ISCF Wave 1:Designing Electrodes for Na Ion Batteries via Structure Electrochemical Performance Correlations
Lead Research Organisation:
Queen Mary University of London
Department Name: School of Engineering & Materials Scienc
Abstract
Alignment with the Industrial Strategy Challenge Funds
This proposal aims to advance fundamental knowledge within the development low cost anodes for Na-ion batteries in order to accelerate the commercialisation of Na-ion batteries in the UK. Our proposed research clearly aligns with the Industrial Strategy Challenge Funds objectives and aims as following:
ELECTRONIBs will closely collaborate with major industrial battery developers in the UK (Johnson Matthey and Faradion). Having them closely involved within our research will enable us to further apply jointly for various industrial funds in the future (for example via Innovate UK or the future Faraday Institute) to facilitate collaborations with other major industrial and academic battery developers in the UK. This will in turn increase the UK businesses' investment in R&D and improved R&D capability and capacity.
ELECTRONIBS is a highly interdisciplinary research involving materials synthesis, electrochemistry, advanced characterisation and modelling and academics with complementary expertise. We will work closely with many EU and international experts from Germany, China, Sweden and Japan and we will involve UK and International industries. Therefore, we are likely to have an important academic and industrial impact not only at national level but also internationally leading to an increased multi- and interdisciplinary research around the very challenging area of low cost energy storage.
Having directly involved in our proposal several UK and international companies working in the challenging are of batteries and energy storage will likely lead to an increased business-academic engagement on innovation activities in the field of Na-ion batteries. Key results will be discussed directly with industry, with a view to applying for Innovate UK funding to develop products based on shared expertise - our knowledge and understanding of the materials and how to synthesize/process them; industry's knowledge of product development, from initial prototype to market-ready devices, as well as their keen business acumen and market knowledge needed to successfully take a product to market.
ELECTRONIBS has partners ranging from well established companies like JM to smaller SMES working in the field of Energy Storage like Faradion as well as companies producing low cost carbon materials such as AVA CO2. We have collaborative links with Toyota Central Research and Development Laboratories, the pioneering hybrid motor vehicle company that has a truly international influence. We also have Chinese Academy of Science via the Institute of Physics involved which have now their own spin off in producing Na-ion batteries. This will likely lead to increased collaboration between younger, smaller companies and larger, more established companies up the value chain in the UK and internationally. Our international collaborations will likely increase overseas investment in R&D in the UK.
Due to their outstanding energy and power density, lithium-ion batteries (LIBs) have become the technology of choice for today's electrical energy storage. However, LIBs are not suitable for stationary energy storage because of their high costs and increasingly higher strain on lithium resources. Therefore there is a strong need to increase the diversity of energy storage solutions for energy security considerations.
Sodium-ion batteries (SIBs) started to receive significantly more attention as low cost and affordable alternative to LIBs. This grant will explore new lost cost anodes based on available precursors with the aim to increase the SIB performance and facilitate their comercialisation. We will develop fundamental insights into the mechanisms of sodium ion storage, diffusion and intercalation in our designed electrodes by employing complex characterisation techniques and molecular simulations during battery operation.
This proposal aims to advance fundamental knowledge within the development low cost anodes for Na-ion batteries in order to accelerate the commercialisation of Na-ion batteries in the UK. Our proposed research clearly aligns with the Industrial Strategy Challenge Funds objectives and aims as following:
ELECTRONIBs will closely collaborate with major industrial battery developers in the UK (Johnson Matthey and Faradion). Having them closely involved within our research will enable us to further apply jointly for various industrial funds in the future (for example via Innovate UK or the future Faraday Institute) to facilitate collaborations with other major industrial and academic battery developers in the UK. This will in turn increase the UK businesses' investment in R&D and improved R&D capability and capacity.
ELECTRONIBS is a highly interdisciplinary research involving materials synthesis, electrochemistry, advanced characterisation and modelling and academics with complementary expertise. We will work closely with many EU and international experts from Germany, China, Sweden and Japan and we will involve UK and International industries. Therefore, we are likely to have an important academic and industrial impact not only at national level but also internationally leading to an increased multi- and interdisciplinary research around the very challenging area of low cost energy storage.
Having directly involved in our proposal several UK and international companies working in the challenging are of batteries and energy storage will likely lead to an increased business-academic engagement on innovation activities in the field of Na-ion batteries. Key results will be discussed directly with industry, with a view to applying for Innovate UK funding to develop products based on shared expertise - our knowledge and understanding of the materials and how to synthesize/process them; industry's knowledge of product development, from initial prototype to market-ready devices, as well as their keen business acumen and market knowledge needed to successfully take a product to market.
ELECTRONIBS has partners ranging from well established companies like JM to smaller SMES working in the field of Energy Storage like Faradion as well as companies producing low cost carbon materials such as AVA CO2. We have collaborative links with Toyota Central Research and Development Laboratories, the pioneering hybrid motor vehicle company that has a truly international influence. We also have Chinese Academy of Science via the Institute of Physics involved which have now their own spin off in producing Na-ion batteries. This will likely lead to increased collaboration between younger, smaller companies and larger, more established companies up the value chain in the UK and internationally. Our international collaborations will likely increase overseas investment in R&D in the UK.
Due to their outstanding energy and power density, lithium-ion batteries (LIBs) have become the technology of choice for today's electrical energy storage. However, LIBs are not suitable for stationary energy storage because of their high costs and increasingly higher strain on lithium resources. Therefore there is a strong need to increase the diversity of energy storage solutions for energy security considerations.
Sodium-ion batteries (SIBs) started to receive significantly more attention as low cost and affordable alternative to LIBs. This grant will explore new lost cost anodes based on available precursors with the aim to increase the SIB performance and facilitate their comercialisation. We will develop fundamental insights into the mechanisms of sodium ion storage, diffusion and intercalation in our designed electrodes by employing complex characterisation techniques and molecular simulations during battery operation.
Planned Impact
This project aims to make significant advances in Na ion battery technologies via multidisciplinary research to enable tuning materials properties for improved performance and faster developments.
The successful delivery of this project will lead to production of Na-ion batteries prototypes and future commercialisation, providing cheaper, cleaner, safer and more sustainable energy storage solutions. This will allow a more intensive use of renewables and therefore a reduction of CO2 emissions within the UK energy landscape and thus bring significant health and environmental benefits.
The development of low cost energy storage devices will also promote reductions in the costs of portable electronic devices, which will have important societal impact.
The benefits to the wider society are:
(1) a low cost energy storage technology made available via sodium ion batteries;
(2) greater energy storage capacity in the UK and thus huge savings in the energy bills for the public;
(3) large-scale employment of renewable energies in the UK ( particularly wind, wave and tidal energy) and thus the transition to a low carbon society;
(4) enhancement of the UK's energy security and environmental sustainability.
Commercial beneficiaries of the research (wealth generation in 10 - 25 years) will be companies in the UK and worldwide in/or part of the supply chain for Na-ion technologies. More specifically, in the 5 - 15 year window, UK industry will directly benefit if the outcomes of the research would lead to more developed and focused academic-industry collaborations (Innovate UK/ Knowledge Transfer Partnerships). The potential IP that could be generated in the area of Na-ion technology for energy storage will yield opportunities for spin-out companies, providing employment opportunities and adding value to the UK economy.
The UK-based and international partners are committed to supporting aspects of this project within their own research capacity. Further collaborations with leading groups and the development of multidisciplinary research projects will be fostered during this project. Close collaborations with prestigious academic partners such as Chinese Academy of Science, Institute of Physics in Beijing, Max-Planck Institutes and KTH Royal Institute of Technology within the project will stimulate global collaborations and facilitate knowledge transfer across countries.
In short-term (3 years), this project will provide highly skilled researchers (i.e. PDRAs and PhDs in the project) who will have developed multidisciplinary skills and will have experienced a broad range of technological fields that are important for R&D programmes required for market innovation for NIB technology and beyond.
