Novel Nanoreplication Methods for Manufacturing of Optoelectronic and Photonic Devices

Lead Research Organisation: University of Leeds
Department Name: Physics and Astronomy

Abstract

Liquid Crystal Displays (LCDs) have quickly grown to become the dominant interface between computer and user; television and viewer; and machine and operator. This success is largely due to the adaptability of the technology to hit new target specifications through the creation of new manufacturing methods and components. In the last three years, novel LCDs have begun to be established in the retail labelling sector through the spin-out company ZBD Displays, Europe's second fastest growing technology company of 2012. This UK success story is based on a new type of LCD in which complex sub-micron textures are manufactured on the internal surface of an otherwise standard display, an invention made by the applicant of this proposal.

ADDING NANO-STRUCTURES TO LCD TO CREATE A NEW BREED OF OPTOELECTRONIC DEVICES

Since founding and technically leading that company to the market place, the applicant now proposes to set up a world leading centre for novel manufacturing methods and technologies based at the University of Manchester. The proposed work will invent new novel sub-micron structures and apply them to a range of novel devices, from other liquid crystal devices used for display and non-display applications, full-colour electronic paper, to photonic devices and sensors. The applicant will bring exceptional industrial experience to the academic environment to not only create internationally judged high quality research, but also to have practical application and job-creation in the UK. It is a primary intention from the outset to create spin-out companies from the proposed work.

The proposal is for a five year period. The work will begin by studying methods for producing smaller and deeper structures than have been explored to date, applying these structures to different types of liquid crystal device, including ultra-fast displays and 2D optical modulators, novel adaptive optic systems (including a bistable contact-lens) and multi-stable phase modulators. As the work progresses, the theme will extend to surface profile aligned liquid crystal systems with additional dispersants included. A range of different dispersants will be investigated, from nano-particle colloids, Janus particle suspensions, emulsions and esoteric particles such as mesogenic nano-particles, carbon-nanotubes, and quantum dots. Key to inventing in this space is the ability to control and manufacture the required surface properties for the desired device operation. Eventually, the novel fabrication method will be extended to allow more complex structures suitable for a wider range of micro-fluidic systems, not just those using liquid crystals.

The range of applications of the work is enormous and diverse, from components in telecommunication systems, novel tuneable lasers, full colour flexible electronic paper that is easy to manufacturer, to biological sensors that can detect individual molecules or viruses.

Planned Impact

The project vision is to create a world-leading centre of excellence for novel fabrication methods of electro-optic and photonic devices; invent revolutionary new devices by combining sub microscopic surface features into novel optoelectronic devices. This approach has previously been successful for the applicant, who founded the UK success story ZBD Displays Limited based on grating aligned liquid crystal displays. Now, the applicant intends to bring the expertise garnered from taking that idea from laboratory to market place, to create other new devices in a wide range of soft-matter systems. It is the project starting intention and a measure of project success, to create spin-out companies based on new IPR developed during the proposed work.

With nearly thirty years in the field of soft-matter physics, the applicant is well known and respected internationally both academically and industrially. Through his previous role as technical leader of the world-renowned Display and Liquid Crystals Group at DERA, Malvern, the applicant already has strong links across the UK soft-matter academic community, and with the various industrial players in this field. This is an area where the UK maintains a world-lead, and remains one of the key areas for on-going support within the EPSRC. Where spin-outs are not the most suitable exploitation route, the applicant will work closely with Manchester University's Intellectual Property (UMIP) group to license the technology to industrial players, both UK and international. The proposal already has strong financial support of ZBD Displays limited, who wish to use improvements related to grating aligned LCDs for retail applications. Many other applications are envisaged. For example, Merck Limited in Southampton, world-leading Quantum dot supplier Nanoco (who have close ties to the University) and Kingston Chemicals of Hull, will benefit from new devices operating with materials that they provide; Film Optics Limited in Shrivenham are a potential beneficiary as a produce of optical films suitable for nano-replication; US spin-out Gamma Dynamics (with whom the applicant also has a close interaction with) will benefit from lower cost manufacturing methods for their novel electro-fluidic approach to electronic paper.

The proposal will not just have an impact on wealth creation and UK industry, but also provide a means for helping target more commercial application across many of the academic groups in the UK working on liquid crystals and soft-matter systems. The creation of a facility dedicated to device manufacturing and operation will help focus the work of the chemists, physicists and mathematicians already working in the area. The number of groups already device focussed is relatively small compared to all of the other nations researching in this field. Adding the applicant's expertise in this area should have a major positive impact on the academic focus. It will also be a facility to provide validation of ideas from other academic devices in practical devices.

