Nanoparticulate mixed metal oxides as electrode materials for Alkaline Polymer Electrolyte Membrane Fuel Cells (APEMFCs)
Lead Research Organisation:
University of Surrey
Department Name: Div of Chemical Sciences
Abstract
Interest in fuel cells has dramatically increased in recent years with the realisation of the tremendous strain developing on world energy resources. This, coupled with environmental concerns regarding the need to reduce greenhouse gas emissions, places great emphasis on the development of efficient and environmentally friendly energy systems, such as fuel cells. Low temperature fuel cells typically have a polymer membrane as the electrolyte, and traditionally research in the area of acidic membranes has tended to dominate the fuel cell literature. More recently internationally pioneering research at the University of Surrey into the development of highly conducting alkaline polymer electrolyte membranes has led to world-wide interest in alkaline polymer electrolyte membrane fuel cells (APEMFCs). The use of alkaline membranes rather than traditional acidic membranes confers a number of significant advantages. In particular, such alkaline membranes offer the potential for replacing expensive precious metal (e.g. platinum) catalysts conventionally used with acidic membranes, with cheaper alternatives. The aim of this study is to investigate one such alternative, namely the potential of nanoparticulate mixed metal oxides as electrode materials for APEMFCs. The project will involve two complementary strands. In the first strand, the incorporation of the mixed metal oxides will be made with a view to reducing the level of precious metal catalysts needed, while the second more adventurous strand will involve the complete replacement of the precious metals. Both strategies offer the prospect for breakthrough reduction in the costs of these fuel cell systems.
Organisations
Publications


Hancock C
(2011)
Synthesis, structure and conductivity of sulfate and phosphate doped SrCoO3
in Journal of Solid State Chemistry

Hancock C
(2012)
Low temperature fluorination of Sr3Fe2O7-x with polyvinylidine fluoride: An X-ray powder diffraction and Mössbauer spectroscopy study
in Journal of Solid State Chemistry

Hancock CA
(2011)
Synthesis of silicon doped SrMO3 (M = Mn, Co): stabilization of the cubic perovskite and enhancement in conductivity.
in Dalton transactions (Cambridge, England : 2003)

Porras-Vazquez J
(2013)
Investigation into the effect of Si doping on the performance of SrFeO3-d SOFC electrode materials
in Journal of Materials Chemistry A
Related Projects
Project Reference | Relationship | Related To | Start | End | Award Value |
---|---|---|---|---|---|
EP/G009929/1 | 30/09/2008 | 31/12/2008 | £98,661 | ||
EP/G009929/2 | Transfer | EP/G009929/1 | 01/01/2009 | 29/04/2012 | £0 |
Description | 1. Demonstration of improved conductivity in perovskite electrode materials through silicate, phosphate doping. 2. Synthesis of new hydroxide catalysts through preparation of fluoride precursors and post-ion exchange. |
Exploitation Route | 1. Meet the Scientist Stand at the Thinktank Museum, Birmingham 2. How Science works hand-on activities at the Thinktank Museum, Birmingham Potential applications as electrode materials for use in low temperature fuel cells |
Sectors | Energy |
Description | Policy in Low Carbon Transport |
Policy Influence Type | Contribution to a national consultation/review |
Impact | Particpated in meeting, which fed recommendations to the G8 summit Target Audience: Government Department |
Description | Doping Studies of Perovskite-related Materials for Potential Applications as Fuel Cell Cathodes |
Form Of Engagement Activity | Scientific meeting (conference/symposium etc.) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Participants in your research or patient groups |
Results and Impact | Invited talk at Anion-Exchange Membranes for Energy Generation Technologies, at the University of Surrey on the 25th and 26th of July 2013. . |
Year(s) Of Engagement Activity | 2013 |
Description | From Apatites to Perovskites: An exploration of Si containing Solid Oxide Fuel Cell Materials |
Form Of Engagement Activity | Scientific meeting (conference/symposium etc.) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Participants in your research or patient groups |
Results and Impact | Invited talk to Functional Inorganic Materials meeting at the University of Liverpool. |
Year(s) Of Engagement Activity | 2013 |
Description | Going Tetrahedral for New SOFC Materials |
Form Of Engagement Activity | Scientific meeting (conference/symposium etc.) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Participants in your research or patient groups |
Results and Impact | Invited talk at 3rd Chalmers-ISIS Workshop, Gothenburg, Sweden, 2010. |
Year(s) Of Engagement Activity | 2010 |
Description | Meet the Scientist |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | Yes |
Primary Audience | Public/other audiences |
Results and Impact | Display on Fuel cells for the Thinktank Museum, Birmingham as part of their Meet the Scientist series. As part of the Thinktank Museum's Meet the Scientist week, we set up a stand on fuel cells, with demonstrations of their operation. |
Year(s) Of Engagement Activity | 2010 |
Description | Novel Electrode Materials For Fuel Cells |
Form Of Engagement Activity | Scientific meeting (conference/symposium etc.) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Participants in your research or patient groups |
Results and Impact | Talk at RSC Solid State Chemistry Group Christmas Conference, UCL, London. |
Year(s) Of Engagement Activity | 2010 |