Bio-fabrication of sustainable functional bacterial cellulose aerogel for building insulation
Lead Research Organisation:
Northumbria University
Department Name: Fac of Health and Life Sciences
Abstract
Climate change is undoubtedly the greatest challenge of our generation. The World Green Building Council is catalysing the construction and property industry to lead the transition to a net zero carbon-built environment. In the UK, the operation of buildings accounts for around 30 percent of emissions, mainly from heating, cooling and electricity use. Heating and cooling in buildings accounts for over 10% of global energy consumption. There is an increasing emphasis on energy efficiency and cutting carbon emissions from our homes and workplaces. The UK Government is keen to see energy efficiency in buildings improved and various initiatives and schemes offered for insulating domestic homes for building energy improvements. However, industrial synthetic insulation materials, such as polystyrene and polyurethane, dominate the building insulation industry. They are oil based polymerised polystyrene and the manufacturing of those materials is an energy intensive process. Moreover, all the synthetic insulation foams are not vapour permeable, which can cause dampness as well as decay in the wall. Some of them will release toxic hydrogen cyanide and isocyanates during a fire. Although interest in the use of bio-based insulation products is steadily increasing, the efficient thermal insulation renewable or biobased materials such as wood chips and sheep wools and recycled paper are generally inferior to that of fossil fuel-based materials such as expanded polystyrene and polyurethane foams. To meet the demand for a sustainable and net zero carbon building industry, there is a pressing need for innovative insulation materials that would facilitate low energy consumption and a minimal impact on the environment.
This NIA proposal is to make breakthroughs in how to use renewable and degradable resources to replace petroleum derivatives production technology, reduce environmental damage, and achieve sustainable development. This proposal is a first step to transform the manufacture of building insulating materials using biotechnology to develop novel cellulose-based aerogel to reduce fossil energy demand and contribute to net zero carbon buildings. The fundamental challenge is to develop novel low cost and low energy intensive ambient drying methods to produce functional bacterial cellulose aerogels with flame retardant, insulation, and anti-bacterial properties, which will have key applications in the field of construction materials. The low cost and low energy intensive drying method using sodium bicarbonate will be studied. The effect of the processing and in particular, the challenges related to the removal of the solvent to generate low-density foams and aerogels on heat transfer properties will be investigated.
An In-situ adaptive modification approach will be applied to address the challenges for using bacterial cellulose aerogel by incorporating functional chitosan in building insulation applications to provide the desired photo-catalytic self-cleaning, antibacterial and flame retardant properties. The interdisciplinary nature of proposal will build a real network for Bioengineering, building physics and Industry partners to work together and conduct research outside of their own discipline area to create a new generation of renewable and degradable bio-cellulose aerogel for energy efficient building. This research is currently at proof-of-concept stage and has high potential for impact with a wide array of applications in the future. This approach will enable the manufacture of insulation materials utilising waste, with little energy input and in ways which are carbon sequestering and non-polluting. It has enormous potential to produce renewable thermally insulating materials with significantly better heat transport properties than the currently commercially dominating materials such as expanded polystyrene, polyurethane foams, and glass wool.
This NIA proposal is to make breakthroughs in how to use renewable and degradable resources to replace petroleum derivatives production technology, reduce environmental damage, and achieve sustainable development. This proposal is a first step to transform the manufacture of building insulating materials using biotechnology to develop novel cellulose-based aerogel to reduce fossil energy demand and contribute to net zero carbon buildings. The fundamental challenge is to develop novel low cost and low energy intensive ambient drying methods to produce functional bacterial cellulose aerogels with flame retardant, insulation, and anti-bacterial properties, which will have key applications in the field of construction materials. The low cost and low energy intensive drying method using sodium bicarbonate will be studied. The effect of the processing and in particular, the challenges related to the removal of the solvent to generate low-density foams and aerogels on heat transfer properties will be investigated.
An In-situ adaptive modification approach will be applied to address the challenges for using bacterial cellulose aerogel by incorporating functional chitosan in building insulation applications to provide the desired photo-catalytic self-cleaning, antibacterial and flame retardant properties. The interdisciplinary nature of proposal will build a real network for Bioengineering, building physics and Industry partners to work together and conduct research outside of their own discipline area to create a new generation of renewable and degradable bio-cellulose aerogel for energy efficient building. This research is currently at proof-of-concept stage and has high potential for impact with a wide array of applications in the future. This approach will enable the manufacture of insulation materials utilising waste, with little energy input and in ways which are carbon sequestering and non-polluting. It has enormous potential to produce renewable thermally insulating materials with significantly better heat transport properties than the currently commercially dominating materials such as expanded polystyrene, polyurethane foams, and glass wool.
Publications
Li T
(2023)
Advancing pressure sensors performance through a flexible MXene embedded interlocking structure in a microlens array
in Nano Research
Lu S
(2024)
A Cellulose/Chitosan Dual Cross-Linked Multifunctional and Resilient Hydrogel for Emergent Open Wound Management.
in Advanced healthcare materials
Qin Z
(2023)
A Simple and Effective Physical Ball-Milling Strategy to Prepare Super-Tough and Stretchable PVA@MXene@PPy Hydrogel for Flexible Capacitive Electronics.
in Small (Weinheim an der Bergstrasse, Germany)
Westlake JR
(2023)
Vanillin Cross-Linked Chitosan Film with Controlled Release of Green Tea Polyphenols for Active Food Packaging.
in ACS food science & technology
Description | A functional biopolymer hydrogel combined with 2D materials for flexible electronic applications |
Organisation | Fujian University of Technology |
Country | China |
Sector | Academic/University |
PI Contribution | The collaborative research project focuses on fabricating a novel super tough, stretchable, and self-healing conductive hydrogel utilizing a combination of polyvinyl alcohol (PVA), MXene nanosheets, and polypyrrole. As a consultant and contributor to this research, our primary role involves providing expert guidance and suggestions for material development and characterization. Our contributions to the project are multifaceted. Firstly, we offer valuable insights into the selection and synthesis of materials, taking into consideration their compatibility, mechanical properties, and conductive behavior. Through our expertise, we advise on the optimal formulation of the hydrogel composite, aiming to achieve the desired balance between toughness, stretchability, and self-healing capabilities. Furthermore, our involvement extends to the characterization of the fabricated hydrogel. We propose and assist in implementing comprehensive characterization techniques to assess key properties such as mechanical strength, conductivity, and self-healing efficiency. By employing advanced analytical methods, we aim to gain a thorough understanding of the structure-property relationships within the hydrogel composite, thereby facilitating further optimization and refinement. Overall, our consultancy and contributions play a pivotal role in driving the success of the collaborative research project, as we work closely with the team to push the boundaries of hydrogel technology and pave the way for transformative advancements in materials science and engineering. |
Collaborator Contribution | The contributions primarily revolve around experiment design, execution, testing of samples, and manuscript preparation. Researchers from the collaborating institutions collaborated closely to design experiments that would elucidate the synergistic effects of the components in the hydrogel formulation. This involved considering factors such as the concentration of each component, the method of incorporation, and the processing conditions to optimize the mechanical and electrical properties of the hydrogel. The experimental phase involved conducting the designed protocols. Each step, from the synthesis of the hydrogel to the incorporation of MXene nanosheets and polypyrrole, was carried out with precision and attention to detail. Collaboration ensured that the expertise of each team member was leveraged effectively to overcome challenges and achieve the desired outcomes. Once the hydrogel samples were fabricated, a battery of tests was conducted to evaluate their mechanical, electrical, and self-healing properties. This involved techniques such as tensile testing, electrical conductivity measurements, and assessment of self-healing capabilities under various conditions. The culmination of the collaborative effort was the preparation of a manuscript detailing the research findings. Contributions from all team members were integrated to provide a cohesive narrative of the experimental work, results, and implications. Through iterative revisions and discussions, the manuscript was refined to meet the standards of scientific rigor and excellence, ready for submission to peer-reviewed journals. |
Impact | https://doi.org/10.1002/smll.202303038 |
Start Year | 2023 |
Description | A versatile biopolymer (cellulose/Chitosan) for active packaging |
