The production and application of Japanese Irogane alloys.

Lead Research Organisation: Sheffield Hallam University
Department Name: Faculty of Arts Computing Eng and Sci

Abstract

The applicant holds an AHRC Fellowship in the Creative and Performing Arts. The research program is entitled 'The production and application of Japanese alloys and patination' and will run from May 2007- April 2010. The material and other costs covered by this application are central to the program of research proposed for the fellowship.

The Western tradition of metal patination and colouring is based on the use of a small range of metals and alloys which are coloured by the application of a wide range of patination solutions. In contrast to this, Japanese metalworkers developed a wide range of irogane alloys which are coloured with a single patination solution (the niiro eki or boiling colour solution). This approach allows different alloys to be combined in one piece and patinated, producing a multi-coloured piece of metalwork.

Irogane alloys are produced primarily on a small scale by skilled craftsmen with many years experience. In order to realise the potential of these alloys it is necessary to study the metallurgy of the alloys and the variations that result from the use of traditional and modern casting techniques. An understanding of the structure and behaviour of the cast alloys may also lead to improvements in the alloys, their processing, and the quality and consistency of the finished products. We will also look at the optimisation of the alloys for practical studio work through the use of micro alloys to control mechanical properties such as hardness and ductility.

This project will look specifically at the reliable production of shakudo (gold/copper), shibuichi (copper/silver), and kuromido (copper/arsenic) alloys. An initial list of alloy compositions to study will include Cu-99% Au-1%, Cu97% Au-3% and Cu-70% Ag-30%. Subject to health and safety considerations a Cu-99% As-1% is also a candidate material.

The research will ask:

1. What are the fundamental metallurgical properties of the irogane alloys?

2. How do the alloys respond to small workshop and industrial production methods? Do they differ and in what way?

3. How will the metallurgical properties of the alloys change during processing and practical studio work?

4. How can we optimise the materials for practical studio work through the use of microalloys?

The research will be located at Sheffield Hallam University (SHU) using the facilities and expertise of the Art and Design Research Centre (ADRC) and the Materials and Engineering Research Institute (MERI). There is a strong team of highly experienced and internationally recognised Metalwork and Jewellery staff at ADRC to support the research. MERI has the background of precious metals research, and the extensive equipment and materials characterisation techniques essential to support this research.

Papers will be submitted to scientific, design and craft related journals. The University website will be utilized for the publication of papers, exhibited works etc. Commercial collaborators will be sought through SHU to exploit any materials or processes that are developed.

The research program will allow me to significantly advance knowledge of technical issues relating to irogane alloys. This project is a fundamental part of the larger research programme as high quality alloys will be necessary for the study of the niiro patination technique and the production of my studio work. The proposed research will build on traditional craft knowledge and on contemporary technical research. This research will be a great contribution to the understanding of Japanese metalsmithing techniques, providing information and solutions to the problems faced by contemporary metalsmiths working with these materials, while also widening the area of possible applications and expression. This research will be of interest to metalsmiths, product designers, the metal finishing industry, and the materials science community.

Publications

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A.H. Jones (2010) Reliable Irogane Alloys and Niiro Patination- Further Study of Production and Application to Jewelry in Proceedings of the Twenty-Fourth Santa Fe Symposium in Albuquerque, New Mexico

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Coilin O'Dubhghaill (Author) (2010) Metal Mosaics: Customizing designs with homemade shibuichi and shakudo in MJSA Journal

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Coilin O'Dubhghaill (Author) (2010) Original research into Japanese alloys and patination in The Goldsmiths' Company Technical Bulletin

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Coilin O'Dubhghaill (Author) (2009) Japanese irogane alloys and patination - a study of production and application in Proceedings of the Twenty-Third Santa Fe Symposium in Albuquerque, New Mexico

 
Title 'Focus', Contemporary Applied Arts, London 
Description I showed a group of patinated vessels developed during the research program. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2010 
Impact The exhibition provided an important networking opportunity and lead to the sale of work to private collections and further exhibition invitations: domesticMATTERS at CAA in 2012 and Collect at Saatchi Gallery in 2014. 
 
Title 'Future Beauty', National Craft Gallery, Kilkenny, Ireland 
Description Exhibition of vessels produced as a result of the research program. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2013 
Impact European networking 
 
Title 9 Create, Scottish Gallery, Edinburgh 
Description This was a follow up exhibition to the Seven Smiths exhibition at Blackwell, I showed a group of patinated vessels developed during the research project. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2007 
Impact UK networking 
 
Title Beneath the skin, SIA Gallery, Sheffield and Galerie Marzee, Netherlands 
Description Beneath the Skin brings together eight academic researchers working within the field of contemporary metalwork and jewellery in order to reveal the research that underpins the object. The aim of the exhibition is to visualise and articulate the complex, multi-faceted and often non-linear creative journey that individual researchers make to get to the final object. It built upon and extended the enquiry started during the KeyPiece exhibition and research event in 2009 where the exhibited objects devoid of any textural explanation provided the basis for intensive critical discourse between participants in order to reveal the embedded knowledge. By presenting a range of tangible textual and non-textual material, Beneath the Skin aims to elicit and reveal the knowledge embodied by the object and proposed that there are intangible aspects within creative research that are not possible to quantify. Exhibition Venues and Dates: Galerie Marzee, Nijmegen, The Netherlands [7th October - 12th December 2012] SIA Gallery, Sheffield, UK [24th March - 20th April 2011] 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2012 
Impact This exhibition led to the purchase of work for the Marzee Collection, Netherlands in 2012 Article: Crafts Magazine, March/April 2011, page 22-23, " Material Research", article discusses Beneath the Skin exhibition. 
URL http://www.mariahanson.co.uk/beneath-the-skin/index.php/researchers/coilin-o-dubhghaill
 
Title Coilin O'Dubhghaill at Galerie Marzee, Netherlands 
Description Solo Exhibition at Galerie Marzee, Netherlands. This research tests the application of irogane alloy and newly developed synthetic niiro patination techniques through the production of a series of decorative vessels. By introducing Japanese alloys into the domain of the traditional silversmith, this work also challenges perceptions of fine crafted metal objects, disregarding hierarchies of value set up by precious metal commodity markets and the institution of the hallmark. Resulting from the application of material and process knowledge developed during earlier laboratory based testing these artefacts are an outcome from the practiced based study into Japanese metalworking techniques. (Irogane alloys and niiro patination).Small scale laboratory samples produced consistent results with the synthetic niiro solution but full exploration of the material and process properties and behaviours required extensive large scale craft workshop activity. Through this ongoing series of vessels, utilising hand forged hammer techniques and fabrication; creative possibilities have been explored by combining an extended range of irogane alloys beyond the standard palette usually encountered. The intrinsic material qualities and subtle variations of colours have been further exploited through surface enrichment and selective polishing resulting in surface finishes with new variegated colours. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2011 
Impact Work from this collection was purchased for the Marzee collection, Netherlands in 2012. 
 
Title Coilin O'Dubhghaill at Scottish Gallery, Edinburgh 
Description Solo exhibition of vessels produced as a result of the research program. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2008 
Impact UK networking 
 
Title Collect, Saatchi Gallery, London 
Description COLLECT: The International Art Fair for Contemporary Objects brings together the world's finest galleries representing exceptional work of museum-quality from their portfolio of artists. I have shown work developed during the research project at the Collect exhibition in 2010/11/12/13/14, with Galerie Marzee, CAA, and National Craft Gallery Ireland. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2010 
Impact Exhibiting at Collect had led to international exhibition invitations, e.g. 'Dubh', AIHS, New York and Oliver Sears Gallery, Dublin; media coverage e.g. Financial Times, and the sale of work to international private collections. In 2012 a piece from the exhibition was purchased for the Crafts Council of Ireland / Department of Foreign Affairs collection Article: Financial Time Magazine, "Touching Base" 20/10/2010 
URL http://www.craftscouncil.org.uk/what-we-do/collect/
 
Title FIVE into FOUR, Oliver Sears Gallery, Dublin, 20 June - 26 July 2013 
Description Exhibition with vessels produced as a result of the research program. From Richard Rabel's blog discussing the Five into Four exhibition: C?il?n ? Dubhghaill is one of the brilliant young designers keeping alive the age-old tradition of silversmithing. There are too few artists like him, so we must show our support for ? Dubhghaill! His works have a noticeably Eastern influence and that is no coincidence - he studied in Japan and received a doctorate for research into traditional Japanese metalwork techniques (the Japanese have a marvelous history of incorporating different metals into stunning pieces). One of my favorite pieces in this show is his "Ritual 9". Taking a cue from traditional Japanese koros, this vessel has the most beautiful speckled finish. The paper-thin silver is also an amazing contrast to what appears to be a very weighty object. Another of his works in the show is this elegant bowl "Ceo 7". Fashioned from a copper and gold alloy, I first took this for pottery until I looked closer. An "? Dubhghaill" piece for sure, I thought, this time working outside of silver to create this earthy, yet sophisticated piece. While we mere mortals would think working with copper or silver is the same, the talent in bringing these two different pieces to such a high level of perfection and beauty is actually quite a feat! 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2013 
Impact Work from this exhibition was purchased for the Irish State Art Collection. Article: The Sunday Times 07/07/13, "Five into Four" Article: Irish Examiner 09/07/13, "Craft show not by the numbers" 
 
