Feasibility of a wetting layer absorption carbon capture process based on chemical solvents

Lead Research Organisation: University of Edinburgh
Department Name: Sch of Engineering


New ideas for carbon capture are urgently needed to combat climate change. Retro-fitting post-combustion carbon capture to existing power plants has the greatest potential to reduce CO2 emissions considering these sources make the largest contribution to CO2 emissions in the UK. Unfortunately, carbon capture methods based on existing industrial process technology for separation of CO2 from natural gas streams (i.e. amine scrubbing) would be extremely expensive if applied on the scale envisaged, as exemplified by the recent collapse of the Government's CCS project at Longannet power station. Moreover, many of the chemical absorbents used, typically amines, are corrosive and toxic and their use could generate significant amounts of hazardous waste. So, more efficient and 'greener' post-combustion CCS technologies are urgently needed if CCS is to be adopted on a global scale.

Efficient separation of CO2 from flue gases requires at least the following; i) an inexpensive sorbent with high CO2 working capacity and selectivity, ii) high rates of CO2 mass transfer into and out of the sorbent, and iii) a low energy cost for sorbent regeneration. A traditional aqueous amine scrubbing process has high selectivity, but is less effective in terms of capacity, mass transfer rate, and sorbent regeneration energy penalty. Here, we propose to investigate a novel process based on the 'wetting layer absorption' (WLA) concept in which a porous material is used to support liquid-like regions of absorbing solvent, which in turn absorb the gas of interest, in this case carbon dioxide. This process, recently invented by one of the authors (MS) of this proposal at Strathclyde, is being pioneered by researchers in Scotland. Initial work involved investigation of the use of physical solvents. Here the focus is on a process involving chemical solvents, i.e. amines. This process should have a high capacity, high slectivity, and high rates of mass transfer. Another novel aspect of this work is the investigation of microwave regeneration, which could also result in much reduced costs for sorbent regeneration. Finally, the process would involve orders of magnitude reductions in solvent recycling, and could make use of much less toxic and corrosive solvents, leading to a much greener process. Ultimately, the WLA process involving chemical solvents could potentially significantly reduce the cost and environmental impact of carbon capture.


10 25 50
Description Two novel techniques to characterize the fundamental properties of the interactions of carbon dioxide on novel wetted nanoporous materials have been developed.
A rapid heating system based on a purposely designed microwave system has been used to study the efficiency of this approach to reduce the energy penalty and size of carbon capture units.
A novel flow system has been developed to study the performance of novel mesoporous materials wetted with highly selective solvents.
These fundamental properties are needed to evaluate the carbon capture processes based on these materials and regeneration techniques.
Exploitation Route The results form the basis for further research into these novel approaches applied to capture of carbon dioxide from industrial sources.
Sectors Chemicals,Energy,Environment