Organisation | University of Bath |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | We offered our expertise and resources in several key areas to support our research collaboration: Provision of Functional Chitosan/Cellulose Materials: Our team provided the functional chitosan/cellulose materials for the experiments. These materials were carefully prepared and tailored to meet the specific requirements of the research objectives. We ensured that the materials were of the highest quality and were provided in sufficient quantities to facilitate comprehensive testing and analysis. Antimicrobial and Antiviral Testing on Developed Functional Films: In addition to providing the functional materials, we conducted thorough antimicrobial and antiviral testing on the developed functional films. Our state-of-the-art laboratory facilities and experienced researchers executed these tests with precision and accuracy, following established protocols and methodologies. The results obtained from these tests provided valuable insights into the efficacy and performance of the films in inhibiting microbial and viral growth. Structured Comments on the Collaborative Paper: As part of our collaboration, we committed to providing structured comments and feedback on the collaborative paper. Our team reviewed the manuscript and offered constructive criticism for improving the paper. |
Collaborator Contribution | During this research collaboration, a dedicated PhD candidate (Bath University) played a pivotal role in advancing our understanding and applications of active films. Specifically, the PhD focused on the intricate process of casting active films by integrating polyphenol compounds into the matrix using crosslinking chitosan. This methodology not only ensured the successful incorporation of the active compounds but also enhanced the structural integrity and functional properties of the resulting films. Moreover, the PhD conducted comprehensive tests to evaluate the controlled release mechanisms employed within the films. Through experimentation and analysis, they elucidated the kinetics of release and optimized the formulation to achieve desired release profiles. Additionally, the PhD demonstrated remarkable proficiency in encapsulating polyphenols within the film matrix, thereby further enhancing the stability and efficacy of the active compounds. |
Impact | https://doi.org/10.1021/acsfoodscitech.3c00222 |
Start Year | 2023 |
Description | A versatile biopolymer integrated with 2D materials for diverse applications |
Organisation | Henan Agricultural University |
Country | China |
Sector | Academic/University |
PI Contribution | This interdisciplinary research effort involves materials scientists, chemists, and biologists collaborating to develop a functional bioadhesive hydrogel tape utilizing modified cellulose and chitosan biopolymers. Our contribution primarily focuses on advancing the study of functional biopolymers, particularly through the modification of cellulose and chitosan. We provided essential expertise and resources, offering invaluable advice and knowledge on hydrogels derived from chitosan and cellulose. Additionally, we extensively supported consultancy services, including detailed physical and chemical characterization of materials. |
Collaborator Contribution | Within the scope of our research collaboration, the institutes have been actively engaged in advancing our scientific activity. Their researchers focused on the development of innovative dual cross-linked multifunctional hydrogel using allyl cellulose and carboxymethyl chitosan. Furthermore, their researcher undertook comprehensive testing protocols to evaluate the performance of the developed hydrogel. the cytocompatibility and antibacterial activity of developed hydrogel were investigated in the lab. Through their diligent efforts and scientific acumen, the researchers have made significant strides in advancing our understanding of our adhesive hydrogel. |
Impact | https://doi.org/10.1002/adhm.202304676 |
Start Year | 2023 |
Description | Chemistry Expericne Week |
Form Of Engagement Activity | Participation in an open day or visit at my research institution |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Schools |
Results and Impact | As part of our research dissemination efforts, we showcased our project during the Chemistry Experience Week at Northumbria University. This event provided a platform for knowledge exchange and engagement with the broader community, particularly targeting local A-level students interested in chemistry. Our team had the privilege of delivering a comprehensive lecture, offering insights into the innovative aspects and significance of our research project. This lecture served to educate and inspire over 50 A-level students, providing them with a deeper understanding of the scientific principles and applications involved. In addition to the lecture, we organized a poster session held in the prestigious Great Hall. This session offered a more interactive and visually engaging experience for the attendees, allowing them to explore the nuances of our research in greater detail. Through vibrant posters and engaging discussions, we had the opportunity to share our findings and methodologies with enthusiastic students, sparking curiosity and fostering a passion for chemistry. Overall, our participation in the Chemistry Experience Week underscored our commitment to scientific outreach and education. By engaging with A-level students in both lecture and poster formats, we aimed to inspire the next generation of scientists and instill an appreciation for the wonders of chemistry. |
Year(s) Of Engagement Activity | 2024 |