High Symmetry Paramagnetic Cages
Lead Research Organisation:
University of Edinburgh
Department Name: Sch of Chemistry
Abstract
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Organisations
People |
ORCID iD |
| Euan Brechin (Principal Investigator) |
Publications
Evangelisti M
(2011)
Cryogenic magnetocaloric effect in a ferromagnetic molecular dimer.
in Angewandte Chemie (International ed. in English)
Hooper T
(2012)
The Importance of Being Exchanged: [Gd III 4 M II 8 (OH) 8 (L) 8 (O 2 CR) 8 ] 4+ Clusters for Magnetic Refrigeration
in Angewandte Chemie International Edition
Lorusso G
(2012)
Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks.
in Chemical communications (Cambridge, England)
Langley S
(2011)
Molecular coolers: The case for [CuII5GdIII4]
in Chemical Science
Berg N
(2012)
What controls the magnetic interaction in bis-µ-alkoxo Mn(III) dimers? A combined experimental and theoretical exploration.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Mason K
(2012)
Linking [MIII3] triangles with "double-headed" phenolic oximes
in Dalton Transactions
Bradley JM
(2010)
MCD spectroscopy of hexanuclear Mn(III) salicylaldoxime single-molecule magnets.
in Dalton transactions (Cambridge, England : 2003)
Houton E
(2012)
Ferromagnetic exchange in a twisted, oxime-bridged [Mn(III)2] dimer.
in Dalton transactions (Cambridge, England : 2003)
Frost JM
(2014)
A truncated [Mn(III)12] tetrahedron from oxime-based [Mn(III)3O] building blocks.
in Dalton transactions (Cambridge, England : 2003)
| Description | The moleculer recipes required to construct molecules with an enhanced magnetocaloric effect (MCE) that makes possible the use of molecules and molecule-based materials as cryogenic coolants, and thus as possible replacements for the rare and expensive He-3. |
| Exploitation Route | Fundamental chemistry and physics that underpins potential use as cryocoolers. |
| Sectors | Chemicals |
| URL | http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin |