Learning how to manipulate spins: EPR studies of anti-ferromagnetic rings and linked rings towards quantum computation
Lead Research Organisation:
The University of Manchester
Department Name: Chemistry
Abstract
Quantum information processing (QIP) sounds like science fiction. In a conventional computer information is stored in a bit which can either be a 0 or a 1, and processing information involves changing 0 to 1 or 1 to 0. In a quantum computer information would be stored as a Qubit which is a super-position of 0 and 1. An analogy would be that a classical bit is like a light switch, which is either on or off, while a Qubit is a dimmer switch set simultaneously to all possible positions. Many systems have been studied as possible Qubits , but at present no efficient means for QIP exists. This is because the physical requirements are very precise and matching all requirements simultaneously is very difficult. In our previous work we have shown that molecular species can be made which have many of the correct characteristics. In this interdisciplinary project between a chemistry group at Manchester and a condensed matter physics group at Oxford we will fully characterise a range of such molecules and examine their suitability for QIP. By this route we intend to demonstrate, at least at prototype level, molecules and addressing techniques that will allow QIP. If QIP can be made to work it allows some calculations to be performed quickly which would be impossibly slow using conventional computers, and hence it would be massive technological step forward.
Publications
Ardavan A
(2015)
Engineering coherent interactions in molecular nanomagnet dimers
Ardavan A
(2015)
Engineering coherent interactions in molecular nanomagnet dimers
in npj Quantum Information
Baker M
(2012)
A classification of spin frustration in molecular magnets from a physical study of large odd-numbered-metal, odd electron rings
in Proceedings of the National Academy of Sciences
Baker M
(2012)
Spin dynamics of molecular nanomagnets unravelled at atomic scale by four-dimensional inelastic neutron scattering
in Nature Physics
Faust TB
(2011)
Chemical control of spin propagation between heterometallic rings.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Faust TB
(2012)
Controlling magnetic communication through aromatic bridges by variation in torsion angle.
in Dalton transactions (Cambridge, England : 2003)
Fernandez A
(2015)
g-Engineering in Hybrid Rotaxanes To Create AB and AB2 Electron Spin Systems: EPR Spectroscopic Studies of Weak Interactions between Dissimilar Electron Spin Qubits.
in Angewandte Chemie (International ed. in English)
Kaminski D
(2014)
Quantum spin coherence in halogen-modified Cr 7 Ni molecular nanomagnets
in Physical Review B
Moro F
(2014)
Coherent electron spin manipulation in a dilute oriented ensemble of molecular nanomagnets: pulsed EPR on doped single crystals.
in Chemical communications (Cambridge, England)
Timco GA
(2013)
Physical studies of heterometallic rings: an ideal system for studying magnetically-coupled systems.
in Chemical Society reviews
| Description | We have performed fundamental studies that underpin the proposed use of magnetic molecules as components in molecular electronic devices or in logic operations. This has included studies of electron spin relaxation effects in large molecules, the embedding of these molecules in crystallines arrays, and their linking into larger supramolecular structures where we can measure and manipulate the interactions between them by pulsed EPR spectroscopies. |
| Exploitation Route | The work shows how molecules can be designed to give favourable electron spin properties for certain proposed applications. This is relevant to the ultimate proposed use of molecules in e.g. logic gates or other areas exploiting their quantum nature, and how they can be incorporated into larger complex materials. |
| Sectors | Chemicals Digital/Communication/Information Technologies (including Software) Electronics |
| Description | This is fundamental research in chemistry and physics whose primary impact has been in the academic sector, but has attracted some interest from industrial research labs. |