High-efficiency Hybrid Solar Cells for Micro-generation
Lead Research Organisation:
The University of Manchester
Department Name: Chemistry
Abstract
Widespread implementation of photovoltaic electricity to meet changing energy demands requires a step-change in the cost of photovoltaic power. This proposal assembles a consortium of chemists, physicists, materials scientists and electrical engineers from The University of Manchester and Imperial College London to address this need through the development of new low-cost, high-efficiency, demonstration solar cells for micro-generation.We propose new designs for hybrid organic/inorganic devices which integrate flexibility and stability with inexpensive materials and solution based processing. In one design, semiconductor quantum dots (QDs) are used as the light absorber at the interface between a high mobility organic hole transporter and an array of directed metal oxide nano-rods, which act as the electron transporter. Independent optimisation of the optical and electronic properties will lead to design rules for maximising power conversion efficiency. In a second design, hybrid polymer/QD blend solar cells with novel metal oxide electrodes will be optimised. This proposal combines new approaches for ultra high efficiency with ultra low cost in the same device concept for the first time. Our aim is to construct affordable demonstration hybrid solar cells that could be mass-produced with long-term potential to achieve energy conversion efficiency of 10%.
Publications

Akhtar J
(2010)
A greener route to photoelectrochemically active PbS nanoparticles
in Journal of Materials Chemistry

Akhtar J
(2011)
Morphology-Tailored Synthesis of PbSe Nanocrystals and Thin Films from Bis[ N , N -diisobutyl- N' -(4-nitrobenzoyl)selenoureato]lead(II)
in European Journal of Inorganic Chemistry

Binks D
(2011)
Multiple exciton generation in nanocrystal quantum dots - controversy, current status and future prospects
in Physical Chemistry Chemical Physics

Hardman SJ
(2011)
Electronic and surface properties of PbS nanoparticles exhibiting efficient multiple exciton generation.
in Physical chemistry chemical physics : PCCP

Horie M
(2010)
Cyclopentadithiophene based polymers-a comparison of optical, electrochemical and organic field-effect transistor characteristics
in Journal of Materials Chemistry

Jackman MJ
(2014)
Adsorption of dopamine on rutile TiO2 (110): a photoemission and near-edge X-ray absorption fine structure study.
in Langmuir : the ACS journal of surfaces and colloids

Saunders BR
(2012)
Hybrid polymer/nanoparticle solar cells: preparation, principles and challenges.
in Journal of colloid and interface science

Stubbs S
(2010)
Efficient carrier multiplication in InP nanoparticles
in Physical Review B
Description | Several papers were published by the team in leading Journals including J. Amer. Chem. Soc. These have been well cited and influential we developed especially with Haque at IC a better understanding of the dynamics of electron transfer in type 3 cells involving quantum dots. And we also with Saunders started to understand better the aggregation of nanomaterials with in polymer matrices. These successes have led to subsequent grant funding from EPSRC. |
Exploitation Route | At present 2016 we continue to work in this area and continue to make breakthroughs with luck some of these will be comercially exploitable |
Sectors | Energy |
Description | Many public lectures on Solar energy presented by POB. He was also an Senior Fellow in the Institute of Advanced studies in this area. Has published highly cited reviews and edited volumes building on this work. |
First Year Of Impact | 2011 |
Sector | Energy |
Impact Types | Cultural Societal Economic Policy & public services |