Microgrid Energy Storage using Lithum-Sulfur Batteries
Lead Research Organisation:
University of Southampton
Department Name: Sch of Chemistry
Abstract
OXIS Energy, a manufacturer Lithium Sulfur battery technology has formed a collaboration with the University of
Southampton to demonstrate a new rechargeable battery technology capable of achieving high cycle life at competitive
costs to target the microgrid energy storage market. The project will exploit OXIS Energy's core Lithium Sulfur technology
using a new electrolyte classification to extend cycle life. The University of Southampton will exploit their extensive
knowledge of novel electrochemical test techniques to assess candidate electrolyte formulations and then test their
performance credentials in the laboratory. These new electrolytes will be then scaled up by OXIS and their full performance
characterised in a prototype Li-S battery cells. The project will demonstrate the commercial feasibility of this new
rechargeable battery technology for stationary energy storage. If successful developed this technology will reduce
consumer costs and carbon emissions whilst improving the Uk's energy security by being less reliant on foreign imports of
fossil fuels.
Southampton to demonstrate a new rechargeable battery technology capable of achieving high cycle life at competitive
costs to target the microgrid energy storage market. The project will exploit OXIS Energy's core Lithium Sulfur technology
using a new electrolyte classification to extend cycle life. The University of Southampton will exploit their extensive
knowledge of novel electrochemical test techniques to assess candidate electrolyte formulations and then test their
performance credentials in the laboratory. These new electrolytes will be then scaled up by OXIS and their full performance
characterised in a prototype Li-S battery cells. The project will demonstrate the commercial feasibility of this new
rechargeable battery technology for stationary energy storage. If successful developed this technology will reduce
consumer costs and carbon emissions whilst improving the Uk's energy security by being less reliant on foreign imports of
fossil fuels.
Planned Impact
The project aims to develop a new lithium-sulphur battery rechargeable battery technology that will be specially well suited
for microgrid energy storage. This will allow a more efficient use of energy: the excess of energy produced by micro-scale
renewables will be stored and used when required. This approach has many advantages for the society. The cost of
electricity will decrease, the energy security will increase due to a lower dependency on fossil fuels and CO2 emissions will
decrease due to an increased use of renewable sources of energy.
The approach taken in this project is to apply the concept of solvent in salt electrolytes in lithium-sulphur batteries. Lithiumsulphur
batteries have many unique advantages. Especially relevant for microgrid energy storage is the fact that lithiumsulphur
batteries are cheap and exhibit a long cycle life. Major improvements in battery performance will be sought in this
project by developing new electrolytes based on the solvent in salt concept, where the amount of solvent that is used in the
battery can be minimized. This produces an obvious decrease in the cost of the batteries. Safety standards are also
significantly improved with this approach due to the higher cycling stability of the lithium negative electrode.
This novel approach could also be highly beneficial in other energy storage systems, such as lithium-metal, lithium-ion and
lithium-air batteries. It is also likely that these new electrolytes could lead to improved electrocatalysis (e.g. improved
synthetic reactions) in the more general context of electrochemistry in organic electrolytes.
In addition to the general benefits to the society, this project will underpin the research development of Oxis and
Southampton. Oxis will strengthen its position in the rechargeable battery market and will attack further interest and
investment in this novel energy technology. Southampton will gain scientific reputation and expand the research output via
high impact publications, patents, participation in conferences, etc.
for microgrid energy storage. This will allow a more efficient use of energy: the excess of energy produced by micro-scale
renewables will be stored and used when required. This approach has many advantages for the society. The cost of
electricity will decrease, the energy security will increase due to a lower dependency on fossil fuels and CO2 emissions will
decrease due to an increased use of renewable sources of energy.
The approach taken in this project is to apply the concept of solvent in salt electrolytes in lithium-sulphur batteries. Lithiumsulphur
batteries have many unique advantages. Especially relevant for microgrid energy storage is the fact that lithiumsulphur
batteries are cheap and exhibit a long cycle life. Major improvements in battery performance will be sought in this
project by developing new electrolytes based on the solvent in salt concept, where the amount of solvent that is used in the
battery can be minimized. This produces an obvious decrease in the cost of the batteries. Safety standards are also
significantly improved with this approach due to the higher cycling stability of the lithium negative electrode.
