at the same two volcanoes, Etna and Kilauea) to try and understand how mercury and its chemically-similar 'cousins' (metals including Cd, Zn, Cu) behave as a rock cools and crystallises. We think that mercury and cadmium, for example, should have a slight preference for certain minerals (clinopyroxene, feldspar), and that as a result their concentration in the melt won't change much during crystallisation, but may change a little by 'degassing'. We can test this idea using precise (laser) measurements of small samples of real rocks.
Organisations
Publications
Aiuppa A
(2007)
Real-time simultaneous detection of volcanic Hg and SO 2 at La Fossa Crater, Vulcano (Aeolian Islands, Sicily)
in Geophysical Research Letters
Bagnato E
(2007)
Degassing of gaseous (elemental and reactive) and particulate mercury from Mount Etna volcano (Southern Italy)
in Atmospheric Environment
Collins S
(2009)
Melt inclusions track pre-eruption storage and dehydration of magmas at Etna
in Geology
Gabrielli P
(2008)
Siderophile metal fallout to Greenland from the 1991 winter eruption of Hekla (Iceland) and during the global atmospheric perturbation of Pinatubo
in Chemical Geology
Martin R
(2008)
Composition-resolved size distributions of volcanic aerosols in the Mt. Etna plumes
in Journal of Geophysical Research: Atmospheres
Martin R
(2009)
Size distributions of fine silicate and other particles in Masaya's volcanic plume
in Journal of Geophysical Research: Atmospheres
Martin R
(2010)
Major and trace element distributions around active volcanic vents determined by analyses of grasses: implications for element cycling and bio-monitoring
in Bulletin of Volcanology
Martin R
(2009)
Sweet chestnut (Castanea sativa) leaves as a bio-indicator of volcanic gas, aerosol and ash deposition onto the flanks of Mt Etna in 2005-2007
in Journal of Volcanology and Geothermal Research
Description | Project findings have all been documented in the final report and on the NERC research outputs database. |
Exploitation Route | Outcomes have been fully documented elsewhere. |
Sectors | Environment |
Description | Our work on natural mercury emissions has been used to develop briefings for policy makers, in the lead up to the discussions around the 2013 Minamata mercury convention. |
First Year Of Impact | 2011 |
Sector | Chemicals,Environment |
Impact Types | Policy & public services |
Description | Costing the Earth |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | Interviewed as part of Lava: A Dangerous Game |
Year(s) Of Engagement Activity | 2015 |
URL | http://www.bbc.co.uk/programmes/b055g73y |
Description | George and the Blue Moon |
Form Of Engagement Activity | A magazine, newsletter or online publication |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Schools |
Results and Impact | I wrote a science essay in a children's book |
Year(s) Of Engagement Activity | 2016 |
URL | https://www.penguin.co.uk/puffin/books/1097513/george-and-the-blue-moon/ |
Description | Life Scientific |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | 30 min programme on Radio 4's Life Scientific broadcast at 9am and via podcast |
Year(s) Of Engagement Activity | 2017 |
URL | http://www.bbc.co.uk/programmes/b08t0d3w |
Description | Oxford Science Blog on impacts of volcanic gases |
Form Of Engagement Activity | Engagement focused website, blog or social media channel |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Wrote a blog about fieldwork |
Year(s) Of Engagement Activity | 2018 |
URL | http://www.ox.ac.uk/news/science-blog/living-volcanic-gases-0 |
Description | The Forum |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Panel discussion The Unpredictable Planet: Understanding Volcanoes and Earthquakes on BBC World Service |
Year(s) Of Engagement Activity | 2016 |
URL | http://www.bbc.co.uk/programmes/p041svq3 |
Description | The Infinite Monkey Cage |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Public/other audiences |
Results and Impact | Part of a panel on The Infinite Monkey Cage with Brian Cox, Robin Ince, comedian Jo Brand and Clive Oppenheimer on BBC Radio 4. |
Year(s) Of Engagement Activity | 2018 |
URL | http://www.bbc.co.uk/programmes/b09r47j1 |