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Smart electrodes for energy storage devices

Lead Research Organisation: Keele University
Department Name: Faculty of Natural Sciences

Abstract

Energy crises and climate changes are the two topmost challenges in this 21st century. Renewable energy resources like solar and wind technology could be the ultimate solution to address these societal and environmental problems. In addition, to ease the gap between the energy supply and demand on the grid, we need sustainable energy storage devices. Promising storage devices are batteries and capacitors. Indeed, capacitors have undergone a series of development stages and nowadays, supercapacitors are at the frontline of energy research. Supercapacitors are considered as bridging the gap between conventional capacitors and batteries in terms of energy and power. They can store more energy than conventional capacitors and supply it at higher power outputs than batteries. Supercapacitors offer an excellent power-to-weight ratio which makes them suitable for high power requirements released in a short period. Over recent years, there has been a growing demand for supercapacitors due to modern applications like electric vehicles and power back-ups that require fast charge release.

The key determinants of an energy storage device's performance are the properties of the electrode materials. The ideal electrode would consist of (i) high conductivity to allow fast electron/hole transfer, and (ii) a high surface area to give many active sites. 2D materials have all these necessary parameters, which makes them next-generation electrode materials for high-performing energy storage devices. So far, graphene, metal oxides, dichalcogenides, and transition metal carbides/nitrides (MXenes), have been investigated for their potential roles in energy storage applications. The limited cycle life and inferior rate capabilities of these materials-based devices still hinder their practical applications. This bottleneck can be overcome by the smart choice of elemental combination along with carbon coupling that will improve rate capability and prolonged cycling stability.

In this project, we are aiming to develop a new class of electrode materials based on metal chalcogenide compounds and their carbon coupling nanostructures. This collaborative project is expected to produce economical, sustainable, high-performance metal chalcogenide electrode materials for next-generation energy storage devices. The project is aligned with the theme of developing materials and devices for sustainable energy storage and has enormous potential to impact energy storage devices, green energy technology, advanced materials, and sustainable energy materials.
 
Description The material composition of a solid polymer electrolyte based on nature rubber and sodium salt is engineered to get maximum conductivity. The composition natural rubber: sodium salt = 1:0.5 (by weight) shows the highest room temperature conductivity of 7.52 × 10-4 S cm-1. This optimized electrolyte is purely an ionic conductor. This electrolyte is used to fabricate supercapacitor by sandwiching it between two reduced graphene oxide (rGO) electrodes. This supercapacitor shows a maximum single electrode specific capacitance of 42.5 F g-1, which is a good value for the lab-scale supercapacitor.
Exploitation Route This outcome has been published in an open-access journal (Journal of Energy Storage, 97, 112683 (2024)
Sectors Energy

URL https://doi.org/10.1016/j.est.2024.112683
 
Description An outreach activity on the theme of Renewable energy was conducted by my team for the International Day of Women and Girls in Science on 8th and 11th February 2025 at Keele in Town, Newcastle-under-Lyme. A supercapacitor device was showcased to the public and the difference between batteries and supercapacitors was explained. nearly 100 people of all ages attended this event.
First Year Of Impact 2025
Sector Energy,Environment
Impact Types Societal

 
Title Data files for paper "Symmetric double-layer capacitor with natural rubber and sodium salt-based solid polymer electrolyte and reduced graphene oxide electrodes" 
Description  
Type Of Material Database/Collection of data 
Year Produced 2024 
Provided To Others? Yes  
URL https://researchdata.keele.ac.uk/85/
 
Description Pakistani partners 
Organisation National University of Sciences and Technology
Country Pakistan 
Sector Academic/University 
PI Contribution Characterizing Titanium Carbide Mxene by Raman, X-ray Diffraction, Scanning Electron Microscopy, and BET . This material will be tested for supercapacitor electrodes.
Collaborator Contribution Synthesized Titanium Carbide Mxene.
Impact This is an ongoing research. This activity could result in a publication by the end of this year.
Start Year 2024
 
Description Sri Lankan partners 
Organisation Associated Speciality Rubbers
Country Sri Lanka 
Sector Private 
PI Contribution A combined research study of sustainable supercapacitors based on natural rubber-based electrolyte and reduced graphene oxide electrodes (rGO) were performed. My team at Keele University prepared and characterised rGO electrodes. Prof. Kumudu Perera and Prof. Kamal Vidanapathirana from Wayamba University of Sri Lanka optimized the electrolytes' conductivity and characterized the supercapacitors.
Collaborator Contribution Wayamba University of Sri Lanka - Staff time, skill and knowledge transfer Associated Speciality Rubbers (PVT) Ltd., Sri Lanka - 49 % methyl grafted natural rubber (MG49-NR) Sakura Graphite - rGO powder
Impact Kumudu S. Perera, Kamal P. Vidanapathirana, Lewis J. Adams, Chris S. Hawes, Nilanthy Balakrishnan, Symmetric double-layer capacitor with natural rubber and sodium salt-based solid polymer electrolyte and reduced graphene oxide electrodes, Journal of Energy Storage 97, 112683 (2024).
Start Year 2024
 
Description Sri Lankan partners 
Organisation Wayamba University of Sri Lanka
Country Sri Lanka 
Sector Academic/University 
PI Contribution A combined research study of sustainable supercapacitors based on natural rubber-based electrolyte and reduced graphene oxide electrodes (rGO) were performed. My team at Keele University prepared and characterised rGO electrodes. Prof. Kumudu Perera and Prof. Kamal Vidanapathirana from Wayamba University of Sri Lanka optimized the electrolytes' conductivity and characterized the supercapacitors.
Collaborator Contribution Wayamba University of Sri Lanka - Staff time, skill and knowledge transfer Associated Speciality Rubbers (PVT) Ltd., Sri Lanka - 49 % methyl grafted natural rubber (MG49-NR) Sakura Graphite - rGO powder
Impact Kumudu S. Perera, Kamal P. Vidanapathirana, Lewis J. Adams, Chris S. Hawes, Nilanthy Balakrishnan, Symmetric double-layer capacitor with natural rubber and sodium salt-based solid polymer electrolyte and reduced graphene oxide electrodes, Journal of Energy Storage 97, 112683 (2024).
Start Year 2024
 
Description International Day of Women and Girls in Science 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Public/other audiences
Results and Impact An outreach activity on the theme of Renewable energy was conducted by my team for the International Day of Women and Girls in Science on 8th and 11th February 2025 at Newcastle-under-Lyme town centre. A supercapacitor device was showcased to the public and the difference between batteries and supercapacitors was explained. nearly 100 people of all ages attended this event.
Year(s) Of Engagement Activity 2025