NANOESCA - ELECTRON SPECTROSCOPY FOR CHEMICAL ANALYSIS IMAGED AT THE NANOSCALE.
Lead Research Organisation:
University of Bristol
Department Name: Chemistry
Abstract
The NanoESCA is an Ultra High Vacuum (UHV) photoemission spectroscopy system with sub-micron spatial resolution for real-space and k-space (reciprocal space) mapping from areas of a few microns of flat material surfaces, and the capability to perform quantitative chemical state mapping at the nanoscale. The system is designed for installation on a synchrotron beam line end-station or in a Nano Science Laboratory.
The system has various modes of operation. UV photon sources are used for Ultra-violet Photoemission Spectroscopy (UPS), Angle Resolved UPS, and Photo Emission Electron Microscopy (PEEM), soft X-rays are used for X-ray Photoemission Spectroscopy (XPS). UPS gives energy filtered information on weakly bound states and the valence band structure in real space and the surface electronic band structure in k-space. XPS is used to probe core level spectra to obtain quantitative information on the chemical composition of a surface. In contrast to the high resolution Scanning Electron Microscope, PEEM directly images surface areas emitting photoelectrons in real time without scanning. By energy filtering PEEM images it is possible to obtain quantitative maps of surface work function. The field of view is adjustable from millimetres to microns allowing high resolution imaging of features as small as 30nm (UPS modes) and 480nm (XPS mode).
The NanoESCA machine being requested represents the next generation in imaging and spectroscopic PEEM. It uses an extension of the established parallel imaging technique, to simultaneously image and filter photoelectrons, by using a double hemispherical (aberration corrected) electron analyser in combination with high photon flux VUV and X-ray sources, to realise nano scale imaging and spectroscopy in real space and in k-space; the latter mode allows information on the electronic band structure of materials to be visualised and compared directly with theoretical models. Uniquely, this capability to obtain nanoscale spectroscopy using either X-ray or VUV sources is obtained by parallel imaging through the same PEEM 'column' which also acts as the entrance lens of the imaging spectrometer.
The system has various modes of operation. UV photon sources are used for Ultra-violet Photoemission Spectroscopy (UPS), Angle Resolved UPS, and Photo Emission Electron Microscopy (PEEM), soft X-rays are used for X-ray Photoemission Spectroscopy (XPS). UPS gives energy filtered information on weakly bound states and the valence band structure in real space and the surface electronic band structure in k-space. XPS is used to probe core level spectra to obtain quantitative information on the chemical composition of a surface. In contrast to the high resolution Scanning Electron Microscope, PEEM directly images surface areas emitting photoelectrons in real time without scanning. By energy filtering PEEM images it is possible to obtain quantitative maps of surface work function. The field of view is adjustable from millimetres to microns allowing high resolution imaging of features as small as 30nm (UPS modes) and 480nm (XPS mode).
The NanoESCA machine being requested represents the next generation in imaging and spectroscopic PEEM. It uses an extension of the established parallel imaging technique, to simultaneously image and filter photoelectrons, by using a double hemispherical (aberration corrected) electron analyser in combination with high photon flux VUV and X-ray sources, to realise nano scale imaging and spectroscopy in real space and in k-space; the latter mode allows information on the electronic band structure of materials to be visualised and compared directly with theoretical models. Uniquely, this capability to obtain nanoscale spectroscopy using either X-ray or VUV sources is obtained by parallel imaging through the same PEEM 'column' which also acts as the entrance lens of the imaging spectrometer.
Planned Impact
The impact of the NanoESCA on University of Bristol (UoB) research themes will be transformative due to new insights expected into the properties of materials at the nanoscale impacting: Nanoscience and Quantum Information (Nanostructured devices for photon/electron confinement in Diamond and Silicon); Electronic and Photonic Materials (Functional complex oxides for solar fuels, Organic Spintronics, Diamond thermionics); Advanced Composites and Intelligent Structures (Next Generation GaN-on-Diamond RF Power Amplifier Devices, Bone and tissue engineering). Each of these themes supports research over a wide range of EPSRC-funded activities ensuring high demand for NanoESCA on existing and future grants.
Organisations
- University of Bristol (Lead Research Organisation)
- Linkoping University (Collaboration)
- Aarhus University (Collaboration)
- University of Manchester (Collaboration)
- University of Bath (Collaboration)
- Humboldt University of Berlin (Collaboration)
- Eindhoven University of Technology (Collaboration)
- National Physical Laboratory (Collaboration)
- University of Padova (Collaboration)
- Norwegian University of Science and Technology (NTNU) (Collaboration)
- DIAMOND LIGHT SOURCE (Collaboration)
Publications
Cattelan M
(2018)
A Perspective on the Application of Spatially Resolved ARPES for 2D Materials.
in Nanomaterials (Basel, Switzerland)
Celorrio V
(2017)
Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction
in MRS Communications
Dominguez-Andrade H
(2020)
Correlating Thermionic Emission with Specific Surface Reconstructions in a <100> Hydrogenated Single-Crystal Diamond.
in ACS applied materials & interfaces
Gobbo P
(2020)
Catalytic processing in ruthenium-based polyoxometalate coacervate protocells.
in Nature communications
Harding L
(2023)
Epitaxial stabilisation of uranium silicide line compounds
in Thin Solid Films
James M
(2021)
Experimental Studies of Electron Affinity and Work Function from Aluminium on Oxidized Diamond (100) and (111) Surfaces
in physica status solidi (b)
James M
(2021)
A review of surface functionalisation of diamond for thermionic emission applications
in Carbon
Jung S
(2020)
Spectral functions of CVD grown MoS2 monolayers after chemical transfer onto Au surface
in Applied Surface Science
Lawrence Bright E
(2022)
Oxidation and passivation of the uranium nitride (001) surface
in Corrosion Science
Description | Materials discovery due to unique visualisation of material properties. A new photoemission technique has been developed that allows the unoccupied levels of a crystalline material to be visualised. This technique is applicable to materials being researched for applications in valleytronics, spintronics, voltaics and phononics. |
Exploitation Route | Bristol NanoESCA has been made a University Facility providing a service to materials researchers located at SW region universities including Bath, Cardiff, Exeter, Oxford, and a basis for international collaborations with researchers in Norway, Denmark, Italy, Germany, France, USA and Japan. |
Sectors | Aerospace Defence and Marine Education Electronics Energy |
URL | http://www.bristol.ac.uk/physics/facilities/nanoesca/ |
Description | Have completed impact acceleration KTS project to demonstrate that samples pre analysed in the Bristol NanoESCA may be transported under ultra high vacuum to a synchrotron beam line (I05 at Diamond Light Source) and further high resolution analysis performed on the end station without any sample preparation. In 2020 we have also demonstrated that this preanalysis technique may be used in conjunction with national synchrotron facilities overseas. For this trial beamtime was successfully completed at Elettra in Trieste, Italy, on the Spectromicroscopy beamline. Diamond Light Source has been funded by EPSRC to evaluate laser PEEM capability linked to I06 beamline. Bristol are supporting this project providing lab beam time analysis of selected 2D materials and have also been training beam line scientists to operate the NanoESCA. Samples have been exchanged between Bristol and Diamond by UHV suitcase. |
First Year Of Impact | 2019 |
Sector | Energy |
Description | SBRI: Fusion Industry Challenges - phase 2 |
Amount | £1,460,000 (GBP) |
Funding ID | SBRI 13513 |
Organisation | Culham Centre for Fusion Energy |
Sector | Academic/University |
Country | United Kingdom |
Start | 04/2023 |
End | 10/2024 |
Description | Solution-Processed Inorganic Thin-Film Photovoltaic Devices (SolPV) |
Amount | £862,980 (GBP) |
Funding ID | EP/V008676/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 07/2021 |
End | 01/2025 |
Title | High Intensity VUV Light Source |
Description | Additional light source installed on the Bristol NanoESCA to increase instrument capability. |
Type Of Material | Improvements to research infrastructure |
Year Produced | 2023 |
Provided To Others? | No |
Impact | The new light source is benefiting existing NanoESCA users and will be featured in a number of publications currently in preparation. The light source allows materials to be analyzed with a greater information depth which is beneficial for the study of samples composed of 2D multilayers or non-smooth single crystal surfaces. This is a unique capability and makes the Bristol NanoESCA instrument accessible to a wider range of researchers working on materials for energy. |
Title | Data from AlO diamond termination paper in PSSB |
Description | This is the data repository for the paper 'Experimental Studies of Electron Affinity and Work Function from Aluminium on Oxidised Diamond (100) and (111) Surfaces' by Michael C. James, Mattia Cattelan, Neil A. Fox, Rui F. Silva, Ricardo M. Silva and Paul W. May. Physica Status Solidi B (2021). |
Type Of Material | Database/Collection of data |
Year Produced | 2021 |
Provided To Others? | Yes |
URL | https://data.bris.ac.uk/data/dataset/3ohhlefvl13zr23pcl9u55a21f/ |
Title | Data from photoluminescence spectroscopy, admittance spectroscopy, photoelectron emission microscopy, current-voltage characteristics, and spectral response of quantum efficiency measurements on Cu2ZnZnSnS4 (CZTS) films and solar cells as a function of... |
Description | This is the dataset used in the journal article to be published in American Chemical Society's Applied Energy Materials. Article Title: Mapping the Energetics of Defect States in Cu2ZnSnS4 films and the Impact of Sb DopingAuthors: Devendra Tiwari, Michael V. Yakushev, Tristan Koehler, Mattia Cattelan, Neil Fox, Robert W. Martin, Reiner Klenk and David J FerminDOI: https://10.1021/acsaem.1c03729 The dataset was produced in collaboration with colleagues from University of Bristol, Strathclyde University and Helmholtz Zentrum Berlin. The dataset contains .csv files and can be accessed can be using any text editor or any spreadsheet software. |
Type Of Material | Database/Collection of data |
Year Produced | 2022 |
Provided To Others? | Yes |
URL | https://figshare.northumbria.ac.uk/articles/dataset/Data_from_photoluminescence_spectroscopy_admitta... |
Title | Mapping Shunting Paths at the Surface of Cu2ZnSn(S,Se)4 Films via Energy-Filtered Photoemission Microscopy |
Description | This deposition includes the data of the experiments and calculations used and presented in the article published in the Cell press journal: iScience titled:"Mapping Shunting Paths at the Surface of Cu2ZnSn(S,Se)4 Films via Energy-Filtered Photoemission Microscopy" authored by Devendra Tiwari, Mattia Cattelan, Robert L. Harniman, Andrei Sarua, Ali Abbas, Jake W. Bowers, Neil A. Fox, David J. Fermin. DOI: 10.1016/j.isci.2018.10.004 |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
Title | The Impact of Sb and Na Doping on the Surface Electronic Landscape of Cu2ZnSnS4 Thin-Films |
Description | This deposition includes the data of the experiments and calculations used and presented in the article published in the Journal: ACS energy letters, Authors: Devendra Tiwari, Mattia Cattelan, Robert L. Harniman, Andrei Sarua, Neil Fox, Tristan Koehler, Reiner Klenk and David J Fermin, DOI: https://10.1021/acsenergylett.8b02081 |
Type Of Material | Database/Collection of data |
Year Produced | 2018 |
Provided To Others? | Yes |
Description | Aarhus University |
Organisation | Aarhus University |
Country | Denmark |
Sector | Academic/University |
PI Contribution | NanoESCA training for PhDs from Department of Physics and Astronomy at Aarhus University. |
Collaborator Contribution | Preparation of sample materials for analysis. |
Impact | Physics, Chemistry |
Start Year | 2019 |
Description | Eindhoven University of Technology |
Organisation | Eindhoven University of Technology |
Country | Netherlands |
Sector | Academic/University |
PI Contribution | NanoESCA Materials Analysis |
