Supramolecular Nanorings for Exploring Quantum Interference
Lead Research Organisation:
University of Liverpool
Department Name: Chemistry
Abstract
Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.
Publications
Vezzoli A
(2020)
A Chemically Soldered Polyoxometalate Single-Molecule Transistor
Wu C
(2020)
A Chemically Soldered Polyoxometalate Single-Molecule Transistor
in Angewandte Chemie
Wu C
(2020)
A Chemically Soldered Polyoxometalate Single-Molecule Transistor.
in Angewandte Chemie (International ed. in English)
Xu W
(2021)
A Peierls Transition in Long Polymethine Molecular Wires: Evolution of Molecular Geometry and Single-Molecule Conductance.
in Journal of the American Chemical Society
Leary E
(2018)
Bias-Driven Conductance Increase with Length in Porphyrin Tapes.
in Journal of the American Chemical Society
Escorihuela E
(2022)
Building large-scale unimolecular scaffolding for electronic devices
in Materials Today Chemistry
Markin A
(2020)
Conductance Behavior of Tetraphenyl-Aza-BODIPYs
in The Journal of Physical Chemistry C
Davidson RJ
(2018)
Conductance of 'bare-bones' tripodal molecular wires.
in RSC advances
| Description | We have achieved enhanced understanding of charge flow through porphyrin molecular wires. This includes the unique discovery of bias voltage driven conductance increases with length in porphyrin tapes. We have detected mechanochemical atropisomerization within an STM break junction containing porphyrin molecular wires. We have extended single molecule conductance measurements to supra-molecular assemblies including porphyrin nano-rings synthesised by our collaborators. Our collaborating partner has also demonstrated quantum interference in porphyrin nanorings through EPR measurements. In addition, we have studied quantum interference effects in other conjugated systems, such as how cross-conjugation increases the conductance of meta-connected fluorenones and the unusual length dependence of the conductance in cumulene molecular wires. |
| Exploitation Route | This project is providing insights into quantum interference which may be valuable in the field of nano-electronic devices and molecular electronics. |
| Sectors | Chemicals Education Electronics |
| Description | As well as laying foundations for understanding charge delocalisation in molecular nanostructures and providing insights into quantum interference which may be valuable in the field of nano-electronic devices and molecular electronics, this project has identified new routes to charge localisation in molecular devices which can be stabilised for longer timescales and operating under ambient conditions. The project has not yet had any economic or societal impact, but has important implications for nanoscale science and molecular electronics since such long-lived charge states might offer future inspiration for redox based molecular memories or memristor architectures. It is fundamental research. |
| First Year Of Impact | 2021 |
| Sector | Chemicals,Electronics |
| Title | CCDC 1578499: Experimental Crystal Structure Determination |
| Description | Related Article: Edmund Leary, Cécile Roche, Hua-Wei Jiang, Iain Grace, M. Teresa González, Gabino Rubio-Bollinger, Carlos Romero-Muñiz, Yaoyao Xiong, Qusiy Al-Galiby, Mohammed Noori, Maria A. Lebedeva, Kyriakos Porfyrakis, Nicolás Agrait, Andrew Hodgson, Simon J. Higgins, Colin J. Lambert, Harry L. Anderson, Richard J. Nichols|2018|J.Am.Chem.Soc.|140|710|doi:10.1021/jacs.7b10542 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2018 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pzkbk&sid=DataCite |
| Title | CCDC 1578844: Experimental Crystal Structure Determination |
| Description | Related Article: Ross J. Davidson, David C. Milan, Oday A. Al-Owaedi, Ali K. Ismael, Richard J. Nichols, Simon J. Higgins, Colin J. Lambert, Dmitry S. Yufit, Andrew Beeby|2018|RSC Advances|8|23585|doi:10.1039/C8RA01257A |
| Type Of Material | Database/Collection of data |
| Year Produced | 2018 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pzxg1&sid=DataCite |
| Title | CCDC 1578845: Experimental Crystal Structure Determination |
| Description | Related Article: Ross J. Davidson, David C. Milan, Oday A. Al-Owaedi, Ali K. Ismael, Richard J. Nichols, Simon J. Higgins, Colin J. Lambert, Dmitry S. Yufit, Andrew Beeby|2018|RSC Advances|8|23585|doi:10.1039/C8RA01257A |
| Type Of Material | Database/Collection of data |
| Year Produced | 2018 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pzxh2&sid=DataCite |
| Title | CCDC 1578846: Experimental Crystal Structure Determination |
| Description | Related Article: Ross J. Davidson, David C. Milan, Oday A. Al-Owaedi, Ali K. Ismael, Richard J. Nichols, Simon J. Higgins, Colin J. Lambert, Dmitry S. Yufit, Andrew Beeby|2018|RSC Advances|8|23585|doi:10.1039/C8RA01257A |
| Type Of Material | Database/Collection of data |
| Year Produced | 2018 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1pzxj3&sid=DataCite |
| Title | CCDC 1893619: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Songjun Hou, Sara Sangtarash, M. Teresa González, Gabino Rubio-Bollinger, Qingqing Wu, Hatef Sadeghi, Lara Tejerina, Kirsten E. Christensen, Nicolás Agraït, Simon J. Higgins, Colin J. Lambert, Richard J. Nichols, Harry L. Anderson|2019|Angew.Chem.,Int.Ed.|58|8378|doi:10.1002/anie.201901228 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2019 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc21kghl&sid=DataCite |
| Title | CCDC 1979403: Experimental Crystal Structure Determination |
| Description | Related Article: Chuanli Wu, Xiaohang Qiao, Craig M. Robertson, Simon J. Higgins, Chenxin Cai, Richard J. Nichols, Andrea Vezzoli|2020|Angew.Chem.,Int.Ed.|59|12029|doi:10.1002/anie.202002174 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2020 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc24fqq1&sid=DataCite |
| Title | CCDC 2074549: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mqyk&sid=DataCite |
| Title | CCDC 2074550: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mqzl&sid=DataCite |
| Title | CCDC 2074551: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr0n&sid=DataCite |
| Title | CCDC 2074552: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr1p&sid=DataCite |
| Title | CCDC 2074553: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr2q&sid=DataCite |
| Title | CCDC 2074554: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr3r&sid=DataCite |
| Title | CCDC 2074555: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr4s&sid=DataCite |
| Title | CCDC 2074556: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr5t&sid=DataCite |
| Title | CCDC 2074557: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr6v&sid=DataCite |
| Title | CCDC 2074558: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr7w&sid=DataCite |
| Title | CCDC 2074559: Experimental Crystal Structure Determination |
| Description | Related Article: Wenjun Xu, Edmund Leary, Sara Sangtarash, Michael Jirasek, M. Teresa Gonza´lez, Kirsten E. Christensen, Lydia Abella´n Vicente, Nicola´s Agrai¨t, Simon J. Higgins, Richard J. Nichols, Colin J. Lambert, Harry L. Anderson|2021|J.Am.Chem.Soc.|143|20472|doi:10.1021/jacs.1c10747 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2021 |
| Provided To Others? | Yes |
| URL | http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc27mr8x&sid=DataCite |
| Description | University of Madrid |
| Organisation | Autonomous University of Madrid |
| Country | Spain |
| Sector | Academic/University |
| PI Contribution | Collaboration in single molecule electronics |
| Collaborator Contribution | Collaboration in single molecule electronics |
| Impact | Publications in preparation. |
| Start Year | 2015 |
| Description | University of Oxford |
| Organisation | University of Oxford |
| Department | Physical and Theoretical Chemistry Laboratory |
| Country | United Kingdom |
| Sector | Academic/University |
| PI Contribution | Collaboration on porphyrin nanoelectronics (measurements). |
| Collaborator Contribution | Collaboration on porphyrin nanoelectronics (synthesis). |
| Impact | Publications as listed. |
| Start Year | 2006 |