Ultrasonic Measurement Of The Transition Zone's Seismic Velocities

Lead Research Organisation: University College London
Department Name: Earth Sciences

Abstract

The Earth's mantle transition zone extends from approximately 410 to 660 km depth, is a vast and inaccessible layer of the Earth. There are no direct samples from the transition zone, so everything we know about this region is inferred from the speed that seismic sound waves transit this region. By constraining the acoustic properties of potential mineral assemblages using experiments, Earth Scientists can infer its temperature, chemistry, structure and water content. Additionally, seismic data can be used in an analogous way to medical ultrasound, to image lateral variations, which reveal that the seismic properties of the transition zone change subtly around the globe, which presumably reflect variations in temperature, mineralogy or composition. The transition zone is particularly important for understanding the large-scale dynamic and chemical evolution of planet Earth because (i) many subducting slabs stall there for millions of years before continuing descent into the lower mantle and (ii) the transition zone has a huge water capacity, potentially holding 10 times more water than the surface oceans. If we could use seismic observations to directly image the temperature and composition of the transition zone we would take a gigantic step towards understanding the behaviour of Earth's deep interior.

Whilst seismology provides us with ever increasingly detailed views of the Earth's interior, the challenge that remains is to interpret this data in terms of the mineralogy, chemistry and temperature of the mantle and core. However, there is surprisingly little experimental data on the seismic properties of mantle minerals under the appropriate pressure and temperature conditions for the transition zone. Even for olivine, the most common upper mantle mineral making up almost 60% of mantle rocks down to depths of 410 km, data are restricted to < 1300 K, whereas upper mantle temperatures range from 1500 to 2000 K. The situation for other mantle phases is far worse. In lieu of data it has been commonplace to use thermodynamic databases, with the assumption that the these can be safely extrapolated to transition zone conditions. However, we have discovered that these databases are not reliable because do not even match the available data.

The paucity of experimental data at high pressure and temperature conditions is simply due to experimental constraints. In this proposal we will employ a new method to routinely measure seismic velocities with high-frequency ultrasonic waves at real transition zone conditions using university-based equipment. We will use this to measure compressional and shear wave velocities of the most significant upper mantle and transition zone minerals as a function of changing pressure, temperature, composition and water content. We believe this will be transformational for our understanding of the deep Earth.

Planned Impact

This is fundamental research, not driven directly by industry or policy makers, so whilst there is no direct application for these communities, there is potential for spin-off projects using the techniques developed in this proposal. Specifically, the development of lab-based X-ray imaging of high-pressure sample environments is of interest to some UK industry - we have already discussed this with AWE who are now in the process of actively looking to collaborate on this development as they are interested in developing it for alternative applications. Initially this is planned to be via funding jointly-led PhD student research.

Additionally, study of the vast and remote interior of Earth can capture the imagination and curiosity of the general public. We plan to continue and develop our current outreach projects, visiting primary and secondary schools in and around London to provide educational workshops and promote science to a wide audience. Furthermore, it is our experience that this, and similar research is of interest to a wide audience who we will attempt to reach via social media, EU science blogs, publications in prominent journals and related media coverage if possible.

Publications

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Thomson A (2021) Incorporation of tetrahedral ferric iron into hydrous ringwoodite in American Mineralogist

 
Description We have determined the PVT EoS and incomplete ultrasonic velocities of ringwoodite as a function of composition from Fa100 to Fo100. We have also measure Fo90 and Fo100 wadsleyite. Data is under analysis for publication
Exploitation Route They will be incorporated in mineral physics models and used to interpret seismological observations
Sectors Education,Environment,Other

 
Title Lab X-ray radiography 
Description The commissioning of Lab X-ray radiography for high pressure samples is almost complete in the high pressure labs at UCL. 
Type Of Material Improvements to research infrastructure 
Year Produced 2022 
Provided To Others? No  
Impact None yet 
 
Description Affiliated Scientist at the Natural History Museum 
Organisation Natural History Museum
Country United Kingdom 
Sector Public 
PI Contribution To facilitate collaboration with Paul Schofield and the crystallography group at the NHM, whose facilities will be utilised throughout this project, I am now an affiliated Scientific Associate.
Collaborator Contribution This partnership is in its infancy
Impact None yet
Start Year 2022
 
Description Collaboration in ultrasonic meausrements of slab related phases 
Organisation Carnegie Institution for Science (CIS)
Country United States 
Sector Charity/Non Profit 
PI Contribution In collaboration with Dr Anne Pommier at Carnegie Institue for Science, we are working together to perform lab-based and beamtime experiments to measure the acoustic velocities of hydrous slab phases.
Collaborator Contribution We have shared results, experimental design and data. We have attended each-others beamtime sessions at APS and are actively working on extending the scope of this project.
Impact data collection and analysis. So far this is still in progress.
Start Year 2022