RestartNH3 - Energy functional processes and materials for storage of renewable energy in ammonia

Lead Research Organisation: University of Cambridge
Department Name: Chemical Engineering and Biotechnology

Abstract

When Carl Bosch and Fritz Haber received their Nobel prize for the discovery of the artificial nitrogen fixation process (the Haber-Bosch process), they acknowledged that there might be other ways of producing ammonia. Over a century later, we are still using the same fossil fuel-dependent process and a very similar catalyst. Now, the time has arrived to restart the role of ammonia beyond feeding over 50 % of the population as fertiliser. In a carbon-free society, ammonia (with a high energy density and a well-established transport infrastructure) is anticipated to be the lynchpin for the long-term storage of renewable energy to align its production with our energy demands. RestartNH3 will provide a ground-breaking recycle-less ammonia synthesis process, driven exclusively by renewable energy, water and air. Its fundamental pillars will be the development of energy functional nano-materials as low temperature ammonia catalysts and high temperature absorbents. Innovative technological advances will build on these revolutionary capabilities through the pioneering integration of the reaction and separation steps into a recycle-less process as well as a self-sustained, energy-efficient regeneration of absorbents via a unique heat integration strategy. RestartNH3 will deliver an agile (fast response), efficient (high energy storage), distributed (low capital versus the economy of scale of the conventional Haber Bosch process) ammonia synthesis process aligned to the intermittent and geographically isolated production of renewable energy. As a result, we will be able to store renewable energy in their production points, to be stored long-term and transported in the form of ammonia. Such a process has the potential to create a new global carbon-free energy trade system similar to the existing one around fossil fuels, essential to fulfil our carbon-free ambitions and contribute to the UN Sustainable Development Goals.

Publications

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Torrente-Murciano L (2023) Process challenges of green ammonia production in Nature Synthesis

 
Description Policy briefing - Green Carbon for the Chemical Industry by Royal Society
Geographic Reach National 
Policy Influence Type Participation in a guidance/advisory committee
 
Description Policy workshop on Maritime Decarbonisation - Department for Transport
Geographic Reach Multiple continents/international 
Policy Influence Type Participation in a guidance/advisory committee
 
Description A paradigm shift in nitrogen activation for green ammonia synthesis
Amount £200,617 (GBP)
Funding ID EP/X016757/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 03/2023 
End 09/2024
 
Title Research data supporting "The potential of Green Ammonia for Agricultural and Economic Development in Sierra Leone" 
Description These data provides the input information to construct a spacial model for rice production and consumption in Sierra Leone and resolve the mass balances, cost equations and energy storage capacity. Information includes a table of current hydroelectric sites, the 48 population centres in which the country is divided in the model, the rice production and area of each of these centres, total rice consumption, current fertliser prices, estimation of agricultural yields, coffee cultivation and amount of fertilisers applied for rice cultivation 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
Impact These data provides the input information to construct a spacial model for rice production and consumption in Sierra Leone and resolve the mass balances, cost equations and energy storage capacity useful for other researchers to build similar models. 
URL https://www.repository.cam.ac.uk/handle/1810/315825
 
Title Supporting Data Exceeding single-pass equilibrium with integrated absorption separation for ammonia synthesis using renewable energy - redefining the Haber-Bosch loop 
Description Selected annotated data results as presented in "Exceeding single-pass equilibrium with integrated absorption separation for ammonia synthesis using renewable energy - redefining the Haber-Bosch loop." This excel workbook contains the crucial but not exhaustive data for ammonia catalysts and absorbents as presented in the associated publication. This dataset is intended to be supplementary to the associated publication rather than self-contained. Fig 1d,1e,3c: This excel sheet contains the data for testing of the catalyst Ru/Cs/CeO2 with varying N2:H2 ratios. In addition to three profiles of conversion with temperature, equilibrium lines and the best fit kinetic model are included. Details of the kinetic model can be found in the associated article. Also included are the conversion profiles with temperature for several other catalysts. All catalysts were tested at 21 barg in a flow reactor where the data measurement consisted of the change of flow through the system due to reaction. Fig2c: This sheet contains the condensed data for comparison of three ammonia absorbents. The absorbents are compared in terms of the amount of ammonia removed per gram absorbent per pressure of ammonia over time. Further details of the absorbent characteristics can be found in the associated article. Fig2d: this sheet contains the performance data for the absorbent MnCl2/SiO2 at four different temperatures over time. The absorbent performance is measurement by the amount of ammonia removed per gram of absorbent. Also included in this sheet are the best fit model for absorption kinetics. Details about the kinetic model can be found in the associated article. Fig3b 1-3 to 2-1: These sheets contain the data for a combined catalyst and absorbent system in which at time zero gas flow from a catalyst bed is diverted to an absorbent bed and second catalyst bed in series. The change in flow with time is a measurement of the amount of ammonia absorbed/produced. The three sheets are divided according to the ratio of N2:H2 (1:3, 1:1, 2:1). Also included in these sheets are the model predictions when utilizing the previously determined kinetic models for catalyst and absorbent independently. Details of the experimental/kinetic methodology can be found in the associated publication. 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
Impact Provides information about catalysis and absorbents for ammonia synthesis used by other researchers in their models. 
URL https://www.repository.cam.ac.uk/handle/1810/318030
 
Description Prof Geoff Moggridge 
Organisation University of Cambridge
Department Department of Chemical Engineering and Biotechnology
Country United Kingdom 
Sector Academic/University 
PI Contribution The group is an expert in reactor design and process integration providing additional expertise on the thermodynamics governing the synthesis of green ammonia.
Collaborator Contribution Prof Geoff Moggridge is an expert on thermodynamics and he is providing useful insights on some of the scientific challenges we are facing in some of the projects related to the synthesis of green ammonia. He is an advisor of some of the members in the group and he is involved in scientific discussion.
Impact This collaboration has resulted in a joint UKIR grant as part of the New Horizons 2021 call entitled "A paradigm shift in nitrogen activation for green ammonia synthesis" where we are investigating new routes for the synthesis of green ammonia
Start Year 2022
 
Description BBC 1 Feature 
Form Of Engagement Activity A broadcast e.g. TV/radio/film/podcast (other than news/press)
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact Joseph El Kadi and Collin Smith were featured on BBC One igniting hydrogen balloons in the lead-up to their interactive Cambridge Festival talk 'Fuel of the Future' which discusses the potential of ammonia to serve as a future fuel or energy vector in a carbon-free society
Year(s) Of Engagement Activity 2021
 
Description Cambridge Festival - NH3 Energy For the Future 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact Presentation on the future role of ammonia as a carbon-free energy vector followed by hydrogen ballon ignition demonstration to show amount of energy stored in a few millilitres of ammonia
Year(s) Of Engagement Activity 2021,2022,2023,2024
 
Description Chelmsford Science and Engineering Society talk 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Professional Practitioners
Results and Impact Green ammonia for a carbon-free society presentation given to Chelmsford Society active since 1920 with older members with industrial experience as well as early career individuals
Year(s) Of Engagement Activity 2023
 
Description Decarbonising Fuels industrial workshop 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact we presented an overview on our work with ammonia and we participated in workshop involving brainstorming, facilitating collaborations and identifying key challenges and bottlenecks
Year(s) Of Engagement Activity 2023