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Calixarenes: Metal-Organic Frameworks and Discrete Superstructures

Lead Research Organisation: University of Edinburgh
Department Name: Sch of Chemistry

Abstract

Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.

Publications

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Martínez-Lillo J (2014) A family of cationic oxime-based hexametallic manganese(III) single-molecule magnets. in Dalton transactions (Cambridge, England : 2003)

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McDonald C (2015) Molecular Pac-Man and Tacos: layered Cu(II) cages from ligands with high binding site concentrations. in Dalton transactions (Cambridge, England : 2003)

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McIntosh R (2011) p-tert-Butylcalix[8]arene: A support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties in Dalton Transactions

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McLellan R (2014) Discovering the pivotal role of carbonate in the formation of a bis-phenolate supported Co15 cluster. in Chemical communications (Cambridge, England)

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McLellan R (2015) Linked supramolecular building blocks for enhanced cluster formation. in Chemistry (Weinheim an der Bergstrasse, Germany)

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McLellan R (2013) Cobalt(II) complexes of calix[6]arenes: Crystallographic studies into heteroatom bridge influence over discrete versus polymeric structure formation in Polyhedron

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McLellan R (2013) Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer in Dalton Transactions

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Palacios MA (2015) Facile interchange of 3d and 4f ions in single-molecule magnets: stepwise assembly of [Mn4 ], [Mn3Ln] and [Mn2Ln2 ] cages within calix[4]arene scaffolds. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Palacios MA (2014) Bifunctional Zn(II)Ln(III) dinuclear complexes combining field induced SMM behavior and luminescence: enhanced NIR lanthanide emission by 9-anthracene carboxylate bridging ligands. in Inorganic chemistry

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Sanz S (2012) Calix[4]arene-supported rare earth octahedra in Chem. Commun.

 
Description Synthesised a range of covalent organic nanocapsules with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Synthesised a range of multi-calixarene building blocks with appropriate functionality for the controlled combination with C[4]-supported polynuclear metal cluster motifs. Utilised nanometre scale building blocks to form novel families of polymeric metal-organic frameworks and discrete metal-organic superstructures.
Exploitation Route Fundamental chemistry and physics with potential future application in materials.
Sectors Chemicals
URL http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin