Fuelling The Future : From Materials Science To New Energy Conversion Systems
Lead Research Organisation:
University of St Andrews
Department Name: Chemistry
Abstract
The philosophy of this proposal is to bring together careful, focused basic studies with development actions to try to provide stepchange advances in Energy technology that have realistic possibility to be implemented in Industrial Development. The focus has been well informed by involvement in the Strategic Research Agenda of the European Hydrogen and Fuel Cells Platform. Our objective is to provide some of the solutions necessary to bring to fruition a vision of the new energy economy as stated below. We prefer not to follow the nuclear option; however, this only makes sense if renewable and clean energy technologies can demonstrate fairly soon that there does exist a viable non-nuclear solution, as we cannot leave Nuclear Technology on standby for very much longer, lest we lose capability. This is perhaps the gauntlet that the UK government Energy White Paper threw down for our clean Energy Community.By 2050 cheap oil will no longer be available and Europe's internal reserves will be exhausted. An increasing proportion of primary energy production will be from renewables such as solar, wind, tidal and biomass possibly supplemented by nuclear, natural gas and coal. We must rely on new energy carriers such as hydrogen, biogas or synfuels and liquid biofuels. These carriers will complement electricity as energy vectors, enabling some degree of energy efficiency optimisation, both on a local and a larger scale. A decentralised electricity generation infrastructure powered by a broad spectrum of renewable and clean technologies with a strong fuel cell component will have been created. The power network will largely be based upon self-contained nodes, each consisting of renewable and/or fuel cell systems. The advantages of this decentralised system arise from lower transmission losses, higher total energy efficiency and improved energy security. These nodes will be supported by a high value network powered by advanced thermal or nuclear systems, hydropower, buffered wind power and fuel cell systems. Our role is to develop high temperature electrochemical technologies to enable the efficient introduction of this new energy economy. Our early work will seek to optimise current fuel cell technology improving durability and stability and reducing cost of manufacture to enable widespread introduction. We will develop new anode formulations to enable efficient utilisation of more complex fuels, ranging from natural gas and LPG through biogas to liquid biofuels and biomass. Efficient utilisation of biomass is central to the new energy economy and this will be achieved by a range of mechanisms. Fuel cell technology is a particularly important enabler for biomass utilisation offering high efficiencies of conversion in fairly small unit sizes and is essential to the new distributed energy economy.Solid Oxide Fuel Cells seem certain to make a significant contribution to the future energy economy in 5-10 years, if good technological progress can be maintained; however, we only see this as one manifestation of this technology. Future development relates to efficient electrolysis, novel systems and carbon neutral fuel production. Efficient electrolysis to produce clean hydrogen is of key importance to the possibility of utilising renewable energy in transport. Similarly reversible fuel cells with careful thermal management can provide good buffering for intermittent power supplies. Discovery of new materials is important to achieving new more efficient technologies and the development of alternative systems based upon other ceramic electrolytes such as protonic or even hydride ion conductors offer even more exciting advances. The efficient conversion of carbon dioxide or nitrogen to useful carbon-free fuels is perhaps our ultimate goal in this project.
Organisations
Publications
Azad A
(2008)
Structural origins of the differing grain conductivity values in BaZr0.9Y0.1O2.95 and indication of novel approach to counter defect association
in Journal of Materials Chemistry
Azad A
(2013)
Spin-glass transition in La0.75Sr0.25Mn0.5Cr0.5-xAlxO3-d perovskites
in Materials Research Bulletin
Jain S
(2008)
Solid state electrochemistry of direct carbon/air fuel cells
in Solid State Ionics
Kim G
(2008)
Engineering Composite Oxide SOFC Anodes for Efficient Oxidation of Methane
in Electrochemical and Solid-State Letters
Kim J
(2009)
Advanced Electrochemical Properties of LnBa[sub 0.5]Sr[sub 0.5]Co[sub 2]O[sub 5+d] (Ln=Pr, Sm, and Gd) as Cathode Materials for IT-SOFC
in Journal of The Electrochemical Society
Tao S
(2007)
Conductivity studies of dense yttrium-doped BaZrO3 sintered at 1325°C
in Journal of Solid State Chemistry
Yue X
(2015)
Understanding of CO 2 Electrochemical Reduction Reaction Process via High Temperature Solid Oxide Electrolysers
in ECS Transactions
Description | The Senior Fellowship has greatly advanced my career. My activity has considerably expanded with a research group of 40 being sustained by a structure including 4 Senior Researchers and 2 Technicians. We have set up a well equiped laboratory able to take new materials right from the electron microscope up to stack scale devices, with a high levelof competency at all these stages. We are supported by UK, European and US agences, UK and International companies. During this period I have been awarded the RSC Materials Chemistry and Lee Hsun Awards and led an EU Coal and Steel consortium, the Delivery of Sustainable Hydrogen Supergen consortium and the EPSRC UK/India Biogas SOFC consortium. I have chaired the Scottish Hydrogen and Fuel Cell Association for the last 5 years and am co-director of the Scottish Energy Technology Partnership. I chaired the 2010 European Fuel Cell Forum and have chaired or co-chaired 4 other International Conferences, editing Proceedings Volumes for all 5. I am or have been on the Editorial Board of several journals including Journal of Materials Chemistry and Advanced Energy Materials. Thus through the Felowship I have maintained and strengthened my strong interdisciplinary profile. There have been several important research achievements and these will continue to have direct impact in the coming year with our ongoing programme building upon these into the future. As proposed, we have maintained and developed our leading position in alternative anode materials discovery and development. Very significant progress has been made in Impregnated Electrode Structures and in Redox Exsolution Chemistry, controlling location and nanostructure of electroactive sites. Important new activities or major advances have also been as follows: * Demonstration of High Performance (900mWcm-2) in a Hybrid Direct Carbon Fuel Cell (HDFC). * Demonstrated Feasibility of Scale up of HDFC. * Observation of Interstitial Oxide Ions in Apatite Conductors * Discovery of Red Metallic Photocatalysis. * Discovery of route to high density proton conducting perovskites. * Discovery of catalysis of water gas shift by proton conducting oxides * Use of proton conducting oxides for syngas production from CO2 and H2O * Low polarisation losses demonstrated at an oxide cathode for CO2 electrolysis. * Observation of electrolysis of pure steam at titanate electrodes. * Direct ammonia synthesis at barium cerate type electrolytes * Discovery and demonstration of High Hydride ion conductivity in saline hydrides * Elucidation of t" phase in Ln2CuO4 system as a metasatble phase formed on rapid cooling * Demonstration of very low polarisation resistance Sm2(Ba,Sr)2CoO5 SOFC cathodes * Discovery of high protonic and oxide ionic conductivity in Si5(PO4)6O and its Ge analogue * Use of net shape process to form dense two phase electrolyte structure with enhanced conduction and mechanical properties * Demonstration of use of reversible fuel cell to store electricity at over 70% cycle efficiency in a thermally integrated concept. |
Exploitation Route | he philosophy of this proposal was to bring together careful, focused basic studies with development actions to provide stepchange advances in Energy technology that have realistic possibility to be implemented in Industrial Development. Our objective is to provide some of the solutions necessary to bring to fruition a vision of the new energy economy as stated below. By 2050 cheap oil will no longer be available and Europe's internal reserves will be exhausted. An increasing proportion of primary energy production will be from renewables such as solar, wind, tidal and biomass possibly supplemented by nuclear, natural gas and coal. We must rely on new energy carriers such as hydrogen, biogas or synfuels and liquid biofuels. These carriers will complement electricity as energy vectors, enabling some degree of energy efficiency optimisation, both on a local and a larger scale. A decentralised electricity generation infrastructure powered by a broad spectrum of renewable and clean technologies with a strong fuel cell component will have been created. The power network will largely be based upon self-contained nodes, each consisting of renewable and/or fuel cell systems. The advantages of this decentralised system arise from lower transmission losses, higher total energy efficiency and improved energy security. These nodes will be supported by a high value network powered by advanced thermal or nuclear systems, hydropower, buffered wind power and fuel cell systems. Our role is to develop high temperature electrochemical technologies to enable the efficient introduction of this new energy economy. This involved optimisation of current fuel cell technology improving durability and stability and reducing cost of manufacture to enable widespread introduction. We develop new anode formulations to enable efficient utilisation of more complex fuels, ranging from natural gas and LPG through biogas to liquid biofuels and biomass. Efficient utilisation of biomass is central to the new energy economy and this will be achieved by a range of mechanisms including Direct Carbon Fuel Cells. Fuel cell technology is a particularly important enabler for biomass utilisation offering high efficiencies of conversion in fairly small unit sizes and is essential to the new distributed energy economy. Solid Oxide Fuel Cells are now satrting to make a significant contribution to the future energy economy; however, we only see this as one manifestation of this technology. Future development relates to efficient electrolysis, novel systems and carbon neutral fuel production. Efficient electrolysis to produce clean hydrogen is of key importance to the possibility of utilising renewable energy in transport. Similarly reversible fuel cells with careful thermal management can provide good buffering for intermittent power supplies. Discovery of new materials is important to achieving new more efficient technologies and the development of alternative systems based upon other ceramic electrolytes such as protonic or even hydride ion conductors offer even more exciting advances. The efficient conversion of carbon dioxide or nitrogen to useful carbon-free fuels is perhaps our ultimate goal in this project. |
Sectors | Energy Environment |
Description | The philosophy of this proposal was to bring together careful, focused basic studies with development actions to provide stepchange advances in Energy technology that have realistic possibility to be implemented in Industrial Development. Our objective is to provide some of the solutions necessary to bring to fruition a vision of the new energy economy as stated below. By 2050 cheap oil will no longer be available and Europe's internal reserves will be exhausted. An increasing proportion of primary energy production will be from renewables such as solar, wind, tidal and biomass possibly supplemented by nuclear, natural gas and coal. We must rely on new energy carriers such as hydrogen, biogas or synfuels and liquid biofuels. These carriers will complement electricity as energy vectors, enabling some degree of energy efficiency optimisation, both on a local and a larger scale. A decentralised electricity generation infrastructure powered by a broad spectrum of renewable and clean technologies with a strong fuel cell component will have been created. The power network will largely be based upon self-contained nodes, each consisting of renewable and/or fuel cell systems. The advantages of this decentralised system arise from lower transmission losses, higher total energy efficiency and improved energy security. These nodes will be supported by a high value network powered by advanced thermal or nuclear systems, hydropower, buffered wind power and fuel cell systems. Our role is to develop high temperature electrochemical technologies to enable the efficient introduction of this new energy economy. This involved optimisation of current fuel cell technology improving durability and stability and reducing cost of manufacture to enable widespread introduction. We develop new anode formulations to enable efficient utilisation of more complex fuels, ranging from natural gas and LPG through biogas to liquid biofuels and biomass. Efficient utilisation of biomass is central to the new energy economy and this will be achieved by a range of mechanisms including Direct Carbon Fuel Cells. Fuel cell technology is a particularly important enabler for biomass utilisation offering high efficiencies of conversion in fairly small unit sizes and is essential to the new distributed energy economy. Solid Oxide Fuel Cells are now satrting to make a significant contribution to the future energy economy; however, we only see this as one manifestation of this technology. Future development relates to efficient electrolysis, novel systems and carbon neutral fuel production. Efficient electrolysis to produce clean hydrogen is of key importance to the possibility of utilising renewable energy in transport. Similarly reversible fuel cells with careful thermal management can provide good buffering for intermittent power supplies. Discovery of new materials is important to achieving new more efficient technologies and the development of alternative systems based upon other ceramic electrolytes such as protonic or even hydride ion conductors offer even more exciting advances. The efficient conversion of carbon dioxide or nitrogen to useful carbon-free fuels is perhaps our ultimate goal in this project. |
Sector | Energy,Environment |
Description | Bloom energy |
Amount | £270,505 (GBP) |
Funding ID | be |
Organisation | Bloom Energy |
Sector | Private |
Country | United States |
Start |
Description | EPSRC |
Amount | £859,124 (GBP) |
Funding ID | EP/G030995/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 08/2009 |
End | 02/2014 |
Description | EPSRC |
Amount | £4,913,990 (GBP) |
Funding ID | EP/G01244X/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 09/2008 |
End | 09/2012 |
Description | EPSRC |
Amount | £142,473 (GBP) |
Funding ID | EP/F062435/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 03/2008 |
End | 03/2009 |
Description | EPSRC |
Amount | £432,148 (GBP) |
Funding ID | EP/I022570/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 07/2011 |
End | 07/2015 |
Description | EPSRC |
Amount | £432,871 (GBP) |
Funding ID | EP/H004130/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 11/2009 |
End | 10/2012 |
Description | EPSRC |
Amount | £253,420 (GBP) |
Funding ID | DT/E010113/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 05/2007 |
End | 05/2010 |
Description | EPSRC |
Amount | £1,007,937 (GBP) |
Funding ID | EP/E064248/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 01/2008 |
End | 12/2012 |
Description | EPSRC |
Amount | £137,448 (GBP) |
Funding ID | EP/I038950/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 01/2012 |
End | 06/2015 |
Description | EPSRC |
Amount | £528,038 (GBP) |
Funding ID | EP/E045421/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 03/2007 |
End | 03/2012 |
Description | EPSRC |
Amount | £1,224,922 (GBP) |
Funding ID | EP/I037016/1 |
Organisation | Engineering and Physical Sciences Research Council (EPSRC) |
Sector | Public |
Country | United Kingdom |
Start | 08/2011 |
End | 08/2014 |
Description | EU Research Fund for Coal and Steel |
Amount | £404,881 (GBP) |
Organisation | Research Fund for Coal and Steel |
Sector | Public |
Country | Belgium |
Start |
Description | European Commission (EC) |
Amount | £215,889 (GBP) |
Funding ID | FP7 |
Organisation | European Commission |
Sector | Public |
Country | European Union (EU) |
Start | 09/2008 |
End | 09/2012 |
Description | European Commission (EC) |
Amount | € 213,940 (EUR) |
Funding ID | FCH-JU-2009-01 |
Organisation | European Commission |
Sector | Public |
Country | European Union (EU) |
Start | 09/2010 |
End | 09/2013 |
Description | European Commission (EC) |
Amount | € 150,089 (EUR) |
Funding ID | HFC JTU |
Organisation | European Commission |
Sector | Public |
Country | European Union (EU) |
Start | 11/2011 |
End | 10/2014 |
Description | European Regional Development Fund |
Amount | £117,071 (GBP) |
Funding ID | lups |
Organisation | European Commission |
Department | European Regional Development Fund (ERDF) |
Sector | Public |
Country | Belgium |
Start | 01/2010 |
End | 03/2013 |
Description | International Copper Association Ltd |
Amount | £56,000 (GBP) |
Funding ID | UStA |
Organisation | International Copper Association Ltd |
Sector | Charity/Non Profit |
Country | United States |
Start |
Description | Office of Naval Research |
Amount | £108,108 (GBP) |
Funding ID | UPenn |
Organisation | US Navy |
Department | US Office of Naval Research Global |
Sector | Academic/University |
Country | United States |
Start |
Description | Sasol Technology |
Amount | £233,727 (GBP) |
Funding ID | sasol |
Organisation | Sasol Technology |
Sector | Private |
Country | South Africa |
Start |
Description | Scottish Enterprise |
Amount | £151,187 (GBP) |
Funding ID | POC |
Organisation | Scottish Enterprise |
Sector | Public |
Country | United Kingdom |
Start | 12/2008 |
End | 01/2011 |