Supramolecular Synthesis of Molecular Clusters: Topological Control of Hybrid Nanomagnets

Lead Research Organisation: University of Edinburgh
Department Name: Sch of Chemistry

Abstract

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Publications

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Atkinson JH (2014) Three-leaf quantum interference clovers in a trigonal single-molecule magnet. in Physical review letters

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Berg N (2012) What controls the magnetic interaction in bis-ยต-alkoxo Mn(III) dimers? A combined experimental and theoretical exploration. in Chemistry (Weinheim an der Bergstrasse, Germany)

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Berg N (2012) Old dog, new tricks: 2,2'-biphenol as a bridging and book-end ligand in discrete and extended Co(ii) architectures in CrystEngComm

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Bradley JM (2010) MCD spectroscopy of hexanuclear Mn(III) salicylaldoxime single-molecule magnets. in Dalton transactions (Cambridge, England : 2003)

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Fairbairn RE (2012) Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition. in Chemical communications (Cambridge, England)

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Houton E (2012) Ferromagnetic exchange in a twisted, oxime-bridged [Mn(III)2] dimer. in Dalton transactions (Cambridge, England : 2003)

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Inglis R (2009) Twisting, bending, stretching: strategies for making ferromagnetic [Mn(III)3] triangles. in Dalton transactions (Cambridge, England : 2003)

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Kennedy S (2010) Metal-organic calixarene nanotubes. in Angewandte Chemie (International ed. in English)

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McIntosh RD (2011) p-tert-Butylcalix[8]arene: a support for sodium and sodium-manganese clusters that exhibit interesting self-assembly properties. in Dalton transactions (Cambridge, England : 2003)

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McLellan R (2014) Discovering the pivotal role of carbonate in the formation of a bis-phenolate supported Co15 cluster. in Chemical communications (Cambridge, England)

 
Description The first use of calix[n]arenes to construct homo- and heterometallic cluster compounds for use as single-molecule magnets and magnetic refrigerants.
Exploitation Route Fundamental chemistry and physics which underpins potential application in materials science.
Sectors Chemicals
URL http://www.chem.ed.ac.uk/staff/academic-staff/professor-euan-k-brechin