Molecular quantum devices

Lead Research Organisation: University of Oxford
Department Name: Materials

Abstract

Whenever a fundamental new principle of science is discovered, the chances are that sooner or later a way will be found to use it for a new technology. The quantum mechanical principles of superposition and entanglement, identified back in the 1930s, are now understood to offer spectacular potential for technological applications. Superposition describes how an object can be in two states at once, as it were 'here' and 'there' at the same time. Two or more objects in superposition states can be entangled, so that measurements on each of them are correlated in a way that goes beyond anything we would expect from everyday intuition. Exploiting these effects in practical devices would provide new capabilities for fields such as molecular light harvesting and for molecular quantum technologies such as sensors, simulators, and quantum computers.

Successful laboratory experiments have shown that molecules of various kinds can exhibit these crucial quantum properties. Molecules are composed of electrons and atomic cores or 'nuclei'. Both electrons and nuclei can have a property called spin associated with them that makes them behave like tiny bar magnets. We have confirmed that electron and nuclear spins can be put into superpositions or entangled, and they can last for a long time in that condition. Most of the experiments so far have been in small test tubes. The crucial step now is to implement the same effects in nanometre scale electrical devices, such as single electron transistors consisting of single sheets of carbon rolled up as nanotubes or flat as sheets of graphene. By making hybrid technologies that combine molecules with nanoelectronics, we will lay the foundation for scaling up to more complex systems.

At this very small size, different atoms or molecules in different places affect the behaviour of the device. A breakthrough in the past few years enables us to see the positions of individual atoms in the materials which we want to use in our devices. The technique is aberration-corrected electron microscopy, and provided the electrons are not too energetic it is possible to look at the structures which we have made without damaging them. In this way we shall be able to relate the device performance to the atomic resolution microscopy of the component materials.

To take this quantum nanotechnology from engineering to application is extremely challenging, and lies at the limit of what is realistically feasible. It needs a team with a remarkable combination of expertise, who know how to collaborate across scientific fields. We must:
1. design the devices which we shall build, based on a deep understanding of how to control their quantum states;
2. produce the materials which we need, such as molecules with suitable spin states with carbon nanotubes and graphene for electrical substrates;
3. make nanoscale devices and examine them in a microscope to see where the individual atoms and molecules are;
4. perform the experiments to develop the quantum control and measurement for the effects which we aim to exploit;
5. undertake theoretical modelling to understand the electron behaviour and to design new materials systems for improved performance.

We are fortunate in having the right people and facilities to do this. The platform grant will sustain a team which brings together all the relevant skills. Together we shall make progress towards the emerging quantum technologies that will implement the deep resources of quantum mechanics in working solid state devices.

Planned Impact

Our underlying motivation in the research to be supported by this Platform Grant is that it should contribute to practical technologies which exploit the quantum resources of superposition and entanglement. If and when such technologies become available there will be simultaneous societal benefits, to users, and commercial benefits, to manufacturers.

The EPSRC Physics Grand Challenges include 'Quantum Physics for New Quantum Technologies' as one of four themes to be pursued, recognizing that they should not be addressed exclusively by physics. The societal and economic impacts of quantum technologies are well summarized in the full report, "Progress in this Grand Challenge could have huge economic benefit through leading to the development of new high value, high tech industries. Companies may manufacture devices or use quantum technology to simulate complex systems in areas such as metrology, sensing, cryptography, drug discovery, or energy. The societal impact also has the potential to be large as information and information technology is such a pervasive part of modern life. Quantum technology may help us solve major global challenges and will most certainly change the technology people use everyday."

We foresee three classes of technology from our research:

1. New technologies which use the deeper quantum phenomena of superposition and entanglement. The first of these may be sensors for small changes in magnetic field, with entanglement enhanced sensitivity and nanoscale size. A second application may lie in using synthetic molecular structures as simulators for studying other quantum processes that lie beyond modeling techniques such as mean field theories. Ultimately there is the exciting prospect of quantum computing, which has driven so much of the development of quantum information processing, and to which our research may contribute some building blocks.

2. Existing technologies which will benefit from the enhanced quantum properties which we shall develop such as long coherence times. Electron spin resonance is an established technique for determining distances in biology, and the availability of molecules with longer coherence times will increase accuracy and make it possible to measure larger separations. Suitable biocompatible molecules may also contribute to the application of ESR imaging for certain niche problems in medicine.

3. Technological spin-offs which do not use coherence or entanglement, but which can benefit from the materials and techniques which we develop in pursuit of the quantum goals. Fullerene molecules serve as an excellent acceptor in nanocomposite photovoltaic structures, and what we learn through functionalizing fullerenes may offer new routes to tailoring their electrical and chemical properties. Anything that we learn about carbon materials and their properties in devices has the potential to contribute to the current pursuit of carbon-based electronics.

We also find that our work can be explained in such as way as to excite the imagination of some of the best and brightest school students, and thus motivate them to choose to study mathematical and physical science subjects at A level and beyond, thus helping to sustain a future supply of qualified people for a wide range of professions and industrial careers.

Publications

10 25 50
 
Title It Keeps Me Seeking 
Description The invitation from science, philosophy and religion 
Type Of Art Creative Writing 
Year Produced 2018 
Impact Book published by Oxford University Press 
URL http://andrewbriggs.org/
 
Title The Penultimate Curiosity 
Description How science swims in the slipstream of ultimate questions 
Type Of Art Film/Video/Animation 
Year Produced 2016 
Impact Book, film, TV broadcasts, SVOD 
URL http://andrewbriggs.org/
 
Description Quantum interference in single molecule devices
Exploitation Route Materials for low-energy ICT
Sectors Digital/Communication/Information Technologies (including Software),Electronics,Manufacturing, including Industrial Biotechology

URL http://andrewbriggs.org
 
Description The Penultimate Curiosity book published by Oxford University Press in 2016 The Curious Science Quest series published by Lion Hudson 2018-2019
First Year Of Impact 2016
Sector Digital/Communication/Information Technologies (including Software),Education,Electronics,Leisure Activities, including Sports, Recreation and Tourism,Culture, Heritage, Museums and Collections
Impact Types Cultural,Societal,Economic,Policy & public services

 
Description EPSRC Programme Grant
Amount £5,296,044 (GBP)
Funding ID EP/N017188/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Academic/University
Country United Kingdom
Start 01/2016 
End 12/2021
 
Description Quantum Technology Capital
Amount £1,445,889 (GBP)
Funding ID EP/N014995/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Academic/University
Country United Kingdom
Start 04/2016 
End 03/2019
 
Description Molecular sensing 
Organisation Oxford Nanopore Technologies
Country United Kingdom 
Sector Private 
PI Contribution Patented method for forming graphene nanogaps
Collaborator Contribution Genome sequencing
Impact Publications and technology
Start Year 2016
 
Title Low cost quantum key distribution system 
Description Architecture design for surface code fault-tolerant distributed quantum computing 
IP Reference US20070025551 
Protection Patent granted
Year Protection Granted
Licensed Commercial In Confidence
Impact This invention formed the basis of the Oxford led Quantum Technology Hub NQIT.
 
Title Method for forming nano-gaps in graphene 
Description Method for forming nano-gaps in graphene 
IP Reference US Patent 20170145483 
Protection Patent granted
Year Protection Granted 2017
Licensed Yes
Impact Funded studentship
 
Company Name Designer Carbon Materials 
Description Spin out company from the University of Oxford with the aim to commercialise higher fullerenes, endohedral fullerenes and their derivatives. 
Year Established 2014 
Website http://www.designercarbon.com/
 
Description Quantum of Spin 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact The Quantum of Spin exhibit was the largest and among the most successful of the many exhibits at the Royal Society Summer Science Exhibition in 2012. Over the course of 1 week from 3 to 8 July, our team explained their research to over ten thousand visitors.
Year(s) Of Engagement Activity 2012
URL http://sse.royalsociety.org/2012/exhibits/
 
Description The Curious Science Quest (OUMNH) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact The Curious Science Quest: presentation by Julia Golding of her series for children based on The Penultimate Curiosity by Roger Wagner and Andrew Briggs, held at the Oxford University Museum of Natural History.
Year(s) Of Engagement Activity 2018
URL http://goldinggateway.com/julia-golding/curious-science-quest/
 
Description Wigner Distinguished Lecture (ORNL) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact ORNL's Eugene P. Wigner Distinguished Lecture Series in Science, Technology, and Policy promotes dialogue among Oak Ridge researchers and renowned leaders in science, industry, and government. The invited lecturers bring distinct perspectives to the lab's community of scientists and engineers, whose scientific discoveries and technological breakthroughs target some of the world's most pressing problems.
Year(s) Of Engagement Activity 2016
URL https://www.ornl.gov/content/wigner-distinguished-lecture-series