Title Frame at Schmuck, Internationale Handwerks Messe, Munich, 2013 
Description Exhibition of vessels produced as a result of the research program. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2013 
Impact European networking 
 
Title Keypiece Exhibition, Sheffield 
Description KeyPiece was a combined public exhibition and research event bringing together leading UK metalworking practitioners and their work in November 2009. The project was initiated by Coilin O'Dubhghaill and developed in collaboration with Maria Hanson and Christoph Zellweger. The project was described in detail in the publication: HANSON, Maria and WOOD, Nicola (2010). KeyPiece: Creating a critical dialogue in contemporary craft; Design and craft: A history of convergences and divergences: 7th Conference of Design History and Design Studies (ICDHS), Brussels, Belgium, 20-22 September 2010. The exhibited pieces provided the basis for discussion between the makers, along with other pieces brought along by the makers that were considered significant but not necessarily suitable for exhibition. The question of how a keypiece can be identified and defined led the makers to develop an understanding of the different roles objects they make play within their practice. The participants were: Lionel Dean, Coilin O'Dubhghaill, Sara O'Hana, Maria Hanson, Grace Horn, Antje Illner, Drummond Masterson, Tine de Ruysser, Lucian Taylor and Christoph Zellweger. This project was supported by funding from Arts Council England/National Lottery and the Art and Design Research Centre at Sheffield Hallam University. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2009 
Impact The Keypiece project developed dialogue looking at the relationship between objects and research within the metalwork research community which lead to the Beneath The Skin project and exhibitions, see: http://www.mariahanson.co.uk/beneath-the-skin/ 
 
Title KunstRAI, Amsterdam (2012) 
Description Exhibition of vessels produced as a result of the research program. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2012 
Impact European networking 
 
Title Object Rotterdam, Netherlands 
Description The fair is a platform for the latest limited editions and one-offs from well-known and upcoming designers working in different design disciplines and various materials. OBJECT is the place where the cutting edge between design, crafts, fashion, architecture and art becomes evident and a must see for collectors, professionals and other design minded people. I showed a collection of patinated vessels produced during the research project at Object. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2009 
Impact European networking 
URL http://objectrotterdam.com/
 
Title PAN, Amsterdam (2011) 
Description Exhibition of vessels produced as a result of the research program. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2011 
Impact European networking 
 
Title Seven Smiths, Blackwell, Bowness-on-Windermere 
Description Seven Smiths: new work in metal and silver 13 November - 31 December 2007 Seven Smiths brings together the new work of seven of the UK's leading silversmiths. Each has exhibited widely both in the UK and internationally, and between them their work is represented in most of the major public collections. Blackwell, filled with exquisite handwork in wood, stone and plaster, provides the peculiarly fitting backdrop for these new examples of an age-old craft. Some of the pieces made for Seven Smiths have evolved as a direct response to the Arts and Crafts Movement, the house and its spectacular setting. Silversmith/designer Coilin O'Dubhghaill studied for a doctorate in Tokyo, where he mastered a range of techniques using coloured metal inlays, or irogane, which he now uses in combination to create vessel forms with an emphasis on surface pattern and colour. He is currently a research fellow at Sheffield Hallam University, researching the production and application of Japanese alloys, such as the copper/gold shakudo alloy, and their patination. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2007 
Impact UK networking 
URL http://www.blackwell.org.uk/exhibitions/seven-smiths-new-work-metal-and-silver
 
Title Shortlisted for National Metalwork Design Award 2008 
Description The award was a national biennial event, sponsored by Yorkshire South Tourism, in partnership with Yorkshire Forward and South Yorkshire Objective 1. Organisers looked to reward the best examples of bold, brave and innovative metalwork design. The prize also emphasised the important role production and design of metal has played in both Sheffield Museums' and the city's past. Included in the shortlist, which was chosen by a judging panel including the Duke of Devonshire and Corin Mellor of cutlery firm David Mellor Design, are well known artists in their field alongside emerging artists from across the UK. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2008 
Impact The exhibition provided an early means to promote and network for the research project. 
 
Title Silverstruck, Ruthin Craft Centre and National Museum of Wales 
Description The Silverstruck exhibition celebrates the current strength of contemporary silversmithing in the UK, reflecting new directions realised by traditional and cutting-edge techniques. I showed two pieces of patinated metalwork produced during the research program. The exhibition opened at Ruthin Craft Centre, The Centre for the Applied Arts from 12 February until 27 March 2011 and then moved to the National Museum of Wales in Cardiff 12 April until 24 July 2011. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2011 
Impact Two pieces from the exhibition were purchased for the The Goldsmiths' Company, Modern Collection, London. This is notable as the Goldsmiths' Company usually only purchases hallmarked precious metalwork. 
URL http://www.ruthincraftcentre.org.uk/exhibitions/silverstruck/
 
Title Sterling Irish, National Craft Gallery, Ireland 
Description This was an exhibition of Irish craftspeople based in the UK. I showed a collection of patinated vessels developed during the research program. 
Type Of Art Artistic/Creative Exhibition 
Year Produced 2009 
Impact A piece of work was purchased for the Crafts Council of Ireland / Department of Foreign Affairs collection. 
 
Description Irogane alloys are produced primarily on a small scale by skilled craftsmen with many years experience. In order to realise the potential of these alloys it is necessary to study the metallurgy of the alloys and the variations that result from the use of traditional and modern casting techniques. Through our study of the alloys we have improved our understanding of the structure and behaviour of the cast alloys and their processing, and the quality and consistency of the milled sheet.



The alloy production research focused on 3 main alloys 50/50 Cu/Ag, 75/25 Cu/Ag and 98/2 Cu/Au. These are representative of shibuichi (au/ag alloys) and shakudo (cu/au) alloys. The alloys were produced using industrial protective atmosphere casting methods and traditional non-protective atmosphere workshop casting methods. The workshop alloys were cast into both traditional water moulds (yudokobuki) and steel moulds. We produced rolled materials from each alloy in the as-rolled and annealed conditions. This sheet was produced under industrial conditions using controlled atmosphere annealing and large rolling mills and under workshop conditions using torch annealing and hammer forging/ small rolling mills. This produced more than 100 samples for characterisation.



The most important aspects in terms of characterising these alloys are; (i) as-cast quality in terms of inclusions/porosity etc. (ii) micro-structure and how it changes with rolling/annealing, and (iii) mechanical behaviour (e.g. hardness, strength, ductility and annealing behaviour).



The study has revealed information that will aid us in both the successful production of the alloys and their patination:



Surface enrichment of one of the two phases of the structure in Ag/Cu alloys can be exploited for decorative effect during surface patination.



Variation in the grain size and in the microstructures of the eutectic phase depending upon the cooling rate of each casting method influences behaviour during rolling/hammering and surface patination.



Variations in porosity depending on casting methods. For steel moulds the porosity was large and concentrated in the areas that were last to solidify, i.e. in the centre of the section and towards the top of the ingot. For the water cast materials the porosity was smaller but more numerous and distributed more evenly throughout the cross-section. Virtually no porosity was observed in the sections through the continuous cast ingots. Porosity levels have a significant effect on the material quality, especially after rolling.



In addition to this research in alloy production we have prepared samples of 34 traditional alloy combinations- cu/au, cu/ag and cu/au/ag which will be used to assess the range of alloy colours achievable during our research into Niiro patination.



Through this study of irogane alloys, their casting and processing methods, we have developed our understanding of their metallurgical properties and an indication of the quality parameters of the various casting methods. It is clear that continuous casting under protective atmosphere is superior to the traditional studio methods. However, it has been very useful to clarify the quality and properties of studio cast alloys as this method is still commonly used by craftspeople and for the production of alloy samples.
Sectors Creative Economy,Manufacturing/ including Industrial Biotechology,Culture, Heritage, Museums and Collections

 
Description Arts Council England Grants for the Arts
Amount £5,500 (GBP)
Organisation Arts Council England 
Sector Public
Country United Kingdom
Start 11/2009 
End 11/2009
 
Description Sasakawa Foundation award
Amount £2,500 (GBP)
Organisation The Great Britain Sasakawa Foundation 
Sector Charity/Non Profit
Country United Kingdom
Start 12/2007 
End 12/2007
 
Description Keypiece research event and exhibition, Sheffield Hallam University. 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact KeyPiece was a combined public exhibition and research event bringing together leading UK metalworking practitioners and their work in November 2009. The project was initiated by Coilin O'Dubhghaill and developed in collaboration with Maria Hanson and Christoph Zellweger. The project was described in detail in the publication: HANSON, Maria and WOOD, Nicola (2010). KeyPiece: Creating a critical dialogue in contemporary craft; Design and craft: A history of convergences and divergences: 7th Conference of Design History and Design Studies (ICDHS), Brussels, Belgium, 20-22 September 2010.

The exhibited pieces provided the basis for discussion between the makers, along with other pieces brought along by the makers that were considered significant but not necessarily suitable for exhibition. The question of how a keypiece can be identified and defined led the makers to develop an understanding of the different roles objects they make play within their practice.

The participants were: Lionel Dean, Coilin O'Dubhghaill, Sara O'Hana, Maria Hanson, Grace Horn, Antje Illner, Drummond Masterson, Tine de Ruysser, Lucian Taylor and Christoph Zellweger.

This project was supported by funding from Arts Council England/National Lottery and the Art and Design Research Centre at Sheffield Hallam University.


The Keypiece project developed dialogue looking at the relationship between objects and research within the metalwork research community which lead to the Beneath The Skin project and exhibitions, see: http://www.mariahanson.co.uk/beneath-the-skin/
Year(s) Of Engagement Activity 2009
 
Description Lecture delivered in Metalsmithing department, Tokyo National University of Fine Art and Music, Japan 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other academic audiences (collaborators, peers etc.)
Results and Impact The presentation provoked discussion about research into craft processes and the contrasting approaches used in the European and Japanese traditions.

The lectures in Japan led to collaborative research with Japanese patination experts which contributed to ongoing research and studio practice
Year(s) Of Engagement Activity 2010
 
Description Lecture delivered in Metalwork Program, Craft Department, Tama Art University, Japan. 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other academic audiences (collaborators, peers etc.)
Results and Impact The presentation provoked discussion about research into craft processes and the contrasting approaches used in the European and Japanese traditions

The lectures in Japan led to collaborative research with Japanese patination experts which contributed to ongoing research and studio practice
Year(s) Of Engagement Activity 2010
 
Description Lecture delivered to Association for Contemporary Jewellery, Crossing conference 2010, UK 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact The presentation provoked discussion about research into craft processes and the contrasting approaches used in the European and Japanese traditions.

The lecture led to an invitation to present to the Colour Group GB and some ongoing collaboration with other UK craftspeople
Year(s) Of Engagement Activity 2010
 
Description Lecture delivered to Jewellery and Metalwork Department, National College of Art and Design, Dublin, Ireland 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Undergraduate students
Results and Impact The lecture led to a discussion of Japanese metalwork processes and techniques



The lecture led to correspondence and advice to students at NCAD relating to their use of patination processes in their work.
Year(s) Of Engagement Activity 2010
 
Description Lecture: Art, Chemistry and Colour in Metalwork, Museums Sheffield / 100 years of Stainless Steel Festival 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Public/other audiences
Results and Impact The presentation led to discussion, correspondence and ongoing collaboration with local metalworkers and designers. The presentation led to an interview and article in the Magazine of Sheffield Festival of Science and Engineering 2013.

The presentation led to discussion, correspondence and ongoing collaboration with local metalworkers and designers. This has led to the production of work for exhibition internationally and to the production of prototypes for jewellery retail manufacture.
Year(s) Of Engagement Activity 2013
URL http://www.museums-sheffield.org.uk/whats-on/events/2013/3/art-chemistry-and-colour-in-metalwork
 
Description Lecture: Irogane, a search for reliability between craft and science, delivered to The Colour Group (GB) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Other academic audiences (collaborators, peers etc.)
Results and Impact The presentation led to a very useful discussion on methods for colour analysis on metalwork and the contrast between European and Japanese metalwork traditions

The presentation led to an invite to present to The Society of Jewellery Historians and ongoing collaboration with museum researchers
Year(s) Of Engagement Activity 2012
URL http://www.colour.org.uk/meetingFebruary12.html
 
Description Speaker, "Understanding Interdisciplinarity: Theory and Practice" conference, Sheffield Hallam University, UK 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other academic audiences (collaborators, peers etc.)
Results and Impact The presentation, Radishes or isothiocyanates? A search for control between art and science, led to to useful discussion about the challenges of research collaborations between artists and scientists

The presentation led to an invite to deliver a Keynote presentation at, Driving Forces: the role of artists and designers in interdisciplinary research conference, Australian National University, School of Art, Canberra, Australia in 2014
Year(s) Of Engagement Activity 2012
URL http://research.shu.ac.uk/engineering-for-life/Conference.html