This novel approach could also be highly beneficial in other energy storage systems, such as lithium-metal, lithium-ion and
lithium-air batteries. It is also likely that these new electrolytes could lead to improved electrocatalysis (e.g. improved
synthetic reactions) in the more general context of electrochemistry in organic electrolytes.
In addition to the general benefits to the society, this project will underpin the research development of Oxis and
Southampton. Oxis will strengthen its position in the rechargeable battery market and will attack further interest and
investment in this novel energy technology. Southampton will gain scientific reputation and expand the research output via
high impact publications, patents, participation in conferences, etc.
Organisations
Publications
Dibden J
(2017)
Quantitative Galvanostatic Intermittent Titration Technique for the Analysis of a Model System with Applications in Lithium-Sulfur Batteries
in ChemElectroChem
Raccichini R
(2018)
Ion Speciation and Transport Properties of LiTFSI in 1,3-Dioxolane Solutions: A Case Study for Li-S Battery Applications.
in The journal of physical chemistry. B
Raccichini R
(2018)
Impedance Characterization of the Transport Properties of Electrolytes Contained within Porous Electrodes and Separators Useful for Li-S Batteries
in Journal of The Electrochemical Society
Description | We have developed new methods to characterize the basic components of lithium-sulfur batteries. This will pave the way towards a rational design of battery components. |
Exploitation Route | Rational screening of battery components |
Sectors | Chemicals Energy Environment |
URL | https://www.southampton.ac.uk/chemistry/about/staff/nga1e12.page |
Description | We have developed novel methodologies that enabled the quantification of key properties affecting the performance of lithium-sulfur batteries, and we have also identified materials (specifically, new electrolytes) that enable significant improvements in battery longevity. The results have been communicated in publications, international conferences, outreach activities and meetings with other academics. The project was a collaboration with Oxis Energy Ltd., where the findings of the project are tested for a variety of applications. |
Sector | Energy,Leisure Activities, including Sports, Recreation and Tourism |
Impact Types | Societal Economic |
Description | FETOPEN |
Amount | € 3,000,000 (EUR) |
Funding ID | FETOPEN-01-2016-2017 SALBAGE |
Organisation | European Commission |
Sector | Public |
Country | European Union (EU) |
Start | 11/2017 |
End | 10/2021 |
Description | LiSTAR |
Amount | £10,000,000 (GBP) |
Funding ID | EP/T012404/1 |
Organisation | The Faraday Institution |
Sector | Charity/Non Profit |
Country | United Kingdom |
Start | 09/2019 |
End | 09/2023 |
Description | 20th Topical Meeting of the ISE (Buenos Aires)- Invited talk |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | 20th Topical Meeting of the International Society of Electrochemistry (Buenos Aires). An invited talk by N Garcia-Araez titled "Using redox mediators for Li-S and Li-O2 batteries and Li recycling" |
Year(s) Of Engagement Activity | 2017 |
URL | http://topical20.ise-online.org/ |
Description | 8th Workshop "Lithium-Sulfur Batteries" by Fraunhofer IWS |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Attendance to Webinar "8th Workshop "Lithium-Sulfur Batteries" (June 18-19, 2020 by Fraunhofer IWS) by N. Garcia-Araez. |
Year(s) Of Engagement Activity | 2020 |
URL | https://www.fraunhofer.de/en/events/lithium-sulfur-batteries.html |
Description | A talk or presentation - Batteries Sweden BASE workshop- talk by Nuria Garcia-Araez |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Batteries Sweden BASE workshop: Battery chemistries - from generation 3 to generation 5, invited talk by N. Garcia-Araez titled 'Sulfur-based battery chemistries' |
Year(s) Of Engagement Activity | 2021 |
Description | Electrochem2017 keynote presentation |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Professional Practitioners |
Results and Impact | Electrochem2017. Talk presented by N. Garcia-Araez titled "Using redox mediators for Li-S and Li-O2 batteries and Li recycling" |
Year(s) Of Engagement Activity | 2017 |
Description | Electrochem2018 oral presentation |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Professional Practitioners |
Results and Impact | Electrochem2018. Talk presented by N. Garcia-Araez titled "Understanding the effect of electrolyte in Li-S batteries: analytical and electrochemical tools to quantify polysulfide formation" |
Year(s) Of Engagement Activity | 2018 |
URL | http://wp.lancs.ac.uk/electrochem/ |
Description | ISE annual meeting 2017 oral presentation by R. Raccichini |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | ISE annual meeting 2017 oral presentation by R. Raccichini titled "Conductivity, Viscosity and Ionic Dissociation of LiTFSI-1,3 Dioxolane Electrolyte Solutions: a Case Study for Li-S Battery Applications" |
Year(s) Of Engagement Activity | 2017 |
URL | http://annual68.ise-online.org/ |
Description | ISE annual meeting 2018 oral presentation |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | The international society of electrochemistry (ISE) meeting in 2018. Talked presented by N. Garcia-Araez titled "Understanding the effect of electrolyte in Li-S batteries: analytical and electrochemical tools to quantify polysulfide formation". |
Year(s) Of Engagement Activity | 2018 |
URL | http://annual69.ise-online.org/ |
Description | ISE annual meeting 2018 oral presentation by L. Furness |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | The international society of electrochemistry (ISE) meeting in 2018. Talk presented by L. Furness titled "Measurements of the conductivity of electrolytes contained within porous electrodes and separators" |
Year(s) Of Engagement Activity | 2018 |
URL | http://annual69.ise-online.org/ |
Description | ISE annual meeting 2018 poster |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | The international society of electrochemistry (ISE) meeting in 2018. N. Garcia-Araez presented a poster titled "Why GITT can provide wrong values of diffusion coefficientand how to avoid it" |
Year(s) Of Engagement Activity | 2018 |
URL | http://annual69.ise-online.org/ |
Description | ISE annual meeting 2020 talk by Nuria Garcia-Araez |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | 71st Annual Meeting of the International Society of Electrochemistry (online event). Oral presentation by N. Garcia-Araez titled "New tools for the rational development of metal-sulfur batteries" |
Year(s) Of Engagement Activity | 2020 |
URL | https://annual71.ise-online.org/ |
Description | LiSM3 2017 -oral presentation by J. Dibden |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | LiSM3 2017. Oral presentation by J. Dibden titled "A Quantitative Tool to Predict the Phase Composition of Lithium-Sulfur Batteries" |
Year(s) Of Engagement Activity | 2017 |
URL | http://www.lism3.org/ |
Description | LiSM3 2017 oral presentation |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Li-SM3 2017. An oral presentation by N. Garcia-Araez titled "Qualitative analysis of GITT measurements of Li-S batteries" |
Year(s) Of Engagement Activity | 2017 |
URL | http://www.lism3.org/ |
Description | Oxford ECS Student Symposium 2017, Plenary lecture |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Postgraduate students |
Results and Impact | Oxford ECS Student Symposium. Plenary lecture given by N. Garcia-Araez titled "Using redox mediators for Li-S and Li-O2 batteries and Li recycling" |
Year(s) Of Engagement Activity | 2017 |
Description | Science and Engineering Day 2017 outreach electrochemical activity |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Public/other audiences |
Results and Impact | Science and Engineering Day 2017, outreach activity about electrochemistry research demonstrated by J. Frith, W. Richardson, J. Dibden, N. Meddings, N. Garcia-Araez and others. |
Year(s) Of Engagement Activity | 2017 |
URL | https://www.southampton.ac.uk/per/university/festival/science-and-engineering-day.page |
Description | Workshop on Characterisation Methods to Accelerate Electrochemical Energy Storage - Invited oral presentation |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Professional Practitioners |
Results and Impact | National workshop "Infrastructure to Knowledge: Advanced Characterisation Methods to Accelerate the Development of Novel Electrochemical Energy Storage Devices". An invited talk by N. Garcia-Araez titled "Fundamental electrochemical characterization of energy storage materials" |
Year(s) Of Engagement Activity | 2018 |
URL | https://faraday.ac.uk/characterisation-methods-to-accelerate-electrochemical-energy-storage-july-16-... |