Laser Induced Micro Plasma Processing (LIMP2)

Lead Research Organisation: Liverpool John Moores University
Department Name: General Engineering Research Institute

Abstract

Micromachining materials such as ceramics and polymers for use in the medical implant or electronics industry is becoming an increasingly important activity for UK industry. Creating features on the micron scale or depositing coatings on the nanoscale has enabled the above industrial sectors to develop new solutions to such applications as: the acceptance of implants by the human body or patterning of thin conduction layers on touch-screen displays at a high resolution, allowing the phone's owner to watch movies while travelling.
All of these breakthroughs in medical devices and microelectronics, are made possible by the creation of small features. Laser Induced Micro Plasma Processing (LIMP2) will be an enabling tool allowing the production of features smaller than the actual laser spot which can be as less than 10 um. LIMP2 would also allow lasers to be used on materials that up to now have been impossible to machine by laser.
The aim of the project is to develop an understanding of how a plasma, a highly energetic hot gas, and laser beam interact at the surface of different substrates such as polymers, glass, metals and ceramics. It will attempt to answer such questions as "Can we control the plasma-laser beam interaction using electrical and magnetic fields and in so doing create interesting effects that will allow the plasma to be pinched into an area that is smaller than the laser spot diameter"? In so doing LIMP2 will allow a relative inexpensive laser system to machine directly on the nanoscale.
LIMP2 will introduce a new manufacturing technology that will be employed in the manufacturing of high value high performance electronic goods. This will benefit the UK suppliers of laser sources into the electronics production machine market. The other benefit that the general public will see in terms of healthcare. An important application in the medical field is microstructure texturing of medical implants such as stents and artificial joints. LIMP2 can be used to create novel microstructures that have the property of being able to control how a living cell interacts with the surface of the implant. The structures will allow one type of cell to grow while suppressing other types that would prove detrimental to the patient's health, causing swelling of a joint and possible rejection of the implant.
The UK companies who are supporting the project will also gain immediate benefits from a successful conclusion of the project. Two laser companies are working together to support the project, one based in the Midlands the other in the South West of England. LIMP2 would open new markets for their laser systems allowing them to compete in the competitive microelectronics market in the Far East.
Two of the projects supporting companies Biomer Technology and MicroSystems plan to use LIMP2 in medical devices market but on very different materials. Biomer Technology produces a polymeric coating that they use to coat medical devices. Biomer is interested in LIMP2 micro-machined surfaces that can control cell growth. MicroSystems on the other hand produce micro-moulds for major pharmaceutical companies. MicroSystems see LIMP2 being used on their micro-moulds to produce surfaces that are hydrophilic, (likes water) or hydrophobic, repels water molecules. This type of control over a surface property is very useful not only in the medical device sector but in other sectors such as aerospace, electronics, and the defence industry.

Planned Impact

The impact of LIMP2 can be divided into two areas, impact within the LIMP2 consortium in terms of economic and social impact such as wealth and job creation. The second area is those outside the consortium such as other end users involved in micromachining.
Fianium: LIMP2 will help strengthen Fianium through laser system sales into applications that are at present beyond the processing capability of their traditional picosecond laser systems. Fianium specialising in picoseconds laser systems they are looking to expand their market into other sectors in both Europe and the US. The medical device market looks especially lucrative, but the difficulty at present is that the Fianium laser system produce only small pulse energy systems and combined with the poor absorption of polymers at 1064nm both of these factors are making it difficult to exploit this market. LIMP2 impact by combining both laser beam and plasma in polymer processing would open the medical device market and allow Fianium to complete with traditional laser processing in the green and UV in terms of both processing quality and the price of the system. The benefits for Fianium would be in the creation of extra jobs and an increase in profitability.
Another potentially important application where LIMP2 could produce major benefits for Fianium is in the processing of thin films. Synergy exists between both Fianium and another consortium member Oxford Lasers with respect to this application. Germany are at present investing in solar cell technology and a big application for lasers will be in scribing thin coatings so isolating areas of conducting tracks. Film thicknesses greater than twenty microns could prove problematical for the Fianium system. LIMP2 impact for Fianium with respect to this application will be in allowing thicker film processing and reducing cycle times. This could have an important impact on earning foreign exchange for the UK in what is primary a Germany market supplied by German laser companies.

GSI Group: The benefit for this company will be extending their knowledge in hybrid laser processing. LIMP2 will be timely for GSI as they have purchase of a number of US laser manufacturers who produce micromachining laser systems. LIMP2 will be the first micro hybrid laser processing application. The impact will be first felt in the application group at Rugby with dissemination to the other US based companies through Rugby hub and the Photonics in Engineering Group (PiE) at LJMU. Though LIMP2 was initially aimed at the picosecond laser system of Fianium, GSI have recognised the potential impact LIMP2 could have with respect to micromachining with nanosecond laser pulses and potential lucrative markets in the plasma screen and photovoltaic cell production in the Far East and as such have given LIMP2 their full support.

Oxford Lasers: LIMP2 could have a major impact for one of Oxford Laser ongoing European research programmes, that of laser material processing of thin films. A description of the actual film is prohibited due to NDA but the performance of a picosecond laser system would be enhanced by LIMP2 hybrid processing. These results could be easily translated to other application where a thin coating needed to be machined on a substrate.

Biomer Technology Ltd: Biomer and the PiE group have a close working relationship. In collaboration with Biomer and the University of Liverpool LIMP2 will be introduced onto a project looking at the control of stem cells using surface topography. Also in parallel with this activity working with bio interests based within GERI, LIMP2 will be used to surface texture a polymer substrate supplied by Biomer that will be used in a coated stent application. The project will look at using surface texturing to control the growth rate of smooth muscle and endothelial cells. If this proves possible then the benefits to Biomer would be significant. Wider impact will be covered in the pathways document.

Publications

10 25 50
publication icon
French. P. W Journal Paper in Applied Surface Science

 
Description Laser Induced Micro Plasma Processing is a new and novel way to produce nano and micro-structuring on a polymer surface and change the surface properties in useful and interesting ways. We touch surfaces every day of our lives without every thinking about the actual surface itself, whether that surface is in the kitchen, the office or a car or door handle we do it without any thought of what is on the surfaces or what's the surfaces microstructure. It is only when there is a potential problem, like a surface being contaminated with a toxic pathogen, on say, a hospital ward do we stop think how a surface can affect our lives. Laser Induced Micro Plasma Processing (LIMP2), as the name suggests, is a laser based processing method that allows you to change the surface properties making it sticky for paints and coatings or make the surface more difficult for marine life to attach. This last application in antifouling technology is important as it gives a surface antifouling properties that doesn't rely on toxic paints which can be detrimental to marine animals and sea life in general. It can be used to machine biomedical polymers and produce a surface that can control cell growth, helping the cells to adhere to a biomedical implant reducing the time for a patient to be in hospital. As part of this EPSRC funded project the LIMP2 team working at Liverpool John Moores University had to develop a coating method for metal on to glass so that coated glass could be used as a plasma generating tool for the LIMP2 process. This new laser based coating method will be used in such fields a laser welding for the aerospace sector and the development of a new generation of sensors based on metamaterials. It is hoped that LIMP2 coating method and LIMP2 processing technology will lead to novel bio-sensors for cancer detection in what is called "point of care" applications. The project was only for 24 months but it has taken a blue sky idea and developed it into a potential anti-fouling technology and bio-medical surface enhancement technique as well as a new way to coat substrates with metals and potentially other materials.
Exploitation Route The whole idea of Laser Induced Micro Plasma Processing was to develop a low capital cost processing technique for polymers that were non-absorbent in the IR spectrum. This notion of developing low cost processing technology is still very relevant for groups who are working in the field of surface functionalisation. It is hoped that LIMP2 is used a new processing tool for surface functionalisation what every the scientific field the group is work in.
In the process of developing LIMP2 I had to develop a method of coating glass with metal so that I could use these glass slides as processing tools. This work will be carried on in developing a potential novel processing tool for carbon fibres and coating composites.
Sectors Aerospace, Defence and Marine,Chemicals,Energy,Environment,Healthcare,Manufacturing, including Industrial Biotechology,Pharmaceuticals and Medical Biotechnology

 
Description Experimental evidence shows that we can have an effect on the behaviour of cells interaction with a polymer surface. We wish to extend LIMP2 into an area of antifouling on polymer substrate. This area will hopefully be explored this summer as part of a SMc project.
First Year Of Impact 2015
Sector Aerospace, Defence and Marine,Pharmaceuticals and Medical Biotechnology
Impact Types Economic

 
Description ANFOLASE - Laser Textured Surfaces for Anti-Fouling 
Organisation Biomer Technology
Country United Kingdom 
Sector Private 
PI Contribution Using the developing technology (Laser Induced Micro Plasma Processing) to process polymer material for anti-fouling trials for Biomer Technology.
Collaborator Contribution Biomer Technology supplied polymeric material that they are developing for applications in the oil and gas industry. If this material is to be successful in this market the material must have anti-fouling properties.
Impact Biomer Technology is a member of a consortium that will us Laser Induced Micro Plasma Processing in an Innovate UK bid addressing anti-fouling novel technology. The total value of the project will be approximately 1M It will involve multi-disciplinary academic team from both engineering and biology as well as industry.
Start Year 2013
 
Description ANFOLASE - Laser Textured Surfaces for Anti-Fouling 
Organisation Liverpool John Moores University
Country United Kingdom 
Sector Academic/University 
PI Contribution Using the developing technology (Laser Induced Micro Plasma Processing) to process polymer material for anti-fouling trials for Biomer Technology.
Collaborator Contribution Biomer Technology supplied polymeric material that they are developing for applications in the oil and gas industry. If this material is to be successful in this market the material must have anti-fouling properties.
Impact Biomer Technology is a member of a consortium that will us Laser Induced Micro Plasma Processing in an Innovate UK bid addressing anti-fouling novel technology. The total value of the project will be approximately 1M It will involve multi-disciplinary academic team from both engineering and biology as well as industry.
Start Year 2013
 
Description Polymeric Surface Functionalisation (International) 
Organisation University of Ghent
Country Belgium 
Sector Academic/University 
PI Contribution The RA on the LIMP2 project traveled over to Ghent for a meeting to discuss collaboration on polymeric surface functionlisation. The RA returned with samples from Ghent to be processed here at LJMU using LIMP2. Dr Peter Cools has visited us here at LJMU and it has been agreed that we will send the RA with one of our laser systems to the University of Ghent to investigate both the surface chemistry of direct laser processing of aluminium, LIMP2 processed polymers.
Collaborator Contribution Our partners in Ghent have the following equipment for plasma analysis as well as other techniques for surface analysis, Laser induced fluorescence spectroscopy (LIF), Two photon LIF (TALIF), Tunable diode laser absorption spectroscopy (TDLAS), Fast imaging High resolution optical emission spectroscopy, Contact Angle Measurement, X-Ray Photo-electrons Spectroscopy, Fourier Transform Infrared Spectroscopy.
Impact We have produced a Polymeric material, that has been processed using the LIMP2 technique, with interesting surface qualities never seen before. This work will be the foundation for our first joint paper with the University of Ghent
Start Year 2014
 
Description Dissemination Activities Nanosmat Dublin 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact The PI, Dr Paul French, gave a presentation at NANOSMAT 2014 in Dublin, Ireland. His presentation generated interest among the audience and he was approached by Dr Dermot Brabazon Director of Advanced Processing Technology Research Centre at Dublin City University. Dr Bradazon group has an interest in laser micro-machining, and is keen to collaborate on a future Horizon of INTERREG project, developing the concept of "Super Surface".

Dr Dermot Brabazon approached Dr French after the presentation and suggested areas of collaboration including hybrid laser-plasma processing for cell control in biomedical applications. Dr French will invite Dr Bradazon over to the UK later this year to discuss Horizon 2020 as Dr Dermot has agreed to use an Irish funding scheme to support a joint European project
Year(s) Of Engagement Activity 2014
 
Description Dissemination Activities Nanosmat US 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact The RA, Adam Rosowski, who worked on the Laser Induced Micro Plasma Processing project gave a presentation at NANOSMAT 2014 in Houston, Texas. His presentation generated interest among the audience and he was approached by to particular members of the audience, Dr Peter Cools from the University of Ghent and Associate Professor Dr Samir M. Iqbal, for the University of Texas, Arlinton. We are working cloesly with Dr Cools on both LIMP2 and another laser based project.

Dr Peter Cools has visited us here in Liverpool and gave a presentation on the areas of research that he is conducting in the department of applied physics. We have now established a long term concord to work together, producing joint publications and look for future funding.
Year(s) Of Engagement Activity 2014
 
Description EPSRC Micro Surface Structuring 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact I have been invited to give a presentation on LIMP2 at the Micro Surface Structuring meeting being held by EPSRC Centre for Innovative Manufacturing in Ultra Precision

The presentation will be based on how we are using LIMP2 in surface texturing for cell control. I'm hoping to speak with people who have an interest in bio-technology.
Year(s) Of Engagement Activity 2014
URL http://www.ultraprecision.org/news/events/micro-surface-structuring/