Nanoengineered Materials for Clean Catalytic Technologies
Lead Research Organisation:
CARDIFF UNIVERSITY
Department Name: Chemistry
Abstract
Catalysis lies at the heart of life on earth, powers our homes and puts food on our tables. However to a large degree our ability to transform individual atoms and molecules into new pharmaceutical medicines, fuels, and fertilisers has depended upon an equal combination of brilliant science and serendipitous discoveries. This reflects the complex interactions between reacting molecules and products, their surrounding environment, and of course the catalyst itself, which ideally remains unchanged over thousands of reaction cycles. Recent advances in chemical synthesis and analysis now offer an unprecedented opportunity to sculpt the atomic structure of solid catalysts and to peer inside their microscopic workings.Over the next five years, I propose to integrate these new experimental and theoretical breakthroughs with my own expertise in catalyst design and testing, to develop a new generation of nanoengineered materials for the clean production of valuable chemical feedstocks and sustainable biofuels. New collaborations, forged with world leaders in the areas of inorganic solid-state chemistry, nanoscale imaging and computer modelling, will help me to develop the multidisciplinary skillsets needed to achieve my vision of solid catalysts, tailored 'on demand', for efficient clean technologies that will benefit society over the coming decade.
Organisations
- CARDIFF UNIVERSITY (Lead Research Organisation)
- Syngenta International AG (Collaboration)
- Elettra Sincrotrone Trieste (Collaboration)
- University of York (Project Partner)
- BP (International) (Project Partner)
- Syngenta (Project Partner)
- DSM Research (The Netherlands) (Project Partner)
- BP (International) (Project Partner)
- European Synchrotron Radiation Facility (ESRF) (Project Partner)
Publications
Wilson K
(2012)
Catalysis for Alternative Energy Generation
Wilson K
(2012)
Rational design of heterogeneous catalysts for biodiesel synthesis
in Catalysis Science & Technology
Pirez C
(2012)
Tunable KIT-6 Mesoporous Sulfonic Acid Catalysts for Fatty Acid Esterification
in ACS Catalysis
Liu D
(2012)
On the impact of Cu dispersion on CO2 photoreduction over Cu/TiO2
in Catalysis Communications
Durndell LJ
(2013)
Tunable Pt nanocatalysts for the aerobic selox of cinnamyl alcohol.
in Nanoscale
Ayris P
(2013)
SO2 sequestration in large volcanic eruptions: High-temperature scavenging by tephra
in Geochimica et Cosmochimica Acta
Eze V
(2013)
Heterogeneous catalysis in an oscillatory baffled flow reactor
in Catalysis Science & Technology
Fairlamb I
(2013)
C-H and C-X Bond Functionalization - Transition Metal Mediation
Parlett C
(2013)
Hierarchically Ordered Nanoporous Pd/SBA-15 Catalyst for the Aerobic Selective Oxidation of Sterically Challenging Allylic Alcohols
in ACS Catalysis
Wainwright S
(2013)
True liquid crystal templating of SBA-15 with reduced microporosity
in Microporous and Mesoporous Materials
Related Projects
| Project Reference | Relationship | Related To | Start | End | Award Value |
|---|---|---|---|---|---|
| EP/G007594/1 | 01/03/2009 | 30/07/2009 | £1,351,103 | ||
| EP/G007594/2 | Transfer | EP/G007594/1 | 31/07/2009 | 30/07/2013 | £251,849 |
| EP/G007594/3 | Transfer | EP/G007594/2 | 31/07/2013 | 13/02/2014 | £257,739 |
| EP/G007594/4 | Transfer | EP/G007594/3 | 14/02/2014 | 12/04/2015 | £57,237 |
| Description | Selective catalytic transformations for agrochemicals |
| Organisation | Syngenta International AG |
| Country | Switzerland |
| Sector | Private |
| PI Contribution | Two part-sponsored PhD studentships have undertake fundamental research into the mechanism of palladium catalysed transformations and identified key factors controlling the catalytic performance and stability of nanoparticles. |
| Collaborator Contribution | Access to laboratories, intellectual guidance, provision of catalysts |
| Impact | One PhD graduated to date, and 2 peer-reviewed publications. |
| Start Year | 2009 |
| Description | Synchtrotron studies of nanostructured materials |
| Organisation | Elettra Sincrotrone Trieste |
| Country | Italy |
| Sector | Academic/University |
| PI Contribution | New research areas in catalysis and materials science developed resulting in numerous jointly authored publications over 17 years. |
| Collaborator Contribution | Access to synchtrotron facilities and training of 8 PhD students and PDRAs |
| Impact | Joint publications, contributions to annual highlights, invited seminar and Fonda-Fasella 2004 award |