The project will also enable the creation of a platform for taking MSc, MEng and BSc students on a vast range of small projects. This will enable graduates (particularly those from QMUL and Surrey) to be trained with cutting edge technology and skills for the job market.
Thus the impact can be seen within the academic community in terms of new and niche UK research, educational areas in terms of skills development and teaching materials and policy areas in terms of growing realistic options within the energy diversity goals.
The successful delivery of this project will lead to production of Na-ion batteries prototypes and future commercialisation, providing cheaper, cleaner, safer and more sustainable energy storage solutions. This will allow a more intensive use of renewables and therefore a reduction of CO2 emissions within the UK energy landscape and thus bring significant health and environmental benefits.
The development of low cost energy storage devices will also promote reductions in the costs of portable electronic devices, which will have important societal impact.
The benefits to the wider society are:
(1) a low cost energy storage technology made available via sodium ion batteries;
(2) greater energy storage capacity in the UK and thus huge savings in the energy bills for the public;
(3) large-scale employment of renewable energies in the UK ( particularly wind, wave and tidal energy) and thus the transition to a low carbon society;
(4) enhancement of the UK's energy security and environmental sustainability.
Commercial beneficiaries of the research (wealth generation in 10 - 25 years) will be companies in the UK and worldwide in/or part of the supply chain for Na-ion technologies. More specifically, in the 5 - 15 year window, UK industry will directly benefit if the outcomes of the research would lead to more developed and focused academic-industry collaborations (Innovate UK/ Knowledge Transfer Partnerships). The potential IP that could be generated in the area of Na-ion technology for energy storage will yield opportunities for spin-out companies, providing employment opportunities and adding value to the UK economy.
The UK-based and international partners are committed to supporting aspects of this project within their own research capacity. Further collaborations with leading groups and the development of multidisciplinary research projects will be fostered during this project. Close collaborations with prestigious academic partners such as Chinese Academy of Science, Institute of Physics in Beijing, Max-Planck Institutes and KTH Royal Institute of Technology within the project will stimulate global collaborations and facilitate knowledge transfer across countries.
In short-term (3 years), this project will provide highly skilled researchers (i.e. PDRAs and PhDs in the project) who will have developed multidisciplinary skills and will have experienced a broad range of technological fields that are important for R&D programmes required for market innovation for NIB technology and beyond.
The project will also enable the creation of a platform for taking MSc, MEng and BSc students on a vast range of small projects. This will enable graduates (particularly those from QMUL and Surrey) to be trained with cutting edge technology and skills for the job market.
Thus the impact can be seen within the academic community in terms of new and niche UK research, educational areas in terms of skills development and teaching materials and policy areas in terms of growing realistic options within the energy diversity goals.
Organisations
- Queen Mary University of London (Lead Research Organisation)
- Chinese Academy of Sciences (Collaboration)
- Humboldt University of Berlin (Collaboration)
- The Faraday Institution (Collaboration)
- Shell Global Solutions International BV (Collaboration)
- Johnson Matthey (United Kingdom) (Collaboration)
- UNIVERSITY OF CAMBRIDGE (Collaboration)
- Petronas (Collaboration)
Publications
Abouelamaiem D
(2018)
Integration of supercapacitors into printed circuit boards
in Journal of Energy Storage
Abouelamaiem D
(2018)
Synergistic relationship between the three-dimensional nanostructure and electrochemical performance in biocarbon supercapacitor electrode materials
in Sustainable Energy & Fuels
Alptekin H
(2020)
Sodium Storage Mechanism Investigations through Structural Changes in Hard Carbons
in ACS Applied Energy Materials
Au H
(2020)
A revised mechanistic model for sodium insertion in hard carbons
in Energy & Environmental Science
Bai J
(2020)
Synthesis of Bi2S3/carbon nanocomposites as anode materials for lithium-ion batteries
in Journal of Materials Science & Technology
Boyjoo Y
(2020)
Molecular-Level Design of Pyrrhotite Electrocatalyst Decorated Hierarchical Porous Carbon Spheres as Nanoreactors for Lithium-Sulfur Batteries
in Advanced Energy Materials
Bray JM
(2020)
Operando visualisation of battery chemistry in a sodium-ion battery by 23Na magnetic resonance imaging.
in Nature communications
Butt M
(2018)
Biomass-Derived Nitrogen-Doped Carbon Aerogel Counter Electrodes for Dye Sensitized Solar Cells
in Materials
Chen Y
(2023)
Sustainable and scalable fabrication of high-performance hard carbon anode for Na-ion battery
in Journal of Power Sources
Glatthaar C
(2023)
Lignin-Derived Mesoporous Carbon for Sodium-Ion Batteries: Block Copolymer Soft Templating and Carbon Microstructure Analysis.
in Chemistry of materials : a publication of the American Chemical Society
Description | see the number 2 version submitted as this grant has been transferred from QMUL to ICL |
Exploitation Route | see v2 submitted this version is no longer valid |
Sectors | Chemicals Electronics Energy Transport |
Description | This grant was transferred hence you will need to look at the follow up from ICL |
Sector | Electronics,Energy,Manufacturing, including Industrial Biotechology,Transport |
Impact Types | Cultural Societal |
Description | Policy even on sustainable batteries |
Geographic Reach | Local/Municipal/Regional |
Policy Influence Type | Influenced training of practitioners or researchers |
Impact | a UK list for critical minerals |
Description | An automated high-throughput robotic platform for accelerated battery and fuels discovery - DIGIBAT |
Amount | £1,656,452 (GBP) |
Funding ID | EP/W036517/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 01/2023 |
End | 12/2025 |
Description | Chair in Emerging Technologies |
Amount | £2,700,000 (GBP) |
Funding ID | CiET1819\2\60 |
Organisation | Royal Academy of Engineering |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start | 02/2020 |
End | 02/2030 |
Description | Petronas Industrial Collaboration |
Amount | £1,300,000 (GBP) |
Organisation | Petronas |
Sector | Private |
Country | Malaysia |
Start | 03/2023 |
End | 04/2025 |
Description | Collaboration on fundamentals of na storage |
Organisation | Chinese Academy of Sciences |
Country | China |
Sector | Public |
PI Contribution | Chinese Academy of Science-Institute of Physics |
Collaborator Contribution | We have worked together towards further understaffing of the Na storage mechanism in hard carbons |
Impact | We have published a series of scientific papers on the na storage mechanism and visited the institute. they also organised the international Na ion battery conference in 2023 in Lying China where I gave a presentation |
Start Year | 2019 |
Description | Collaboration with Shell |
Organisation | Shell Global Solutions International BV |
Department | Shell Chemicals in Europe |
Country | Netherlands |
Sector | Private |
PI Contribution | We are performing research on discovering low cost anode materials for Na ion batteries and test their electrochemical interfaces to achieve high reversible Coulombic efficiency. |
Collaborator Contribution | They funded two PhD students and one PDRA to complement the ISCF project and deliver the next generation on na ion batteries and they will provide some access to Shell laboratories in Amsterdam. |
Impact | Is to early to list outputs as this was funded end of 2019 |
Start Year | 2019 |
Description | Johnson Matthey Battery Technology Centre |
Organisation | Johnson Matthey |
Department | Johnson Matthey Technology Centre |
Country | United Kingdom |
Sector | Private |
PI Contribution | QMUL was responsible for the development of anode materials for Na-ion batteries from biomass derived precursors in terms of synthesis, characterisation and performance analysis. QM's involvement in the project was definitely beneficial as the vast expertise of Prof Titirici's in the synthesis of sustainable and low cost carbons with various characteristics (pore size, functionality, level of graphitisation) was constructive on the decision making on the progress of developing the anode materials and corresponding half cell testings. |
Collaborator Contribution | Johnson Matthey's involvement in the LOCONIBs project was on the development of the cathode materials and the half and full cell testing. They have succesfully achieved the milestones set, which were: - To develop cathodes materials based on reduced or substitution of critical raw materials with more abundant, lower cost, elements while maintaining the performance - To develop a protocol to test sodium ion batteries - To investigate ways to maximise the electrochemical performance. |