Collaborator Contribution | Complimentary Materials analysis and sample preparation. |
Impact | None to date. |
Start Year | 2016 |
Description | Humboldt-Universität zu Berlin |
Organisation | Humboldt University of Berlin |
Country | Germany |
Sector | Academic/University |
PI Contribution | NanoESCA Beamtime analysis of materials |
Collaborator Contribution | Provision of material samples. |
Impact | Physics, Chemistry |
Start Year | 2018 |
Description | Laser PEEM facility at Diamond Light Source |
Organisation | Diamond Light Source |
Country | United Kingdom |
Sector | Private |
PI Contribution | Provided NanoESCA training and pre-characterisation of samples for Laser PEEM project. |
Collaborator Contribution | Installation and commissioning of Laser PEEM. |
Impact | Publication is planned. |
Start Year | 2021 |
Description | Linkoping University (Dr. Vagin) |
Organisation | Linkoping University |
Department | Department of Physics, Chemistry and Biology (IFM) |
Country | Sweden |
Sector | Academic/University |
PI Contribution | NanoESCA materials analysis |
Collaborator Contribution | Complimentary materials analysis. |
Impact | Publication in preparation. |
Start Year | 2016 |
Description | Metal Halide 2D material |
Organisation | University of Manchester |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | Access to Bristol NanoESCA facility, expertise associated with operation and data interpretation. |
Collaborator Contribution | Production of 2D samples |
Impact | Draft manuscript in preparation. |
Start Year | 2023 |
Description | NPL (Dr. Kazakova) |
Organisation | National Physical Laboratory |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | NanoESCA Materials Analysis. |
Collaborator Contribution | Material preparation. |
Impact | None to date. |
Start Year | 2017 |
Description | Norwegian University of Science and Technology (NTNU) |
Organisation | Norwegian University of Science and Technology (NTNU) |
Country | Norway |
Sector | Academic/University |
PI Contribution | Training for NTNU staff on the NanoESCA instrument platform. |
Collaborator Contribution | Technical advice on angle resolved photoemission of diamond. |
Impact | Physics, Chemistry |
Start Year | 2018 |
Description | University of Bath (Dr. Da Como) |
Organisation | University of Bath |
Department | Department of Physics |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | NanoESCA Material Analysis |
Collaborator Contribution | Sample preparation and complimentary analysis |
Impact | Publication in preparation. |
Start Year | 2017 |
Description | University of Bath (Dr. Nogaret) |
Organisation | University of Bath |
Department | Department of Physics |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | NanoESCA Materials Analysis |
Collaborator Contribution | Complimentary Materials analysis and sample synthesis. |
Impact | Publication in preparation. |
Start Year | 2017 |
Description | University of Padova (Prof. Agnoli) |
Organisation | University of Padova |
Country | Italy |
Sector | Academic/University |
PI Contribution | NanoESCA materials analysis |
Collaborator Contribution | Complimentary material analysis. |
Impact | Publication in press. |
Start Year | 2016 |
Description | Aberration-Corrected PEEM Workshop |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Professional Practitioners |
Results and Impact | Workshop on the upgrade of IO-6 beamline at Diamond Light Source to incorporate Aberration-Corrected PEEM. Discussions about sample transfer between IO6 and Bristol NanoESCA with attendees. |
Year(s) Of Engagement Activity | 2019 |
Description | UK Surface Analysis Forum |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Third sector organisations |
Results and Impact | University of Bristol hosted the April event of the bi-annual meeting of UKSAF. |
Year(s) Of Engagement Activity | 2022 |
Description | UKSAF 2018 |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Industry/Business |
Results and Impact | Invited talk on the NanoESCA facility. |
Year(s) Of Engagement Activity | 2018 |