High-efficiency Hybrid Solar Cells for Micro-generation
Lead Research Organisation:
Imperial College London
Department Name: Physics
Abstract
Widespread implementation of photovoltaic electricity to meet changing energy demands requires a step-change in the cost of photovoltaic power. This proposal assembles a consortium of chemists, physicists, materials scientists and electrical engineers from The University of Manchester and Imperial College London to address this need through the development of new low-cost, high-efficiency, demonstration solar cells for micro-generation.We propose new designs for hybrid organic/inorganic devices which integrate flexibility and stability with inexpensive materials and solution based processing. In one design, semiconductor quantum dots (QDs) are used as the light absorber at the interface between a high mobility organic hole transporter and an array of directed metal oxide nano-rods, which act as the electron transporter. Independent optimisation of the optical and electronic properties will lead to design rules for maximising power conversion efficiency. In a second design, hybrid polymer/QD blend solar cells with novel metal oxide electrodes will be optimised. This proposal combines new approaches for ultra high efficiency with ultra low cost in the same device concept for the first time. Our aim is to construct affordable demonstration hybrid solar cells that could be mass-produced with long-term potential to achieve energy conversion efficiency of 10%.
Organisations
People |
ORCID iD |
Jenny Nelson (Principal Investigator) | |
James Durrant (Co-Investigator) |
Publications

Atienzar P
(2010)
Control of Photocurrent Generation in Polymer/ZnO Nanorod Solar Cells by Using a Solution-Processed TiO 2 Overlayer
in The Journal of Physical Chemistry Letters

Atienzar P
(2009)
Hybrid polymer-metal oxide solar cells by in situ chemical polymerization
in Journal of Materials Chemistry

Ben Dkhil S
(2017)
P-type semiconductor surfactant modified zinc oxide nanorods for hybrid bulk heterojunction solar cells
in Solar Energy Materials and Solar Cells

Dyer-Smith C
(2009)
The Effect of Ionization Potential and Film Morphology on Exciplex Formation and Charge Generation in Blends of Polyfluorene Polymers and Silole Derivatives
in The Journal of Physical Chemistry C

Haque SA
(2010)
Physics. Toward organic all-optical switching.
in Science (New York, N.Y.)

Leventis HC
(2010)
Transient optical studies of interfacial charge transfer at nanostructured metal oxide/PbS quantum dot/organic hole conductor heterojunctions.
in Journal of the American Chemical Society

Mawyin J
(2011)
Hybrid Heterojunction Nanorods for Nanoscale Controlled Morphology in Bulk Heterojunction Solar Cells
in The Journal of Physical Chemistry C

Ravirajan P
(2012)
Post-Processing Treatments in Hybrid Polymer/Titanium Dioxide Multilayer Solar Cells
in Journal of Nanoelectronics and Optoelectronics
Description | We have learnt how the properties of the organic and inorganic materials used in hybrid solar cells influence the solar cell performance. In particular, we showed how the treatment of the interface between the two components has a strong influence on performance. We applied new spectroscopic and materials preparation techniques to achieve the results. |
Exploitation Route | The experimental results and the characterisation techniques used will be relevant to other academic groups researching hybrid electronic materials, and could be of interest to industry. |
Sectors | Chemicals Electronics Energy Environment |
Description | EPSRC |
Amount | £83,656 (GBP) |
Funding ID | EP/I501053/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start |