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Supported MoTe2: proving the viability of a 2D material to be employed in the PEM flow cell for the hydrogen production

Lead Research Organisation: University of Glasgow
Department Name: School of Chemistry

Abstract

Climate change and energy insecurity are two great challenges facing humankind. Suppose we can mitigate it by benefiting from the greater powers of nature which are in abundance such as wind and sun. We can make it work but adapting renewable electricity will bring intermittency challenge. What do we do when the sun does not shine, and the wind does not blow? We can solve it by generating green hydrogen by water electrolysis to manage the peaks and troughs in electricity production. We can make it work by stock-piling hydrogen reserves and re-utilising them when needed for heavy transport, domestic or industrial heating and chemical feedstock. Substantial progress in this direction would prevent the global warming and divert us from the reliance on fossil fuels.
Electrolysers are devices for water splitting and they are probably the most advanced solution for creating green hydrogen when coupled with renewable energy sources. Although there has been a significant progress in the design of industrial electrolysers; effective compact systems ready for dynamic response and capable of being deployed in tandem with renewable energy sources such as solar are still limited. The state-of-the-art technologies are still facing serious drawbacks by relying on expensive noble metal catalysts but what if we created few nanometers thick layers with abundance of active sites to catalyse the hydrogen evolution reaction at the surface? We can do it by using 2D materials that consist of earth-abundant elements and intrinsically prone to forming atomically-flat thin layers.
Delivered by a team of chemists and engineers the project will explore efficient and practical ways towards hydrogen production on MoTe2 which is a 2D material. The unique feature of MoTe2 is the abundance of catalytic sites at the surface. When supported on a high surface area substrate and laminated to proton exchange membrane it will act as cathode in the membrane electrode assembly within a flow cell that will generate hydrogen by water splitting. As such, the proposed research aims to create the first prototype of an electrolyser that works based on a 2D material. Success in this work would demonstrate an innovative solution by accessing MoTe2 on high surface area substrates to produce a highly stable and robust form of 2D catalyst for application in corrosive environments. This will allow further exploration of its use in delivering green hydrogen at scale.
 
Description This research investigates a non-platinum catalyst called 1T'-MoTe2 as a potential replacement for expensive platinum in proton exchange membrane (PEM) water electrolyzers, critical for sustainable "green" hydrogen. Initial three-electrode tests showed 1T'-MoTe2's hydrogen evolution performance approached leading 1T'-MoS2, suggesting its viability. However, in a full PEM electrolyzer, 1T'-MoTe2 underperformed, only reaching 150 mA cm-2 at 2 V. Analysis revealed an unexpected passivating tellurium layer, inhibiting catalytic activity. This discrepancy between idealized three-electrode and realistic electrolyzer results underscores the need to validate new catalysts in actual systems, to identify robust non-platinum options for sustainable green hydrogen production.
Exploitation Route The outcomes of this research funding have the potential for significant real-world impact, as the team has developed an enormous level of expertise that can be leveraged to drive further progress in sustainable hydrogen production.

Most importantly, the researchers have gained valuable insights into the critical role the anode plays in PEM electrolyzer performance. This knowledge will inform the development of more robust and efficient electrolyzer designs. The team plans to continue this line of study, building on the foundations laid by the current work.

Additionally, the funding received has been extremely valuable, with a long-lasting impact. The research has enabled the team to establish strong collaborations with industrial partners, who can help translate the findings into practical applications. More papers and intellectual property (IP) applications are expected to follow shortly, further disseminating the knowledge gained.

This expertise and the ongoing research will undoubtedly benefit the broader scientific community and industry players working towards the goal of sustainable hydrogen production. The insights gleaned from the challenges encountered with the 1T'-MoTe2 catalyst, such as the unexpected passivation behavior, will help guide the development and evaluation of other non-platinum alternatives.

Overall, the outcomes of this funding have laid a solid groundwork for continued advancements in PEM electrolyzer technology, with the potential for significant long-term impact on the transition to a more sustainable energy future.
Sectors Energy

Environment

Transport

URL https://www.linkedin.com/posts/alexey-ganin-2380978a_have-you-ever-wondered-why-so-few-studies-activity-7150130305285181440-AWgH
 
Description In addition to the academic impact, the outcomes of this research funding have also yielded significant non-academic benefits. We have developed a new oxygen evolution catalyst for PEM electrolysers that is currently tested with our industrial partners. In addition, the work continues on the anode layer creation with a possibility for start up company considered. While the specific details of this anode layer design cannot be disclosed at the moment due to pending intellectual property (IP) considerations, the impact on the industrial partner's operations has been substantial. The enhanced efficiency of their hydrogen production process translates to cost savings, improved sustainability, and increased competitiveness in the clean energy market.
First Year Of Impact 2023
Sector Energy,Environment
Impact Types Economic

 
Description Giving the evidences on Energy Storage, including hydrogen and batteries, hydrogen to power to Dr Anna Stephenson, Department for Energy Security
Geographic Reach National 
Policy Influence Type Contribution to a national consultation/review
 
Title CSD 2314472: Experimental Crystal Structure Determination 
Description Related Article: Weihao Li, Niklas Wolff, Arun Kumar Samuel, Yuanshen Wang, Vihar P. Georgiev, Lorenz Kienle, Alexey Y. Ganin|2023|ChemElectroChem|10|e202300428|doi:10.1002/celc.202300428 
Type Of Material Database/Collection of data 
Year Produced 2023 
Provided To Others? Yes  
URL http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.25505/fiz.icsd.cc2hpdd0&sid=DataCite
 
Description Collaboration with the University of Ulm 
Organisation University of Ulm
Country Germany 
Sector Academic/University 
PI Contribution A joint paper has been published / Prof. Axel Gross's group hosted PhD student
Collaborator Contribution Prof. Axel Gross's group contributed with computational work to two joint papers
Impact Two join papers has been published so far
Start Year 2022