High Symmetry Paramagnetic Cages
Lead Research Organisation:
University of Edinburgh
Department Name: Sch of Chemistry
Abstract
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Organisations
People |
ORCID iD |
| Euan Brechin (Principal Investigator) |
Publications
Atkinson JH
(2014)
Three-leaf quantum interference clovers in a trigonal single-molecule magnet.
in Physical review letters
Berg N
(2013)
Synthetic, structural, spectroscopic and theoretical study of a Mn(III)-Cu(II) dimer containing a Jahn-Teller compressed Mn ion.
in Dalton transactions (Cambridge, England : 2003)
Berg N
(2012)
What controls the magnetic interaction in bis-ยต-alkoxo Mn(III) dimers? A combined experimental and theoretical exploration.
in Chemistry (Weinheim an der Bergstrasse, Germany)
Bradley JM
(2010)
MCD spectroscopy of hexanuclear Mn(III) salicylaldoxime single-molecule magnets.
in Dalton transactions (Cambridge, England : 2003)
Evangelisti M
(2011)
Cryogenic magnetocaloric effect in a ferromagnetic molecular dimer.
in Angewandte Chemie (International ed. in English)
Frost JM
(2014)
A truncated [Mn(III)12] tetrahedron from oxime-based [Mn(III)3O] building blocks.
in Dalton transactions (Cambridge, England : 2003)
Hooper TN
(2012)
The importance of being exchanged: [Gd(III)4M(II)8(OH)8(L)8(O2CR)8]4+ clusters for magnetic refrigeration.
in Angewandte Chemie (International ed. in English)
Houton E
(2012)
Ferromagnetic exchange in a twisted, oxime-bridged [Mn(III)2] dimer.
in Dalton transactions (Cambridge, England : 2003)
Langley S
(2011)
Molecular coolers: The case for [CuII5GdIII4]
in Chemical Science
| Description | The moleculer recipes required to construct molecules with an enhanced magnetocaloric effect (MCE) that makes possible the use of molecules and molecule-based materials as cryogenic coolants, and thus as possible replacements for the rare and expensive He-3. |
| Exploitation Route | Fundamental chemistry and physics that underpins potential use as cryocoolers. |
| Sectors | Chemicals |
| URL | http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin |