The Flexible Fuel Cell
Lead Research Organisation:
Imperial College London
Department Name: Chemistry
Abstract
Fuel Cells have a problem.The current geometrical design of common fuel cells is not fault tolerant and requires all components to operate in an almost ideal manner. This is because each power generating unit in a fuel cell stack is connected in series: the weakest link in the fuel cell chain dictates performance and reliability. Put simply: if a fuel cell is like a string of batteries all connected in a line, then that fuel cell can only operate as well as the worst performing of all of the batteries. If one of the batteries fails, then the entire fuel cell fails. This means that each battery (or membrane electrode assembly in the fuel cell case) must be produced to very high standards. We need to make sure that none of them fail during the operational life of the fuel cell stack. This makes the fuel cell electrodes very difficult to produce and contributes significantly to their cost. But what if we could design a fuel cell stack so that we can switch out bad units and allow the fuel cell to continue operation?Such a fuel cell would then show fault tolerance and resilience to adverse environmental and internal influences. Indeed it might even be possible to nurse poorly performing electrodes, and coax them back to good health (or at least stop them from failing entirely). In a nut-shell, that is the purpose of this project - to radically redesign how fuel cells operate. This will allow us to have much greater control of the fuel cell operation compared to the configuration used almost exclusively everywhere else. An interesting by-product of the new design is that we can integrate the power control electronics directly with the fuel cell. This means that we can achieve significant space savings and a decrease in the cost of the controlling electronics. In order to produce this new type of fuel cell, we require a very tight coupling between both Chemistry and Chemical Engineering aspects of the work. The development of new types of electrodes is guided by some subtle chemistry associated with the production of 'through-membrane' connectors. The integration of those electrodes into a stack requires a radically different type of housing. Such work must be carefully guided by modelling and simulation, and the results need to be fed back to optimise the electrodes. Thus we require close cooperation between both chemists and engineers in order to ensure the success of the project. The research team will be assisted by four collaborating external partners. These collaborators will assist with the development of the fuel cell system and represent a balanced team representing the development chain: a technology transfer company (Imperial Innovations Ltd) who will manage the commercialisation of this work out of Imperial; an applications developer (Applied intellectual Capital) who will define the market and establish precise operational requirements; a materials supplier / developer (SPC Technologies Ltd) who will supply sample materials for use as flow fields and sealant material and contribute expertise on the processing of porous plastics; and a potential end user (The Defence Science and Technology Laboratory) who will test the robust lightweight design against requirements for infantry missions.
Publications
Daniels F
(2014)
Current collector design for closed-plenum polymer electrolyte membrane fuel cells
in Journal of Power Sources
Greenhalgh E
(2014)
Mechanical, electrical and microstructural characterisation of multifunctional structural power composites
in Journal of Composite Materials
Iden H
(2014)
Analysis of effective surface area for electrochemical reaction derived from mass transport property
in Journal of Electroanalytical Chemistry
Kalyvas C
(2015)
The Flexi Planar Fuel Cell
Lopes T
(2015)
Assessing the performance of reactant transport layers and flow fields towards oxygen transport: A new imaging method based on chemiluminescence
in Journal of Power Sources
Obeisun O
(2014)
Advanced Diagnostics Applied to a Self-Breathing Fuel Cell
in ECS Transactions
Obeisun O
(2014)
Development of open-cathode polymer electrolyte fuel cells using printed circuit board flow-field plates: Flow geometry characterisation
in International Journal of Hydrogen Energy
Rubio-Garcia J
(2018)
Hydrogen/manganese hybrid redox flow battery
in Journal of Physics: Energy
Description | We have developed a new type of fuel cell which can be manufactured using inexpensive technology. This fuel cell offers the possibility to radically reduce the cost of fuel cell systems. The technology has been spun out into a company |
Exploitation Route | Company has been formed based on the technology developed in this project - see url above |
Sectors | Electronics Energy |
URL | https://www.brambleenergy.com |
Description | The findings have been used to publish papers and give talks at conferences. We also have been successful in attracting further funding for the approach from our respective university technology transfer offices and the Carbon Trust. We also have been successful in obtaining funding from Innovate UK. As a result of furthermore, we have been able to spinout a company to take the approaches developed in this project further. That company is called Bramble Energy and Professor Kucernak is the CSO of that company and Professor Brett is Director of Innovation |
First Year Of Impact | 2013 |
Sector | Energy,Environment |
Impact Types | Economic |
Description | Carbon Trust Polymer fuel cell challenge |
Amount | £54,000 (GBP) |
Organisation | Carbon Trust |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start | 01/2012 |
End | 11/2014 |
Description | Development of a demonstrator for EP/G041792-1 |
Amount | £49,965 (GBP) |
Funding ID | P46013 |
Organisation | Imperial Innovations |
Sector | Private |
Country | United Kingdom |
Start | 01/2013 |
End | 07/2014 |
Description | Development of a demonstrator for EP/G041792-1 |
Amount | £49,965 (GBP) |
Funding ID | P46013 |
Organisation | Imperial Innovations |
Sector | Private |
Country | United Kingdom |
Start | 01/2013 |
End | 02/2014 |
Description | Fuel Cell Manufacturing & the Supply Chain |
Amount | £232,000 (GBP) |
Funding ID | P51890_CHIS |
Organisation | Innovate UK |
Sector | Public |
Country | United Kingdom |
Start | 09/2014 |
End | 09/2016 |
Description | Pathways to Impact - Development of a demonstrator for EP/G041792-1 |
Amount | £74,357 (GBP) |
Funding ID | P46012 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 01/2013 |
End | 07/2014 |
Description | Symbiotic |
Amount | € 3,000,000 (EUR) |
Funding ID | http://symbiotic-project.eu/project/ |
Organisation | European Commission H2020 |
Sector | Public |
Country | Belgium |
Start | 01/2016 |
End | 11/2018 |
Description | Bramble Energy |
Organisation | Bramble Energy Ltd |
Country | United Kingdom |
Sector | Private |
PI Contribution | We have contributed knowledge to better understand the operation of the fuel cells developed by Bramble |
Collaborator Contribution | Bramble Energy is a spinout and has contributed materials for testing within my research group |
Impact | Three patents |
Start Year | 2016 |
Description | Collaboration with Hydrogen and Fuel Cell Supergen |
Organisation | Hydrogen and Fuel Cell Supergen |
Country | United Kingdom |
Sector | Charity/Non Profit |
PI Contribution | H2FC is the hydrogen and fuel cell supergen. We have presented results at H2FC conferences and as Kucernak is a theme leader the results have been used to set the direction of future research |
Collaborator Contribution | Allow research to be seen by wider audience. |
Impact | Presentation of results at H2FC conferences |
Start Year | 2017 |
Description | Flexible fuel cell collaboration |
Organisation | Photomechanical servides |
Country | United Kingdom |
Sector | Private |
PI Contribution | None |
Collaborator Contribution | Photomechanical services has provided training and knowledge transfer in the area of printed circuitboard production |
Impact | Better deposition of corrosion protection layers in fuel cells |
Start Year | 2009 |
Title | CORROSION PROTECTION COATING |
Description | An electrically conductive composite coating comprises a layer of an electrically conductive coating material (101) comprising a carbon-based material and an azole corrosion inhibitor; and a layer of tin or a tin alloy (102), such as tin-antimony (Sn-6wt%Sb) alloy. The coating material may include an organic binder. The coating may be used to protect a component (100) in an electrochemical device such as a fuel cell assembly, a battery, a redox flow battery, an electrolyser or a supercapacitor. The coating shows no significant sign of corrosion after 9 days in accelerated long term corrosion tests in an aggressive environment. |
IP Reference | WO2017212295 |
Protection | Patent application published |
Year Protection Granted | 2017 |
Licensed | Yes |
Impact | Patent licensed to Bramble energy |
Title | ELECTRICALLY CONDUCTIVE COMPOSITE CORROSION PROTECTION COATING |
Description | An electrically conductive composite coating comprises a layer of an electrically conductive coating material (101) comprising a carbon-based material and an azole corrosion inhibitor; and a layer of tin or a tin alloy (102), such as tin-antimony (Sn-6wt%Sb) alloy. The coating material may include an organic binder. The coating may be used to protect a component (100) in an electrochemical device such as a fuel cell assembly, a battery, a redox flow battery, an electrolyser or a supercapacitor. The coating shows no significant sign of corrosion after 9 days in accelerated long term corrosion tests in an aggressive environment. |
IP Reference | CA3026384 |
Protection | Patent application published |
Year Protection Granted | 2017 |
Licensed | Yes |
Impact | Patent licensed to fuel cell company, Bramble Energy |
Title | FUEL CELL |
Description | A fuel cell assembly is disclosed comprising a fuel cell electrode component and a reactant gas flow component ink bonded thereto. In one aspect direct bonding of a gas diffusion layer with a flow field is achieved allowing a simplified structural configuration. In another aspect improved component printing techniques reduce corrosion effects. In a further aspect flow fields are described providing reactant channels extending in both the horizontal and vertical directions, i.e. providing three dimensional flow. In a further aspect an improved wicking material allows wicking away and reactant humidification. In a further aspect improved mechanical fastenings and connectors are provided. In a further aspect improved humidification approaches are described. Further improved aspects are additionally disclosed. |
IP Reference | WO2013164639 |
Protection | Patent granted |
Year Protection Granted | 2013 |
Licensed | Yes |
Impact | Patent has been licenced to the company "Bramble Energy" |
Title | FUEL CELL COMPRISING AT LEAST TWO STACKED PRINTED CIRCUIT BOARDS WITH A PLURALITY OF INTERCONNECTED FUEL CELL UNITS |
Description | A fuel cell comprising at least two stacked fuel cell boards (22) which each comprise a membrane of substantially gas impervious electrolyte material and at least two electrode pairs wherein the anode and cathode of each said electrode pair are arranged on respective faces of said membrane. An electrode of each pair of electrodes is connected to an electrode of an adjacent pair of electrodes by a through-membrane connection (13) or by an external connection on a Printed Circuit Board, comprising an electrically conductive region of said electrolyte material. A method for forming the through-membrane electrical connections in the electrolyte membrane is also disclosed. |
IP Reference | CA2828460 |
Protection | Patent application published |
Year Protection Granted | 2012 |
Licensed | Yes |
Impact | Fuel Cell company now using this patent to make fuel cells |
Title | FUEL CELL COMPRISING AT LEAST TWO STACKED PRINTED CIRCUIT BOARDS WITH A PLURALITY OF INTERCONNECTED FUEL CELL UNITS |
Description | A fuel cell comprising at least two stacked fuel cell boards (22) which each comprise a membrane of substantially gas impervious electrolyte material and at least two electrode pairs wherein the anode and cathode of each said electrode pair are arranged on respective faces of said membrane. An electrode of each pair of electrodes is connected to an electrode of an adjacent pair of electrodes by a through-membrane connection (13) or by an external connection on a Printed Circuit Board, comprising an electrically conductive region of said electrolyte material. A method for forming the through-membrane electrical connections in the electrolyte membrane is also disclosed. |
IP Reference | US2018233765 |
Protection | Patent application published |
Year Protection Granted | 2018 |
Licensed | Yes |
Impact | Patent licensed to Bramble Energy Ltd |
Title | FUEL CELL COMPRISING AT LEAST TWO STACKED PRINTED CIRCUIT BOARDS WITH A PLURALITY OF INTERCONNECTED FUEL CELL UNITS |
Description | A fuel cell comprising at least two stacked fuel cell boards (22) which each comprise a membrane of substantially gas impervious electrolyte material and at least two electrode pairs wherein the anode and cathode of each said electrode pair are arranged on respective faces of said membrane. An electrode of each pair of electrodes is connected to an electrode of an adjacent pair of electrodes by a through-membrane connection (13) or by an external connection on a Printed Circuit Board, comprising an electrically conductive region of said electrolyte material. A method for forming the through-membrane electrical connections in the electrolyte membrane is also disclosed. |
IP Reference | WO2012117035 |
Protection | Patent application published |
Year Protection Granted | 2012 |
Licensed | Yes |
Impact | Patent being used by company to manufacture systems |
Title | FUEL CELL COMPRISING AT LEAST TWO STACKED PRINTED CIRCUIT BOARDS WITH A PLURALITY OF INTERCONNECTED FUEL CELL UNITS |
Description | A fuel cell comprising at least two stacked fuel cell boards (22) which each comprise a membrane of substantially gas impervious electrolyte material and at least two electrode pairs wherein the anode and cathode of each said electrode pair are arranged on respective faces of said membrane. An electrode of each pair of electrodes is connected to an electrode of an adjacent pair of electrodes by a through-membrane connection (13) or by an external connection on a Printed Circuit Board, comprising an electrically conductive region of said electrolyte material. A method for forming the through-membrane electrical connections in the electrolyte membrane is also disclosed. |
IP Reference | WO2012117035 |
Protection | Patent granted |
Year Protection Granted | 2012 |
Licensed | Yes |
Impact | Patent has been licenced to fuel cell company "Bramble Energy" Patent granted in US 24.04.2018 |
Title | Fuel Cell Comprising at Least Two Stacked Printed Circuit Boards with a Plurality of Interconnected Fuel Cell Units |
Description | A fuel cell comprising at least two stacked fuel cell boards (22) which each comprise a membrane of substantially gas impervious electrolyte material and at least two electrode pairs wherein the anode and cathode of each said electrode pair are arranged on respective faces of said membrane. An electrode of each pair of electrodes is connected to an electrode of an adjacent pair of electrodes by a through-membrane connection (13) or by an external connection on a Printed Circuit Board, comprising an electrically conductive region of said electrolyte material. A method for forming the through-membrane electrical connections in the electrolyte membrane is also disclosed. |
IP Reference | US2014154604 |
Protection | Patent application published |
Year Protection Granted | 2014 |
Licensed | Yes |
Impact | used by company to produce fuel cells |
Title | Fuel cell |
Description | A fuel cell assembly is disclosed comprising a fuel cell electrode component and a reactant gas flow component ink bonded thereto. In one aspect direct bonding of a gas diffusion layer with a flow field is achieved allowing a simplified structural configuration. In another aspect improved component printing techniques reduce corrosion effects. In a further aspect flow fields are described providing reactant channels extending in both the horizontal and vertical directions, i.e. providing three dimensional flow. In a further aspect an improved wicking material allows wicking away and reactant humidification. In a further aspect improved mechanical fastenings and connectors are provided. In a further aspect improved humidification approaches are described. Further improved aspects are additionally disclosed. |
IP Reference | CN104488125 |
Protection | Patent application published |
Year Protection Granted | 2015 |
Licensed | Yes |
Impact | Patent being used by company to manufacture systems |
Title | Fuel cell comprising at least two stacked printed circuit boards with a plurality of interconnected fuel cell units |
Description | A fuel cell comprising at least two stacked fuel cell boards (22) which each comprise a membrane of substantially gas impervious electrolyte material and at least two electrode pairs wherein the anode and cathode of each said electrode pair are arranged on respective faces of said membrane. An electrode of each pair of electrodes is connected to an electrode of an adjacent pair of electrodes by a through-membrane connection (13) or by an external connection on a printed circuit board, comprising an electrically conductive region of said electrolyte material. A method for forming the through-membrane electrical connections in the electrolyte membrane is also disclosed. |
IP Reference | CN103620842 |
Protection | Patent application published |
Year Protection Granted | 2014 |
Licensed | Yes |
Impact | patent used to produce fuel cells by company |
Company Name | Bramble Energy |
Description | Bramble Energy develops and manufactures fuel cells using printed circuit board materials within established supply chains. |
Year Established | 2015 |
Impact | Early stage at the moment. |
Website | http://www.brambleenergy.com |
Description | Chief Scientific Officer of Bramble Energy Ltd |
Form Of Engagement Activity | A formal working group, expert panel or dialogue |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Industry/Business |
Results and Impact | Asked to be CSO of Bramble energy - spinout company formed due to this research. Attend monthly board meeting |
Year(s) Of Engagement Activity | 2016,2017,2018,2019 |
Description | Stand demonstrating technology at "The great exhibition rd festival", 2019 |
Form Of Engagement Activity | Participation in an open day or visit at my research institution |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Public/other audiences |
Results and Impact | Stand at the "Great Exhibition Rd festival in June 2019 |
Year(s) Of Engagement Activity | 2019 |
URL | https://www.greatexhibitionroadfestival.co.uk/whats-on/ |