Quantum and Many Body Physics Enabled by Advanced Semiconductor Nanotechnology
Lead Research Organisation:
University of Sheffield
Department Name: Physics and Astronomy
Abstract
Light emitting semiconductor materials and devices dominate many aspects of everyday life. Their influence is all pervasive providing the sources which enable the internet, large area displays, room and street lighting to give just a few examples. Their existence relies on the high quality semiconductor structures which may be prepared by advanced crystal growth and sophisticated nanofabrication. Our proposal aims to capitalise on the advanced growth and fabrication to achieve similar advances in the quantum world where often counter-intuitive behaviour is governed solely by the laws of quantum mechanics.
Our overall aim is to explore the behaviour of nano-devices operating in regimes where fundamentally new types of quantum-photonic phenomena occur, with potential to underpin the next generation of quantum technologies. We focus on two complementary systems: III-V semiconductors with their highly perfect crystal lattices, proven ability to emit photons one by one and long coherence quantum states, and atomically-thin graphene-like two dimensional (2D) semiconductors enabling new band structures, stable electron-hole bound states (excitons) and easy integration with patterned structures. The combination of the two material systems is powerful enabling phenomena ranging from the single photon level up to dense many-particle states where interactions dominate. A significant part of our programme focusses on on-chip geometries, enabling scale-up as likely required for applications.
The semiconductor systems we employ interact strongly with photons; we will achieve interactions between photons which normally do not interact. We will gain entry into the regime of highly non-linear cavity quantum electrodynamics. Excitons (coupled electron-hole pairs) and photons interact strongly, enabling ladders of energy levels leading to on-chip production of few photon states. By coupling cavities together, we will aim for highly correlated states of photons. These advances are likely to be important components of photonic quantum processors and quantum communication systems.
In similar structures, we access regimes of high density where electrons and holes condense into highly populated states (condensates). We aim to answer long-standing fundamental questions about the types of phase transitions that can occur in equilibrium systems and in out-of-equilibrium ones which have loss balanced by gain. We will also study condensate systems up to high temperatures, potentially in excess of 100K, and of the mechanisms underlying phase transitions to condensed states. The condensed state systems, besides their fundamental interest, also have potential as new forms of miniature coherent light sources.
Nanofabrication will play a vital role enabling confinement of light on sub-wavelength length scales and fabrication of cavities for photons such that they have very long lifetimes before escaping. The ability to place high quality emitters within III-V nanophotonic structures will receive enhancement and potential world lead from a crystal growth machine we have recently commissioned, specially designed for this purpose, funded by the UK Quantum Technologies programme. Similar impact is expected from our ability to prepare 2D heterostructures (atomically thin layers of two separate materials placed one on top of the other) under conditions of ultrahigh vacuum free from contamination, enabling realisation of bound electron-hole pair states of very long lifetime, the route to condensation to high density states. The easy integration of 2D heterostructures with patterned photonic structures furthermore enables nonlinear and quantum phenomena to be studied, including in topological structures where light flow is immune to scattering by defects.
Taken all together we have the ingredients in place to achieve ground-breaking advances in fundamental quantum photonics with considerable potential to underpin next generations of quantum technologies.
Our overall aim is to explore the behaviour of nano-devices operating in regimes where fundamentally new types of quantum-photonic phenomena occur, with potential to underpin the next generation of quantum technologies. We focus on two complementary systems: III-V semiconductors with their highly perfect crystal lattices, proven ability to emit photons one by one and long coherence quantum states, and atomically-thin graphene-like two dimensional (2D) semiconductors enabling new band structures, stable electron-hole bound states (excitons) and easy integration with patterned structures. The combination of the two material systems is powerful enabling phenomena ranging from the single photon level up to dense many-particle states where interactions dominate. A significant part of our programme focusses on on-chip geometries, enabling scale-up as likely required for applications.
The semiconductor systems we employ interact strongly with photons; we will achieve interactions between photons which normally do not interact. We will gain entry into the regime of highly non-linear cavity quantum electrodynamics. Excitons (coupled electron-hole pairs) and photons interact strongly, enabling ladders of energy levels leading to on-chip production of few photon states. By coupling cavities together, we will aim for highly correlated states of photons. These advances are likely to be important components of photonic quantum processors and quantum communication systems.
In similar structures, we access regimes of high density where electrons and holes condense into highly populated states (condensates). We aim to answer long-standing fundamental questions about the types of phase transitions that can occur in equilibrium systems and in out-of-equilibrium ones which have loss balanced by gain. We will also study condensate systems up to high temperatures, potentially in excess of 100K, and of the mechanisms underlying phase transitions to condensed states. The condensed state systems, besides their fundamental interest, also have potential as new forms of miniature coherent light sources.
Nanofabrication will play a vital role enabling confinement of light on sub-wavelength length scales and fabrication of cavities for photons such that they have very long lifetimes before escaping. The ability to place high quality emitters within III-V nanophotonic structures will receive enhancement and potential world lead from a crystal growth machine we have recently commissioned, specially designed for this purpose, funded by the UK Quantum Technologies programme. Similar impact is expected from our ability to prepare 2D heterostructures (atomically thin layers of two separate materials placed one on top of the other) under conditions of ultrahigh vacuum free from contamination, enabling realisation of bound electron-hole pair states of very long lifetime, the route to condensation to high density states. The easy integration of 2D heterostructures with patterned photonic structures furthermore enables nonlinear and quantum phenomena to be studied, including in topological structures where light flow is immune to scattering by defects.
Taken all together we have the ingredients in place to achieve ground-breaking advances in fundamental quantum photonics with considerable potential to underpin next generations of quantum technologies.
Organisations
- University of Sheffield (Lead Research Organisation)
- Pittsburg State University (Collaboration)
- UNIVERSITY OF MANCHESTER (Collaboration)
- Swiss Federal Institute of Technology in Lausanne (EPFL) (Collaboration)
- Blaise Pascal University (Collaboration)
- Queen's University (Collaboration)
- AegiQ (Collaboration, Project Partner)
- University of Exeter (Collaboration)
- University of Strathclyde (Collaboration)
- Ossila (Project Partner)
- Chase research Cryogenics Ltd (Project Partner)
- A-Modelling Solutions Ltd (Project Partner)
- NIMS (Project Partner)
- Ludwig-Maximilians-Universität München (Project Partner)
- University of Oxford (Project Partner)
- ITMO University (Project Partner)
- City College of New York (Project Partner)
Publications
Dagvadorj G
(2021)
First-order dissipative phase transition in an exciton-polariton condensate
Sala EM
(2021)
Droplet epitaxy of InAs/InP quantum dots via MOVPE by using an InGaAs interlayer.
in Nanotechnology
Comaron P
(2021)
Non-equilibrium Berezinskii-Kosterlitz-Thouless transition in driven-dissipative condensates (a)
in Europhysics Letters
Dagvadorj G
(2021)
First-order dissipative phase transition in an exciton-polariton condensate
in Physical Review B
Whittaker C
(2021)
Optical and magnetic control of orbital flat bands in a polariton Lieb lattice
in Physical Review A
Ovenden C
(2021)
Nanoscale wafer patterning using SPM induced local anodic oxidation in InP substrates
in Semiconductor Science and Technology
Deuar P
(2021)
Fully Quantum Scalable Description of Driven-Dissipative Lattice Models
in PRX Quantum
Kuriakose T
(2021)
Few-photon all-optical phase rotation in a quantum-well micropillar cavity
Whittaker C
(2021)
Exciton-polaritons in GaAs-based slab waveguide photonic crystals
in Applied Physics Letters
Sala E
(2021)
Effect of Cap Thickness on InAs/InP Quantum Dots Grown by Droplet Epitaxy in Metal-Organic Vapor Phase Epitaxy
in physica status solidi (RRL) - Rapid Research Letters
Lyons T
(2022)
Giant effective Zeeman splitting in a monolayer semiconductor realized by spin-selective strong light-matter coupling
in Nature Photonics
Zotev P
(2022)
Van der Waals Materials for Applications in Nanophotonics
Gajjela RSR
(2022)
Control of Morphology and Substrate Etching in InAs/InP Droplet Epitaxy Quantum Dots for Single and Entangled Photon Emitters.
in ACS applied nano materials
Delphan A
(2022)
Polariton lasing in AlGaN microring with GaN/AlGaN quantum wells
Hallett D
(2022)
Engineering Chiral Light-Matter Interactions in a Waveguide-Coupled Nanocavity
in ACS Photonics
Flower C
(2022)
Topological Edge Mode Tapering
Lovett S
(2022)
Observation of Zitterbewegung in photonic microcavities
Ferrier A
(2022)
Searching for the Kardar-Parisi-Zhang phase in microcavity polaritons
in Physical Review B
Li F
(2022)
Condensation of 2D exciton-polaritons in an open-access microcavity
in Journal of Applied Physics
| Title | Making quantum light with quantum dots |
| Description | Animation video to show how quantum dots can be used for generation of quantum light |
| Type Of Art | Film/Video/Animation |
| Year Produced | 2022 |
| Impact | 17 K views, 6.5 K subscribers to channel "Quantum Light University of Sheffield" |
| URL | https://www.youtube.com/watch?time_continue=117&v=fqSUDLTjaCA&embeds_referring_euri=https%3A%2F%2Fww... |
| Title | Twistronics: building moiré superlattices from 2D materials |
| Description | Animation on electronic properties of 2D materials. When ultrathin two-dimensional materials are stacked together to build designer nanomaterials, they can be twisted relative to one another, such that the atoms in each layer line up differently. This twisting, which is not possible in most present-day thin film nanotechnology, can lead to enormous changes of the material properties. The great potential on offer has given rise to a new field of scientific research termed "twistronics", which seeks to discover new functionality by taking two-dimensional materials and adding a twist. |
| Type Of Art | Film/Video/Animation |
| Year Produced | 2023 |
| Impact | >6.2 k views on youtube channel. |
| URL | https://www.youtube.com/watch?v=yuwuyzHhrho |
| Description | 1) Hybridisation of 2D excitons and photons in microresonators enables strong effective photon-photon interactions. For quantum optical signal processing with photon qubit strong interactions are required for manipulating the state (phase) of one photon with another. We report that one photon may induce a phase shift up to 150 mRad in another photon, which is very promising for constructing quantum gates in quantum computing architectures if single photon phase shift devices are cascaded in a special way. The scalability of such devices is ensured by the 2D excitonic natures in semiconductor nanostructures. 2) Quantum dots can be coupled together coherently within waveguides to produce super-radiant emission in which the lifetime is shorter than for individual dots. This coherent coupling of two quantum dots is the first step in the road map towards building large networks of coupled dots for observing many-body physics. The step was made possible by very advanced nanofabrication methods that enabled separate tuning of two dots on the same chip, thus enabling us to tune the dots to resonance with each other. 3) We have demonstrated that chiral effects can be enhanced by using glide-plane nano-photonic waveguides. The goal here is to demonstrate that the direction of the emission from a quantum dot can be linked to the spin, as the basis for quantum spin networks. In previous work we demonstrated high directionality, but the coupling between the waveguide mode and the quantum emitter was not strong enough. The use of the glide-plane waveguide enhances the coupling through the Purcell effect in the slow light region. We have shown a world-best Purcell effect of 5 for a chiral dot, and are working to increase this further in the next generation devices. 4) We have employed bulk Van der Waals materials for fabrication of topological photonic crystals and waveguides. The advantage of Van der Waals materials is that they can be integrated with any type of substrate and incorporate optically active nonlinear 2D materials and other crystalline thin films though van der Waals bonding, which is important for future development of nonlinear and quantum photonics. We fabricated Z2 topological photonic crystal (honeycomb lattice) out of ~100 nm thick film of WS2 positioned on SiO2 substrate and observed circularly polarised edge modes at the interface between trivial/topological crystal lattices. 5) We studied the physics of flat band in Lieb polariton photonic lattices. Flat bands play a significant role in many physics phenomena, including ferromagnetism, superconductivity and photonics. By employing resonant pumping of the flat band we observed that the giant polariton nonlinearity stabilizes compacton (localised state formed in the flat band) and leads to its pumping preferential over the dispersive bands. 6) We demonstrate the appearance of an analogue Zitterbewegung effect, a term which translates as 'trembling motion' in English, which was originally proposed for relativistic Dirac electrons and consisted of the oscillations of the centre of mass of a wavepacket in the direction perpendicular to its propagation. We present and experimentally study the effects of the photonic spin-orbit coupling on the real space propagation of polariton wavepackets in planar semiconductor microcavities and polaritonic analogues of graphene. In particular, for a planar microcavity, we observe regular Zitterbewegung oscillations whose amplitude and period depend on the wavevector of the polaritons. We then extend these results to a honeycomb lattice of coupled microcavity resonators. |
| Exploitation Route | We anticipate that companies working on realisation of quantum optical computes (for example, Aegiq, Xanadu, PsiQuantum to name just a few) may benefit from our discoveries. Currently, photonic quantum architectures rely on two photon interferences, which enables realisation of probabilistic quantum gates. Introducing scalable nonlinear elements enabling strong photon-photon interactions and hence quantum non-demoliation measurements or deterministic photon entanglement, may possibly result in more advance and functional quantum photonic architecture, which is more efficient and consume much less resources. More research on scalability and integration of hybrid exciton-photonic devices in photonic circuits is required to push such a realisation forward. |
| Sectors | Digital/Communication/Information Technologies (including Software) Electronics |
| Description | There are several aspects to this. Firstly, a spin-out company from the University of Sheffield Aegiq has been established by former Sheffield PhD students and postdocs in 2019 as a result of fundamental quantum optics discoveries and technological developments conducted in our group. This company specialises in high frequency single photon sources and integrated quantum optical circuits for future quantum communications and computing. Since then the company has attracted a significant amount of funding. Since our graduates and postdocs receive training in advanced spectroscopic methods, semiconductor device fabrication and growth, they are particularly attractive for the growing semiconductor quantum industry. This can be judged by the fact that many former Sheffield group members (about 10) have been employed by Aegiq in the last 3-5 years. Aegiq continues close interaction with the academics working on the Programme grant and there have been ongoing discussions about transformation of laboratory research into real world applications. This concerns research on single photon nonlinearities in hybrid light-matter systems and use of 0D tunable microresonators for efficient high frequency single photon generation. Prof. Pieter Kok, who provides theory support to the Programme grant research, is also employed part-time in Aegiq working on quantum photonic circuiting utilising extended entangled photonic (cluster) states. As part of our programme on 2D material technology, there is close interaction between the Sheffield team (Tartakovskii group) and Manchester spin-out company Graphene Industries (see letter of engagement). As part of this interaction, the Graphene industry continues optimization of its glove box for 2D material transfer and heterostructure assembly. |
| Sector | Digital/Communication/Information Technologies (including Software),Electronics |
| Impact Types | Societal Economic Policy & public services |
| Description | Consultation with Department of Digital Culture Media and Sports and latterly Department of Science Innovation and Technology on the Semiconductor Strategy and the ongoing consultations on the Industrial Strategy |
| Geographic Reach | National |
| Policy Influence Type | Contribution to a national consultation/review |
| URL | https://assets.publishing.service.gov.uk/media/66599c1f0c8f88e868d3343c/national_semiconductor_strat... |
| Title | Development of tunable open cavity setup where light can be confined to a scale of 1 micrometer. |
| Description | The open cavity setups consist of two mirrors controlled by nanopiezopositioners. These mirrors enable enable very strong polariton confinement in all three dimensions leading to realisation of single polariton nonlinearity |
| Type Of Material | Technology assay or reagent |
| Year Produced | 2021 |
| Provided To Others? | No |
| Impact | This research tool has had only academic impact for now, enabling observation of single polariton nonlinearity (publication in Nature Photonics 2022). Potentially, it paves the way towards development of nonlinear quantum optical devices. |
| Title | Membrane fabrication methods for Vertical Cavity Semiconductor Lasers VCSELs) |
| Description | To facilitate the use of transfer print methods in this project, we have made progress on the development of separable membranes containing VCSEL devices. These devices will form a major part of this grant, but more generically the ability to transfer print operating VCSELs will be broadly applicable to other application areas. The capability will eventually be made available to all UK researchers through the National Epitaxy Facility |
| Type Of Material | Improvements to research infrastructure |
| Year Produced | 2021 |
| Provided To Others? | No |
| Impact | Too early in grant at this time, but further opportunities are being investigated. |
| Title | New techniques for epitaxy of quantum dots |
| Description | Demonstration of InAs/InP quantum dots on a multi-wafer MOVPE reactor has added to the capability of the EPSRC National Epitaxy Facility, and will be use to support other UK researchers in the field through the Facilities access model. |
| Type Of Material | Improvements to research infrastructure |
| Year Produced | 2017 |
| Provided To Others? | Yes |
| Impact | With the first demonstration of an entangled LED light source and further improvements to the epitaxy method, the work will lead to increased interest among industrial collaborators in the development of single photon sources for quantum telecommunications now that results have been demonstrated by a commercially viable epitaxy technique. Ongoing development (as of 2025) of InAs QD technology for telecoms wavelengths at 1550nm and by the commercially suitable MOVPE epitaxy technique has been supported by a number of grants on quantum technologies, and their close relationship with the National Epitaxy Facility in Sheffield. There is an ongoing roadmap of technical developments required including improved single and entangled photon coherence, improved yield, and the development of site-controlled techniques to allow precise placement of ultra-high quality QDs on a semiconductor wafer allowing the development of quantum integrated circuits. |
| URL | http://www.nationalepitaxyfacility.co.uk |
| Title | Nonlinear optical experiment using UV ultrafast laser. Fabrication of grating in- and out-couplers |
| Description | To perform the nonlinear optical experiment we used 100 fs pulsed laser at 800 nm and rep rate of 80 MHz. It was further amplified by 10000 using Spitfire Spectra-Physics amplifier and then pulses were converted to 345 nm using optical parametric amplifier (TOPAS of Lightconversion). The GaN waveguide is excited resonantly using grating couplers and spectrum of light in energy and momentum space is monitored as a function of power from the other outcoupler. |
| Type Of Material | Improvements to research infrastructure |
| Year Produced | 2019 |
| Provided To Others? | No |
| Impact | The research method allows investugate spatio-temporal soliton dynamics in various planar waveguide systems. |
| Title | Ultrafast two color laser spectroscopy |
| Description | We developed a new technique to probe excitations on top of analog black hole arising from vortex superfluid. One high power pump creates high density large orbital angular momentum vortex ("black hole"). The other laser probes the excitations at higher frequencies than that of the pump. Synchronization of two independent laser pulses is required, which we achieved using Spectra Physics lock-to-clock systems. Filtering of high intensity pump is performed in k-space and using spectrometer. |
| Type Of Material | Improvements to research infrastructure |
| Year Produced | 2024 |
| Provided To Others? | No |
| Impact | Overall, this new method can be used to probe excitations in photonic and polaritonic condensates. |
| Title | pump-probe experiments on observation of parametrically stimulated polariton blockade |
| Description | We synchronised to pulsed lasers at different frequencies in order to observe stimulated scattering of pump polaritons to the lower and higher energy states in a micropillar. Employed pulsed lasers with different frequencies in order to observe cross-phase-modulation between single photons. |
| Type Of Material | Technology assay or reagent |
| Year Produced | 2019 |
| Provided To Others? | No |
| Impact | No impact yet |
| Title | Controlling cooperative emission and superradiance in waveguide-coupled quantum dots |
| Description | Experimental data supporting figures shown in the paper: Controlling cooperative emission and superradiance in waveguide-coupled quantum dotsPreprint available at: https://arxiv.org/abs/2410.17890Abstract: We report the measurement of collective emission from a pair of independently tuneable InAs quantum dots embedded in a nanophotonic waveguide. A split diode structure allows independent electrical control of the quantum dot transition energies over a wide range with minimal loss in waveguide coupling efficiency. We utilise this to systematically map out the transition from collective to independent emission. We perform both lifetime as well as Hanbury Brown-Twiss measurements on the device, observing anti-dips in the photon coincidences indicating collective emission while at the same time observing a drop in lifetime around zero detuning, indicating superradiant behaviour. Performing both measurement types allows us to investigate detuning regions which show both superradiant rate enhancement and inter-emitter coherence, as well as regions in which correlations persist in the absence of rate enhancement. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2024 |
| Provided To Others? | Yes |
| URL | https://orda.shef.ac.uk/articles/dataset/Controlling_cooperative_emission_and_superradiance_in_waveg... |
| Title | Data for Nonlinear Rydberg exciton-polaritons in Cu2O microcavities |
| Description | Experimental data for the Light: Science & Applications article "Nonlinear Rydberg exciton-polaritons in Cu2O microcavities" |
| Type Of Material | Database/Collection of data |
| Year Produced | 2024 |
| Provided To Others? | Yes |
| URL | https://orda.shef.ac.uk/articles/dataset/Data_for_Nonlinear_Rydberg_exciton-polaritons_in_Cu2O_micro... |
| Title | Data for Nonlinear Rydberg exciton-polaritons in Cu2O microcavities |
| Description | Experimental data for the Light: Science & Applications article "Nonlinear Rydberg exciton-polaritons in Cu2O microcavities" |
| Type Of Material | Database/Collection of data |
| Year Produced | 2024 |
| Provided To Others? | Yes |
| URL | https://orda.shef.ac.uk/articles/dataset/Data_for_Nonlinear_Rydberg_exciton-polaritons_in_Cu2O_micro... |
| Title | Dataset for "Spin-order-dependent magneto-elastic coupling in two dimensional antiferromagnetic MnPSe3 observed through Raman spectroscopy" |
| Description | Input files for the open source Quantum Espresso and Phonopy codes (and the required pseudopotentials) are provided to reproduce the calculations presented in the associated paper, with the following abstract. Layered antiferromagnetic materials have emerged as a novel subset of the two dimensional family with promising physical properties which provide a highly accessible framework in which to examine a multitude of phenomena arising from a unique combination of low dimensionality, fast spin dynamics and a robustness to external magnetic fields. Specifically, materials such as metal thiophosphates, MPX$_3$ (M = group VIIB or VIII element, X = chalcogen element), hold a lot of promise for investigating fundamental interactions between magnetic and lattice degrees of freedom, and for the exploration of developing fields such as spintronics and magnonics. Here, we use a combination of temperature dependent Raman spectroscopy and density functional theory to explore ordering-dependent interactions between the antiferromagnetic manganese spin degree of freedom and lattice vibrations via a super-exchange pathway in both bulk and few layer manganese phosphorous triselenide (MnPSe$_3$) from 5-250 K including the Ne{\'e}l transition temperature of 74 K. We observe a non-linear temperature dependent shift of all seven Raman active phonon lines, including two magnetic modes (84 cm$^{-1}$ and 109 cm$^{-1}$), a hybridised two-magnon mode (126 cm$^{-1}$) and four lesser studied vibrational modes predominantly associated with the non-magnetic sub-lattice (143 cm$^{-1}$, 156 cm$^{-1}$, 173 cm$^{-1}$, and 221 cm$^{-1}$) which possess a non-trivial spin-phonon coupling below the Ne{\'e}l temperature. Using an analytical approach consisting of combining anharmonic temperature dependent shifts with magnetic-specific Brillouin function fitting to these four phonon lines, we extract a spin-phonon coupling constant for each mode. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2023 |
| Provided To Others? | Yes |
| URL | https://researchdata.bath.ac.uk/id/eprint/1218 |
| Title | Dataset for Few-photon all-optical phase rotation in a quantum-well micropillar cavity |
| Description | Dataset for Few-photon all-optical phase rotation in a quantum-well micropillar cavity |
| Type Of Material | Database/Collection of data |
| Year Produced | 2022 |
| Provided To Others? | Yes |
| URL | https://figshare.shef.ac.uk/articles/dataset/Dataset_for_Few-photon_all-optical_phase_rotation_in_a_... |
| Title | Dataset for Observation of Zitterbewegung in photonic microcavities |
| Description | Dataset for Observation of Zitterbewegung in photonic microcavities |
| Type Of Material | Database/Collection of data |
| Year Produced | 2023 |
| Provided To Others? | Yes |
| URL | https://figshare.shef.ac.uk/articles/dataset/Dataset_for_Observation_of_Zitterbewegung_in_photonic_m... |
| Title | Raw Data for: Spin-order-dependent magneto-elastic coupling in two dimensional antiferromagnetic MnPSe3 observed through Raman spectroscopy |
| Description | Layered antiferromagnetic materials have recently emerged as an intriguing subset of the two-dimensional family providing a highly accessible regime with prospects for layer-number-dependent magnetism. Furthermore, transition metal phosphorus trichalcogenides, MPX3 (M= transition metal; X= chalcogen) provide a platform on which to investigate fundamental interactions between magnetic and lattice degrees of freedom and further explore the developing fields of spintronics and magnonics. Here, we use a combination of temperature dependent Raman spectroscopy and density functional theory to explore magnetic-ordering-dependent interactions between the manganese spin degree of freedom and lattice vibrations of the non-magnetic sub-lattice via a Kramers-Anderson super-exchange pathway in both bulk, and few-layer, manganese phosphorus triselenide (MnPSe3). We observe a nonlinear temperature dependent shift of phonon modes predominantly associated with the non-magnetic sub-lattice, revealing their non-trivial spin-phonon coupling below the N'eel temperature at 74 K, allowing us to extract mode-specific spin-phonon coupling constants. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2023 |
| Provided To Others? | Yes |
| URL | https://orda.shef.ac.uk/articles/dataset/Raw_Data_for_Spin-order-dependent_magneto-elastic_coupling_... |
| Title | Raw Data for: Spin-order-dependent magneto-elastic coupling in two dimensional antiferromagnetic MnPSe3 observed through Raman spectroscopy |
| Description | Layered antiferromagnetic materials have recently emerged as an intriguing subset of the two-dimensional family providing a highly accessible regime with prospects for layer-number-dependent magnetism. Furthermore, transition metal phosphorus trichalcogenides, MPX3 (M= transition metal; X= chalcogen) provide a platform on which to investigate fundamental interactions between magnetic and lattice degrees of freedom and further explore the developing fields of spintronics and magnonics. Here, we use a combination of temperature dependent Raman spectroscopy and density functional theory to explore magnetic-ordering-dependent interactions between the manganese spin degree of freedom and lattice vibrations of the non-magnetic sub-lattice via a Kramers-Anderson super-exchange pathway in both bulk, and few-layer, manganese phosphorus triselenide (MnPSe3). We observe a nonlinear temperature dependent shift of phonon modes predominantly associated with the non-magnetic sub-lattice, revealing their non-trivial spin-phonon coupling below the N'eel temperature at 74 K, allowing us to extract mode-specific spin-phonon coupling constants. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2023 |
| Provided To Others? | Yes |
| URL | https://orda.shef.ac.uk/articles/dataset/Raw_Data_for_Spin-order-dependent_magneto-elastic_coupling_... |
| Description | Collaboration with Prof Stephen Hughes, Queen's University, Canada |
| Organisation | Queen's University |
| Country | Canada |
| Sector | Academic/University |
| PI Contribution | Experimental studies of topological photonic waveguides |
| Collaborator Contribution | Theory input for studies of topological photonic waveguides |
| Impact | Journal article: Topological and conventional nanophotonic waveguides for directional integrated quantum optics Phys. Rev. Research 6, L022065 - Published 20 June, 2024 DOI: https://doi.org/10.1103/PhysRevResearch.6.L022065 |
| Start Year | 2023 |
| Description | Collaboration with Prof. D Snoke from the University of Pittsburg, USA |
| Organisation | Pittsburg State University |
| Country | United States |
| Sector | Academic/University |
| PI Contribution | Optical measurements of polariton propagation, condensation and optical parametric scattering in microcavity samples with long lifetime >100 ps. |
| Collaborator Contribution | Supply of high quality GaAs-based microcavity sample with low photonic spatial disorder and long polariton lifetime to realise analogue black hole using polariton superfluids |
| Impact | NA |
| Start Year | 2022 |
| Description | Collaboration with the group of Nicolas Gradjean at EPFL, Lausanne, Switzerland to study nonlinear polariton phases in GaN polariton slab waveguides |
| Organisation | Swiss Federal Institute of Technology in Lausanne (EPFL) |
| Country | Switzerland |
| Sector | Public |
| PI Contribution | The nonlinear experiments on GaN waveguide polariton samples. Fabrication of in-couplers and out-couplers in GaN waveguides using electron-beam lithography. |
| Collaborator Contribution | The Lausanne group supplied Sheffield group with high quality AlGaN waveguide samples with multiple GaN quantum wells, which were grown by MOCVD technique. General contribution in data analysis and interpretation. |
| Impact | Observation of strong exciton-photon coupling and the resultant polaritons in GaN -based waveguides at high temperature up to 300 K. Observation of continuum generation in polariton waveguides at T up to 300 K. Observation of modulational polariton instabilities at T up to 300 K. Observation of non-linear diffraction. |
| Start Year | 2018 |
| Description | Collaboration with the group of Prof. Gorbachev from Uni of Manchester and Graphene institute |
| Organisation | University of Manchester |
| Country | United Kingdom |
| Sector | Academic/University |
| PI Contribution | The University of Sheffield is conducting investigation of light-matter interactions and novel many body photon, exciton and polariton phases in photonic structures with embedded 2D material heterostructures, which are fabricated in the group of Gorbachev |
| Collaborator Contribution | The group of Prof. Gorbachev is working on fabrication of high quality gated heterostructures made of various monolayers of transition metal dichalcogenides , graphene and hBN. These structures are being made in ultra high vacuum or inert gas to avoid possible contamination and ensure the highest optical properties. High quality structures are essential for investigation of light-matter interactions and many body photon and polariton phases in photonic structures with embedded 2D material heterostructures. These optical studies are conducted at the University of Sheffield. |
| Impact | NA |
| Start Year | 2021 |
| Description | Collaboration with the theory group of Prof. Dmitry Sonyshkov from the Université Blaise Pascal, France |
| Organisation | Blaise Pascal University |
| Country | France |
| Sector | Academic/University |
| PI Contribution | We have initiated the experiment on the realisation of analogue black holes in semiconductor microcavities. We pumped our system with an optical vortex at high density, which realises supersonic/subsonic transition near the analogue black hole core. |
| Collaborator Contribution | The group of Solnyshkov is providing the theoretical interpretation and modelling of the observed results. |
| Impact | NA |
| Start Year | 2023 |
| Description | Collaboration with the theory group of Prof. Oleksandr Kyriienko from the University of Exeter, UK |
| Organisation | University of Exeter |
| Country | United Kingdom |
| Sector | Academic/University |
| PI Contribution | My group performed experiments on the observation of single photon phase shift in semiconductor polariton microcavities, when the linear polarisation of one polariton is observed to rotate due to present of another circularly polarised polariton arising from giant spin-dependent polariton-polariton interactions. The induced phase up to 3 mrad per particle is observed, which can be increased further by a factor of 10-100 in state of the art microcavities with smaller photonic confinement and higher Q-factor. |
| Collaborator Contribution | The group of professor Kyriienko provided theoretical support for interpretation of the results on single photon phase shifts in polariton semiconductor micropillars with embedded 2D InGaAs quantum wells. In particular, they showed that using the state of the art polariton micropillars and cascading them into a chain connected by one-way propagating mode it should be possible to construct C-Phase quantum gate with a fidelity near 99%, which paves the way towards development of active and scalable photonic devices. |
| Impact | 1. Few-photon all-optical phase rotation in a quantum-well micropillar cavity Tintu Kuriakose, Paul M. Walker, Toby Dowling, Oleksandr Kyriienko, Ivan A. Shelykh, Phillipe St-Jean, Nicola Carlon Zambon, Aristide Lemaître, Isabelle Sagnes, Luc Legratiet, Abdelmounaim Harouri, Sylvain Ravets, Maurice S. Skolnick, Alberto Amo, Jacqueline Bloch & Dmitry N. Krizhanovskii Nature Photonics volume 16, pages566-569 (2022) 2. Nonlinear Quantum Optics with Trion Polaritons in 2D Monolayers: Conventional and Unconventional Photon Blockade O. Kyriienko, D. N. Krizhanovskii, and I. A. Shelykh Phys. Rev. Lett. 125, 197402 - Published 5 November 2020 3. Highly nonlinear trion-polaritons in a monolayer semiconductor RPA Emmanuele, M Sich, O Kyriienko, V Shahnazaryan, F Withers, ...Nature communications 11 (1), 3589 (2020) |
| Start Year | 2018 |
| Description | Industrial collaboration AegiQ |
| Organisation | AegiQ |
| Country | United Kingdom |
| Sector | Private |
| PI Contribution | Joint development of designs for single photon sources based to quantum dots |
| Collaborator Contribution | Joint development of designs for single photon sources based to quantum dots |
| Impact | Several iterations of designs and test have bene done collaboratively with Aegiq. As a result of the scientific collaboration Aegiq has become a commercial customer of the National Epitaxy Facility, and is a collaborators on a number of UKRI grants with other industrial partners. |
| Start Year | 2022 |
| Description | Strathclyde-Sheffield collaboration on Transfer Print of lasers and quantum emitters |
| Organisation | University of Strathclyde |
| Country | United Kingdom |
| Sector | Academic/University |
| PI Contribution | Ongoing development of transfer print processes through Photonics Hub spoke funding has led to a new EPSRC grant on Photonic Interconnects on CMOS between Sheffield and Strathclyde. Further collaboration with Starghclcyde on transfer printing of a variety of devices including detectors, VCSELs, and quantum emitters has been ongoing and new capabilities have been established through grants |
| Collaborator Contribution | Strathclyde have provided the advanced transfer print processes for transferring lasers onto new substrates as well as design concepts Sheffield has contributed the development of bespoke epitaxy for transfer print membranes and the development of processes for the fabrication of membranes as a result of collaborative grants. Sheffield has installed in the National Epitaxy Facility in 2023 a commercial transfer print tool to drive capabilities in Heterogeneous integration of III-Vs and Silicon photonics, including for applications in quantum technologies. Further collaborations with Strathclyde is envisaged including tech transfer form Strathclyde to Sheffield's commercial tool available to all users in the UK. |
| Impact | New EPSRC grant funded in 2021: EP/V005022/1 EP/V004859/1 In addition the results of this collaboration were used to prepare a proposal for inclusion of a commercial era ever print tool in the National Epitaxy Facility (NEF) at Sheffield, which was subsequently installed in 2023. The tool is now being used to support the large number of NEF users on research for heterogeneous integration of semiconductors. This direction is a major focus of the UK Government's National Semiconductor strategy. |
| Start Year | 2019 |
| Title | SINGLE PHOTON SOURCES |
| Description | A single photon source comprises a photon emitter (10), an excitation waveguide (30) arranged to direct excitation photons having a first polarisation direction into the photon emitter, and a collection waveguide (42) arranged to collect photons having a second polarisation direction from the photon emitter. The first polarisation direction is coupled to a first exciton state of the photon emitter and the second polarisation direction is non-parallel to the first polarisation direction and is coupled to a second exciton state of the photon emitter, and the first and second exciton states have substantially equal energies. |
| IP Reference | US2022381979 |
| Protection | Patent / Patent application |
| Year Protection Granted | 2022 |
| Licensed | Yes |
| Title | Code for Nonlinear Rydberg exciton-polaritons in Cu2O microcavities |
| Description | code for the Light: Science & Applications article "Nonlinear Rydberg exciton-polaritons in Cu2O microcavities" |
| Type Of Technology | Software |
| Year Produced | 2024 |
| URL | https://orda.shef.ac.uk/articles/software/Code_for_Nonlinear_Rydberg_exciton-polaritons_in_Cu2O_micr... |
| Title | Code for Nonlinear Rydberg exciton-polaritons in Cu2O microcavities |
| Description | code for the Light: Science & Applications article "Nonlinear Rydberg exciton-polaritons in Cu2O microcavities" |
| Type Of Technology | Software |
| Year Produced | 2024 |
| URL | https://orda.shef.ac.uk/articles/software/Code_for_Nonlinear_Rydberg_exciton-polaritons_in_Cu2O_micr... |
| Description | Animations - Quantum Light University of Sheffield YouTube channel |
| Form Of Engagement Activity | Engagement focused website, blog or social media channel |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Schools |
| Results and Impact | Quantum Light University of Sheffield YouTube channel - 5.77k subscribers Recent animations - 2023 - Twistronics: building moiré superlattices from 2D materials - 846 views (Jan 2023) 2022 - Making Quantum Light with Quantum Dots - 6.5k views (Jan 2023) |
| Year(s) Of Engagement Activity | 2022,2023 |
| URL | https://www.youtube.com/@quantumlightuniversityofsh5496 |
| Description | Cheltenham Science Festival (dates of event 04-09/06/2024). |
| Form Of Engagement Activity | Participation in an activity, workshop or similar |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Public/other audiences |
| Results and Impact | We presented at the Cheltenham Science Festival (dates of event 04-09/06/2024). Our exhibit was situated in the "Discover Zone" which was one of three, free to enter zones. Over the week, 12,770 visited the Discover Zone, which was the most popular of the free zones, and nearly a 50% increase on the previous year's festival. Additionally, 3,650 of these visitors were school children attending from 97 schools. Due to our part in the success of the event, we have been invited back next year. |
| Year(s) Of Engagement Activity | 2024 |
| Description | Contribution to Royal Academy of Engineering report on Infrastructure needs for the National Quantum Technology Programme |
| Form Of Engagement Activity | A formal working group, expert panel or dialogue |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Policymakers/politicians |
| Results and Impact | A report by the Royal Academy of Engineering on Infrastructure needs for the National Quantum Technology Programme. This was review of ongoing needs and investment opportunities that contributed to Phase III of the National Quantum technology Programme particularly in relation to industrial scale-up and commercial exploitations of quantum technology R&D. Consultation involved 1-2-1 interviews and attendance at a number of RAEng workshops. |
| Year(s) Of Engagement Activity | 2023,2024 |
| URL | https://raeng.org.uk/media/rrqjm2v3/quantum-infrastructure-review.pdf |
| Description | Creating an Innovation Pipeline for Compound Semiconductors in the UK |
| Form Of Engagement Activity | Participation in an activity, workshop or similar |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Professional Practitioners |
| Results and Impact | Under the auspices of the National Epitaxy Facility and supported by the Photonics Manufacturing Hub, a one day workshop on the infrastructure available to support innovation in compound semiconductors int he UK was held in February 2022. The meeting was online and attracted over 180 delegates from both academia, industry, government and research councils. Outputs of the meeting are being actively fed into government consultations and will be followed up in summer 2022. |
| Year(s) Of Engagement Activity | 2022 |
| URL | https://www.nationalepitaxyfacility.co.uk/news-events/ |
| Description | Formation of an All-party Parliamentary Group (APPG) on Semiconductors |
| Form Of Engagement Activity | A formal working group, expert panel or dialogue |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Policymakers/politicians |
| Results and Impact | In 2024 a new APPG on semiconecutors was formed to create a body that can inform and advise MPs on the importance of the semiconductor industry in the Uk and the opportunities available for UK researchers and industry in this huge industry. The group is comprised of MPs and advisory board consisting of academics and industry representatives. Jon Heffernan is a member of the advisory board. Several key events have been held by the APPG including an important reception in Parliament in Feb 2025. The output of the group is reported to the broad semiconductor community int he UK and has a broad reach including to the media. |
| Year(s) Of Engagement Activity | 2024 |
| URL | https://www.appgsemcon.co.uk |
| Description | New Scientist Live event in London |
| Form Of Engagement Activity | Participation in an activity, workshop or similar |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Schools |
| Results and Impact | Members of the LDSD group exhibited at the New Scientist Live event in London as part of the UK National Quantum Technology Program "Quantum City" exhibit. Over the 3 days, over 2500 people visited the Quantum City stand including many children from local schools. One of the group's exhibits has also been featured on New Scientist's social media channels where it has amassed 1.8m views (Jan 2023). |
| Year(s) Of Engagement Activity | 2022 |
| URL | https://www.tiktok.com/@newscientist/video/7152188912838905093?is_copy_url=1&is_from_webapp=v1 |
| Description | Photonics21 working group meeting on Quantum Integrated Photonics Circuits (QPICs) |
| Form Of Engagement Activity | A formal working group, expert panel or dialogue |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Policymakers/politicians |
| Results and Impact | Professor Heffernan attended a meeting of the Photonics21 working group of the European Commission to discuss the current status and future potential for QPICs. The meeting was primarily held to review the European position in this growing field and to further the development and inclusion of this area in the future EU R&D funding plans. The meeting was attended by representatives of the EU commission and a large number of academic and industrial researchers from across Europe, with strong representation from the UK. Professor Heffernan attended and contributed to discussions, particularly on heterogenous integration strategies including transfer print processes being developed under Heteroprint. |
| Year(s) Of Engagement Activity | 2021 |
