| Description |
Data files contain the raw data for the Figures in the manuscript and SI. Fig2a contains the raw SAXS XY data for bulk LLC phases of MO-water (20 wt%), MO-C6AzoC4E4 (20 wt%)-water (20 wt%) and MO-C8AzoC8E4 (20 wt%)-water (20 wt%). Columns are q (Å-1), intensity (C6AzoC4E4), intensity (C8AzoC8E4) and intensity (MO). Fig2b contains the POM micrograph for a bulk LLC phase of MO- C6AzoC4E4 (20 wt%)-water (20 wt%). Fig 2c contains the POM micrograph for a bulk LLC phase of MO- C8AzoC8E4 (20 wt%)-water (20 wt%). $$ \ $$ Fig3a contains the cryo-TEM micrograph for a dispersion of MO-water (20 wt%). The scale bar indicates 100 nm. Fig3b contains the cryo-TEM micrograph for a dispersion of MO-C6AzoC4E4 (20 wt%)-water (20 wt%). The scale bar indicates 100 nm. Fig3c contains the raw SAXS XY data for dispersions containing MO-water (20 wt%), MO-C6AzoC4E4 (10 wt%)-water (20 wt%) and MO-C8AzoC8E4 (10 wt%)-water (20 wt%) at 25 °C. Columns are q (Å-1), intensity (MO), intensity (C6AzoC4E4) and intensity (C8AzoC8E4). Fig 3d contains the raw SAXS XY data for dispersions containing MO-C8AzoC8E4-water of varying concentration of C8AzoC8E4 and water. Columns are q (Å-1) and intensity for: 10 wt% water, 10 wt% C8AzoC8E4; 20 wt% water, 10 wt% C8AzoC8E4; 30 wt% water, 10 wt% C8AzoC8E4; 40 wt% water, 10 wt% C8AzoC8E4; 20 wt% water, 20 wt% C8AzoC8E4; 20 wt% water, 0 wt% C8AzoC8E4; 20 wt% water, 30 wt% C8AzoC8E4. Fig3e contains the XY data for lattice parameter vs. initial water concentration and AzoPS concentration. Columns are: initial water concentration (wt%); lattice parameter - C6AzoC4E4 (Å); y error; lattice parameter - C8AzoC8E4 (Å); y error; AzoPS concentration (wt%); lattice parameter - C6AzoC4E4 (Å); y error; lattice parameter - C8AzoC8E4 (Å); y error. $$ \ $$ Fig4 contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C8AzoC8E4 (20 wt%)-water (10 wt%) diluted to 69 µM. Columns are: wavelength (nm) and absorbance on storage in the dark, irradiation at 365 nm, irradiation at 450 nm. $$ \ $$ Fig5a contains the raw SAXS XY data for dispersions containing MO-C8AzoC8E4-water (20wt%) on increasing C8AzoC8E4 concentration in the trans and cis states. Columns are q (Å-1) and intensity for: trans, 10 wt% C8AzoC8E4; trans, 20 wt% C8AzoC8E4; trans, 30 wt% C8AzoC8E4; cis, 10 wt% C8AzoC8E4; cis, 20 wt% C8AzoC8E4; cis, 30 wt% C8AzoC8E4. Fig5b contains the XY data for lattice parameter vs. initial water concentration for MO-AzoPS (10 wt%) -water dispersions in the trans and cis states. Columns are: initial water concentration (wt%); lattice parameter - trans, C6AzoC4E4 (Å); y error; lattice parameter - cis, C6AzoC4E4 (Å); y error; lattice parameter - trans, C8AzoC8E4 (Å); y error; lattice parameter - cis, C8AzoC8E4 (Å); y error. Fig5c contains the XY data for lattice parameter vs. AzoPS concentration for MO-AzoPS-water (20 wt%) dispersions in the trans and cis states. Columns are: AzoPS concentration (wt%); lattice parameter - trans, C6AzoC4E4 (Å); y error; lattice parameter - cis, C6AzoC4E4 (Å); y error; lattice parameter - trans, C8AzoC8E4 (Å); y error; lattice parameter - cis, C8AzoC8E4 (Å); y error. $$ \ $$ Fig6a contains contains the cryo-TEM micrograph for a dispersion of MO MO-C6AzoC4E4 (20 wt%)-water (20 wt%) in the cis state. The scale bar indicates 100 nm. Fig6b contains the cryo-TEM micrograph for a dispersion of MO-C8AzoC8E4 (20 wt%)-water (20 wt%) in the cis state. The scale bar indicates 100 nm. Fig6c contains the XY data for the hydrodynamic diameter (nm) and PDI vs. AzoPS concentration in MO- C6AzoC4E4-water (20wt%) dispersions in the trans and cis states. Columns are: AzoPS concentration (wt%); DH - trans; DH - cis; PDI - trans; PDI - cis; DH error - trans; PDI error - trans. $$ \ $$ Fig7a contains the XY data for the fluorescence spectra for a reference MO-water (20 wt%) dispersion and MO- C8AzoC8E4 (30 wt%)-water (20 wt%) dispersion, both loaded with Nile Red, before and after 3 min of UV irradiation. Columns are: wavelength (nm); intensity (reference, before UV); intensity (reference, after UV); intensity (C8AzoC8E4, before UV); intensity (C8AzoC8E4, after UV). Fig7b contains the data for emission intensity at 640 nm vs. time (minutes) after dispersion for a sample of MO- C8AzoC8E4 (30 wt%)-water (20 wt%) in the trans and cis states. Columns are: time, for trans (min); intensity, trans; time, for cis (min); intensity, cis. $$ \ $$ FigS1 contains POM micrographs for bulk LLC phases of MO and (a) 10 wt%, (b) 20 wt% and (c) 40 wt% water. FigS2 contains the raw SAXS XY data for the LLC phase formed from MO in excess water. Columns are q (Å-1) and intensity. FigS3 contains the example correlation data and cumulants fit plots used to calculate the Z-average hydrodynamic diameter and polydispersity index for a MO-C8AzoC8E4 (10 wt%)-water (10 wt%) dispersion. FigS4 contains photographs of LLC dispersions with varying initial water and AzoPS concentrations on storage in the dark for 10 months. FigS5 contains the cryo-TEM micrograph for a dispersion of MO-C8AzoC8E4 (10 wt%)-water (10 wt%) dispersion. The scale bar indicates 100 nm. FigS6 contains the raw SAXS XY data for dispersions of MO with varying initial water concentrations. Columns are q (Å-1) and intensity for: 10, 20, 30 and 40 wt% initial water. FigS7 contains the raw SAXS XY data for dispersions containing MO-C6AzoC4E4-water of varying concentration of C6AzoC4E4 and water. Columns are q (Å-1) and intensity for: 10 wt% water, 10 wt% C6AzoC4E4; 20 wt% water, 10 wt% C6AzoC4E4; 30 wt% water, 10 wt% C6AzoC4E4; 40 wt% water, 10 wt% C6AzoC4E4; 20 wt% water, 20 wt% C6AzoC4E4; 20 wt% water, 30 wt% C6AzoC4E4; 20 wt% water, 0 wt% C6AzoC4E4. FigS8a contains the XY data from the SAXS for plots of ln(I(q)) vs. q2 (Å-2) for dispersions of MO with varying initial water concentration. Columns are q2 (Å-2); ln(I(q)) for initial water concentrations of 10 wt%, y error, 20 wt%, y error, 30 wt%, y error, 40 wt%, y error. FigS8b contains the XY data from the SAXS for plots of ln(I(q)) vs. q2 (Å-2) for dispersions of MO-C6AzoC4E4-water (20 wt%) with varying C6AzoC4E4 concentration. Columns are q2 (Å-2); ln(I(q)) for C6AzoC4E4 concentrations of 10 wt%, y error, 20 wt%, y error, 30 wt%, y error. FigS9 contains the raw SAXS XY data for repeat dispersions containing MO-AzoPS (30 wt%)-water (20wt%). Columns are q (Å-1) and intensity for: C6AzoC4E4 repeats 1, 2 and 3; C8AzoC8E4 repeats 1, 2 and 3. FigS10a contains the raw SAXS XY data for dispersions containing MO- C6AzoC4E4 (30 wt%)-water (20wt%) at increasing temperatures. Columns are q (Å-1) and intensity for: 25, 35, 45 and 55 °C. FigS10b contains the raw SAXS XY data for dispersions containing MO- C8AzoC8E4 (30 wt%)-water (20wt%) at increasing temperatures. Columns are q (Å-1) and intensity for: 25, 35, 45, 55 °C and on cooling to 25 °C. FigS11a contains the XY data for the UV-Vis absorption spectra of C6AzoC4E4 in solution (57 µM); an MO-C6AzoC4E4 (20 wt%)-water (10 wt%) dispersion (69 µM); and, an MO-water (20 wt%) dispersion (46 µM). Columns are: wavelength (nm); absorbance for C6AzoC4E4 in dispersion; C6AzoC4E4 in solution; MO dispersion. FigS11b contains the XY data for the UV-Vis absorption spectra of C8AzoC8E4 in solution (68 µM); an MO-C8AzoC8E4 (20 wt%)-water (10 wt%) dispersion (69 µM); and, an MO-water (20 wt%) dispersion (46 µM). Columns are: wavelength (nm); absorbance for C8AzoC8E4 in dispersion; C8AzoC8E4 in solution; MO dispersion. FigS12 contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C6AzoC4E4 (20 wt%)-water (10 wt%) diluted to 69 µM. Columns are: wavelength (nm) and absorbance on storage in the dark, irradiation at 365 nm, irradiation at 450 nm. FigS13a contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C6AzoC4E4 (20 wt%)-water (10 wt%) diluted to 69 µM, as a function of time irradiated with UV (365 nm) light. Columns are: wavelength and absorbance at increasing time stamps (s). FingS13a_2 contains the XY data for UV irradiation time (s) vs. ln(A0-APSS)/(At-APSS) for a dispersion of MO- C6AzoC4E4 (20 wt%)-water (10 wt%) diluted to 69 µM. FigS13b contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C6AzoC4E4 (20 wt%)-water (10 wt%) diluted to 69 µM, as a function of time irradiated with blue (450 nm) light after 5 minutes of initial UV irradiation. Columns are: wavelength and absorbance at increasing time stamps (s). FigS13b_2 contains the XY data for blue irradiation time (s) vs. ln(A0-APSS)/(At-APSS) for a dispersion of MO- C6AzoC4E4 (20 wt%)-water (10 wt%) diluted to 69 µM. FigS14a contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C8AzoC8E4 (20 wt%)-water (10 wt%) diluted to 69 µM, as a function of time irradiated with UV (365 nm) light. Columns are: wavelength and absorbance at increasing time stamps (s). FigS14a_2 contains the XY data for UV irradiation time (s) vs. ln(A0-APSS)/(At-APSS) for a dispersion of MO- C8AzoC8E4 (20 wt%)-water (10 wt%) diluted to 69 µM. FigS14b contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C8AzoC8E4 (20 wt%)-water (10 wt%) diluted to 69 µM, as a function of time irradiated with blue (450 nm) light. Columns are: wavelength and absorbance at increasing time stamps (s). FigS14b_2 contains the XY data for blue irradiation time (s) vs. ln(A0-APSS)/(At-APSS) for a dispersion of MO- C8AzoC8E4 (20 wt%)-water (10 wt%) diluted to 69 µM. FigS15 contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C6AzoC4E4 (20 wt%)-water (10 wt%) as a function of time stored in the dark after 5 minutes of initial UV irradiation. Columns are: wavelength (nm), absorbance in the native, trans state and at increasing time stamps after UV irradiation (days). FigS15_2 contains the XY data for time stored in the dark (s) vs. ln(A0-APSS)/(At-APSS) for a dispersion of MO- C6AzoC4E4 (20 wt%)-water (10 wt%) diluted to 69 µM. FigS16 contains the XY data for the UV-Vis absorption spectra of a dispersion of MO- C8AzoC8E4 (20 wt%)-water (10 wt%) as a function of time stored in the dark after 5 minutes of initial UV irradiation. Columns are: wavelength (nm), absorbance in the native, trans state and at increasing time stamps after UV irradiation (days). FigS16_2 contains the XY data for time stored in the dark (s) vs. ln(A0-APSS)/(At-APSS) for a dispersion of MO- C8AzoC8E4 (20 wt%)-water (10 wt%) diluted to 69 µM. FigS17 contains the raw XY SAXS data for dispersions of MO- C6AzoC4E4 (10 wt%)-water with increasing concentration of initial water in the trans and cis states. Columns are: q (Å-1) and intensity for: trans, 10 wt%; trans, 20 wt%; trans, 30 wt%; trans, 40 wt%; cis, 10 wt%: cis, 20 wt%: cis, 30 wt%: cis, 40 wt%. FigS18 contains the raw XY SAXS data for dispersions of MO- C6AzoC4E4- water (20 wt%) with increasing concentration of C6AzoC4E4 in the trans and cis states. Columns are: q (Å-1) and intensity for: trans, 10 wt%; trans, 20 wt%; trans, 30 wt%; cis, 10 wt%: cis, 20 wt%: cis, 30 wt%. FigS19 contains the raw XY SAXS data for dispersions of MO- C8AzoC8E4 (10 wt%)-water with increasing concentration of initial water in the trans and cis states. Columns are: q (Å-1) and intensity for: trans, 10 wt%; trans, 20 wt%; trans, 30 wt%; trans, 40 wt%; cis, 10 wt%: cis, 20 wt%: cis, 30 wt%: cis, 40 wt%. FigS20 contains the raw SAXS XY data for repeat dispersions containing MO-AzoPS (30 wt%)-water (20wt%) in the cis state. Columns are q (Å-1) and intensity for: C6AzoC4E4 repeats 1, 2 and 3; C8AzoC8E4 repeats 1, 2 and 3. Text files can be opened with any text editor. PNG or JPEG or TIFF files can be opened with any imaging editor |
