High Symmetry Paramagnetic Cages
Lead Research Organisation:
University of Edinburgh
Department Name: Sch of Chemistry
Abstract
Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.
Organisations
People |
ORCID iD |
| Euan Brechin (Principal Investigator) |
Publications
Bradley JM
(2010)
MCD spectroscopy of hexanuclear Mn(III) salicylaldoxime single-molecule magnets.
in Dalton transactions (Cambridge, England : 2003)
Langley S
(2011)
Molecular coolers: The case for [CuII5GdIII4]
in Chemical Science
Evangelisti M
(2011)
Cryogenic magnetocaloric effect in a ferromagnetic molecular dimer.
in Angewandte Chemie (International ed. in English)
Hooper T
(2012)
The Importance of Being Exchanged: [Gd III 4 M II 8 (OH) 8 (L) 8 (O 2 CR) 8 ] 4+ Clusters for Magnetic Refrigeration
in Angewandte Chemie International Edition
Ungur L
(2012)
Net toroidal magnetic moment in the ground state of a {Dy6}-triethanolamine ring.
in Journal of the American Chemical Society
Houton E
(2012)
Ferromagnetic exchange in a twisted, oxime-bridged [Mn(III)2] dimer.
in Dalton transactions (Cambridge, England : 2003)
Lorusso G
(2012)
Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks.
in Chemical communications (Cambridge, England)
Richmond CJ
(2012)
A flow-system array for the discovery and scale up of inorganic clusters.
in Nature chemistry
Mason K
(2012)
Linking [MIII3] triangles with "double-headed" phenolic oximes
in Dalton Transactions
| Description | The moleculer recipes required to construct molecules with an enhanced magnetocaloric effect (MCE) that makes possible the use of molecules and molecule-based materials as cryogenic coolants, and thus as possible replacements for the rare and expensive He-3. |
| Exploitation Route | Fundamental chemistry and physics that underpins potential use as cryocoolers. |
| Sectors | Chemicals |
| URL | http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin |