A new spin on chemical reaction dynamics
Lead Research Organisation:
University of Oxford
Department Name: Oxford Chemistry
Abstract
Many chemical processes involve molecules with angular momentum, associated either with the spin and orbital motion of the electrons, or with the rotation of the nuclear framework of the molecule itself. Angular momentum is a vector quantity, and therefore is characterized by both magnitude and direction. The objective of the proposed research will be to develop a novel probe of angular momentum polarization (i.e. the angular distribution characterizing the direction of the angular momentum) in the products of molecular photodissociation and bimolecular reactions. The experiments are based on the laser induced fluorescence detection method, and will exploit the technique of Faraday rotation, in which a weak magnetic field is applied to the sample to induce Zeeman quantum beats in the time resolved laser fluorescence decay of the product species of interest. This should allow sensitive detection of polarization information since the information is obtained on every laser shot of the experiment. The new method will be applied to a number of prototypical photodissociation and bimolecular collisional systems.
Organisations
People |
ORCID iD |
Mark Brouard (Principal Investigator) |
Publications
Aoiz FJ
(2009)
The collisional depolarization of (2S+1)Sigma radicals by closed shell atoms: Theory and application to OH(A (2)Sigma(+))+Ar.
in The Journal of chemical physics
Brouard M
(2009)
Collisional depolarization of NO(A) by He and Ar studied by quantum beat spectroscopy
in The Journal of Chemical Physics
Brouard M
(2009)
Collisional depolarization of OH(A) with Ar: Experiment and theory.
in The Journal of chemical physics
Brouard M
(2009)
Applications of Zeeman quantum beat spectroscopy to angular momentum polarization studies
in Physica Scripta
Costen ML
(2009)
Elastic depolarization of OH(A) by He and Ar: a comparative study.
in The journal of physical chemistry. A