BLOG-H (using a Battolyser to produce LOw cost Green Hydrogen)

Lead Research Organisation: Loughborough University
Department Name: Wolfson Sch of Mech, Elec & Manufac Eng

Abstract

Earlier this year, the UK government in keeping with many other nations laid out its hydrogen strategy plan. This equates to a target of 5GW of low carbon hydrogen production by 2030. Presently, the most common production route for hydrogen is steam methane reformation. Hydrogen can also be produced through electrolysis of which there are four main types; alkaline, PEM, Anion exchange membranes and solid oxide. The Anion exchange membrane is currently <5000 hours life span and the solid oxide electrolyser has a stack capital cost that exceeds £1500/kWe. The alkaline electrolyser is cheaper at a stack cost of £200/kWe and the PEM is close to £300/kWe. The total cost including balance of plant is closer to £700-£1000/kWe including rectifiers, H2 purification, water supply and purification and cooling. Most units are manufactured at around 1MW, however, there are plans for a 20MW trial unit.

The government has also pledged to move to 100% renewable energy and therefore to meet the technical requirements around electricity grid stability including meeting winter peak at times of low wind, additional capacity renewable generation needs to be installed. Instead of curtailing a wind farm due to grid based operational constraints, the energy produced as part of this can be used to produce hydrogen at minimal extra operating cost. The cost of the hydrogen therefore depends on the capital costs of the technology, storage and transport. If there is ample free electricity, for which there is little other use, then the efficiency of the hydrogen producing is less of an issue than its cost.

This proposal looks at using an alternative and complimentary technology to electrolysers to achieve this; the battolyser. A battolyser is a battery/electrolyser combined and is based on aqueous flow battery technology. Because it is pre-designed for battery functionality too, the electrodes may be more stable than those in an electrolyser. Flow batteries are being designed in scales of up to 100MW, 500MWh compared to Electrolysers at a planned 20MW and therefore there is good potential to scale up battolyser technology quickly once it passes early stage TRL hurdles. Additional advantages of a battolyser include the use of low hazard chemicals and the higher availability of materials used in manufacture. There is also additional potential to link into existing recycling facilities helping with long term sustainability planning.

As the battolyser is a single device which can produce both electricity and hydrogen it has the potential to be more economically viable than an electrolyser because of the multiple value streams.
This project will research the potential of a battolyser to produce low cost green hydrogen. The project aims to show that this is both financially viable and technically possible by modelling, prototyping and characterising a green hydrogen producing battolyser in conjunction with an offshore wind farm. The team based at the Centre for Renewable Energy Systems Technologies (CREST) at Loughborough University will be joined by wind farm experts from Strathclyde University and partner companies FibreTech, Arenko and SSE to complete this research into zero emission hydrogen.
 
Description We have been researching different chemistry combinations that allow a mixture of battery and electrolysis functionality. We have discovered several new battery-electrolysers and that have good durability. The most notable one is lead-vanadium because it allows for very deep discharge. This has been running for 5months on durability test and >500 cycles on test. Results still to be published as the cell has not yet failed. As part of this we have discovered a low cost method of producing iron and hydrogen through electrolysis.
Exploitation Route Both key findings above should be taken forward to larger prototype scale. More research is required before a demonstrator project.
Sectors Chemicals

Energy

Manufacturing

including Industrial Biotechology

 
Description The work has been showcased at a science festival to help inform the public about green hydorgen
First Year Of Impact 2023
Sector Education
Impact Types Societal

 
Description Fibre Technology - Loughborough University KTP Programme KTP13592
Amount £201,295 (GBP)
Funding ID KTP13592 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 01/2024 
End 06/2026
 
Title Blog H technoeconomic analysis spreadsheet 
Description Allows techno-economic studies of battery-electrolysers and batteries and electrolysers to be connected to windfarms of different type and size 
Type Of Material Computer model/algorithm 
Year Produced 2023 
Provided To Others? Yes  
Impact Delft University have been using this model 
 
Description Supergen energy networks conference 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Poster session to discuss our research on BlogH
Year(s) Of Engagement Activity 2023
URL https://www.ncl.ac.uk/supergenenhub/events/supergenenergynetworksconference/supergenenergynetworksco...
 
Description Winter hydrogen school HYDEX visit 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Gave a tour of our research laboratory
Year(s) Of Engagement Activity 2024
 
Description iMech visit Nov 2023 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Professional Practitioners
Results and Impact We gave a talk and visit based on the blogH research
Year(s) Of Engagement Activity 2023