Impact | Significant results have been achieved in this one year long feasibility project for the development of low cost electrodes for sodium ion batteries. The promising results in terms of electrochemical performances show the materials's potential use as electrodes in Na-ion batteries and are believed to be close to the level required for practical applications. Significant knowledge and experience have been gained concerning materials preparation, scaling up and testing protocols. Additionally, the project was presented in UK Energy Storage (UKES) Conference and an entry was made for Rushlight Awards. Excellent feedback was received from both. A poster prize was achieved in UKES with the title of "Biomass-Derived Low Cost Negative Electrodes in Na-Ion Batteries." Three manuscripts are also being worked on to be published in specialised journals |
Start Year | 2016 |
Description | Understanding fundamentals on na ion batteries |
Organisation | Humboldt University of Berlin |
Country | Germany |
Sector | Academic/University |
PI Contribution | understanding intercalation of Na in hard carbons |
Collaborator Contribution | Access to equipment to measure change in electrode's thickness during cycling |
Impact | scientific papers |
Start Year | 2021 |
Description | Working together on Na anode free batteries |
Organisation | Petronas |
Country | Malaysia |
Sector | Private |
PI Contribution | We are investigating new ways to achieve high energy density and sustainable Na ion batteries |
Collaborator Contribution | Petronas i s funding a research project with me as PI and 2 PDRAs |
Impact | we are working towards a patent |
Start Year | 2023 |
Description | collaboration on na storage mechanism |
Organisation | University of Cambridge |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | we have made use of the knowdlelege and NMR facilities in the department of chemistry at cambridge |
Collaborator Contribution | performed solid state NMR experiments |
Impact | several high impact publications |
Start Year | 2019 |
Description | upscaling Na ion battery cathodes and manufacturing of pouch cells |
Organisation | The Faraday Institution |
Country | United Kingdom |
Sector | Charity/Non Profit |
PI Contribution | upscaling hard carbon anodes and pouch cells manufacturing |
Collaborator Contribution | providing cathodes for pouch cells |
Impact | we will upscale our hard carbon anodes and provide to all NEXGENA partners and we manufacture pouch cells with various nextgena cathodes |
Start Year | 2023 |
Description | COPS 26-talk on sustainable batteries |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Media (as a channel to the public) |
Results and Impact | with Royal Society of Chemistry I contributed to a panel discussion on sustainable batteries |
Year(s) Of Engagement Activity | 2021 |
Description | Consultation at the House of lords on Critical Materials |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Policymakers/politicians |
Results and Impact | I was invited to provide a consultation to the House of Lords on critical materials and batteries |
Year(s) Of Engagement Activity | 2021,2022 |
Description | Discussion of electric cars and Na-ion technology on BBC Radio 4's Inside Science |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Media (as a channel to the public) |
Results and Impact | Recording a short segment/interview with a journalist from BBC Radio 4's Inside Science about the future of electric cars, and future battery technology, to raise awareness of alternative energies and discussion about viability. |
Year(s) Of Engagement Activity | 2020 |
URL | https://www.bbc.co.uk/programmes/m000d8st |
Description | Many scientific conferences, MRS, ACS, MC-16, Commonwealth Conferences, etc |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Postgraduate students |
Results and Impact | I have given over 150 talks at various conferences/events on disseminating my research results |
Year(s) Of Engagement Activity | 2021,2022,2023,2024 |
Description | Outreach for general public |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Public/other audiences |
Results and Impact | We organised a meeting on food waste, raising awarnence and explaining ways to convert waste into battery materials |
Year(s) Of Engagement Activity | 2023 |
Description | Outreach to general public |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Public/other audiences |
Results and Impact | I gave a talk on sustainable energy for the general public in a pub |
Year(s) Of Engagement Activity | 2022 |
Description | Science museum-future of mobility |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Schools |
Results and Impact | we organised an expo for kids and parents on the future of transport in 2035 |
Year(s) Of Engagement Activity | 2022 |