The applicant's industrial and entrepreneurial experience will benefit the University of Manchester in particular. This is most timely, with the explosion of interest and opportunity springing from its work on Graphene, and the formation of the National Graphene Institute.
 
Description We have developed novel manufacturing methods using 3D ink-jet printing for fabricating on curved plastic surfaces. Although concentrating on switchable contact lenses, the techniques being applied are applicable to other optoelectronic devices such as beam steering and adaptive optic applications.

Research into the embossing manufacturing method that allows profiled structures adding into electrically addressable devices has been extended to include aligned reactive mesogen photopolymers. The addition of birefringence to the optical structures has led to novel optical applications such as polarisation independent operation in switchable liquid crystal lenses. This work and the resulting patent have attracted the company Merck to investigate the use of such methods in Augmented and Virtual Reality applications.
Exploitation Route Several papers have been published, three patents filed and a company spun-out. The award is a fellowship aimed at bringing industrialists into an academic environment. This has been very successful, since the academic is involved in several collaborative projects (both EPSRC funded and Industrial), has written several grant applications and settled into teaching too.

The spin-out company is building prototypes of remotely switchable contact lenses for the relief of presbyopia. It has recruited 3 employees: one PDRA employed on this project (Bailey) and one MPhys student who did a relevant project with me in his 4th year. During the course of 2019 it will seek a much larger funding round and will begin to employ a much larger number of staff, and take up a position in the Nexus innovation centre at Leeds. The aim of the next stage will be to develop and begin certification of the contact lens first products. Many of the manufacturing methods being developed have been tuned from those set up by myself and Bailey in the Leeds LCD cleanroom.
Sectors Digital/Communication/Information Technologies (including Software),Electronics,Healthcare,Manufacturing, including Industrial Biotechology

 
Description Creation of spin-out company. Raising of grub round from VC (IP Group) and Impact Acceleration Funding from University of Leeds (CLIP). Raising of £460,000 seed round from IPG, Parkwalk ventures and Innovate UK. The company recruited 3 people and led to an infrafred powered switchable contact lens in 2020 (see Bailey et al 2022, J. Phys. D.). However, the company failed to raise its second VC funding round in 2020. Funding for further research on birefringent lenses from Merck under the "Leeds and Merck Partnership".
First Year Of Impact 2018
Sector Electronics,Healthcare,Manufacturing, including Industrial Biotechology
Impact Types Economic

 
Description Contact Lenses Independent of Polarisation (CLIP)
Amount £50,000 (GBP)
Organisation University of Leeds 
Sector Academic/University
Country United Kingdom
Start 09/2016 
End 03/2017
 
Description Lipid-coated Liquid Crystal Droplets as Highly Sensitive Sensors of Bacterial Toxins and other Bio-active Molecules
Amount £1,028,735 (GBP)
Funding ID EP/P024041/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 03/2017 
End 02/2020
 
Description Novel Grating Aligned Liquid Crystal Devices
Amount £75,000 (GBP)
Organisation Displaydata 
Sector Private
Country United Kingdom
Start 01/2016 
End 06/2019
 
Title Data for 'Method for tuneable homeotropic anchoring at micro-structures in liquid crystal devices' 
Description The data included were used to characterise the efficacy of a vapour-phase silane surface treatment for polymer microstructures in liquid crystal devices. The data is referenced in "Method for tuneable homeotropic anchoring at micro-structures in liquid crystal devices" by Sophie A. Jones, James Bailey, David R. E. Walker, Guy P. Bryan-Brown, and J. Cliff Jones. Details of the experimental and modelling methods used to obtain the data can be found in the readme.txt file. 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Description Consultancy for Dynamic Vision Systems 
Organisation Dynamic Vision Systems Limited
Country United Kingdom 
Sector Private 
PI Contribution This is the spin-out founded by myself and Prof H. Gleeson at Leeds, and Prof P. Morgan at Manchester University. Following JCJ winning a Impact Acceleration grant (EPSRC funded at Leeds University), this led to an Innovate UK grant and investment from the venture capital company IPG, totalling £460,000. The consultancy enables ongoing interaction between Prof Jones and DVS.
Collaborator Contribution Financial.
Impact Company was dissolved in May 2020, after failing to raise its second funding round.
Start Year 2018
 
Description Displaydata studentship 
Organisation Displaydata
Country United Kingdom 
Sector Private 
PI Contribution Displaydata fund a studentship (Sophie Jones) to work on novel grating aligned liquid crystal devices, particularly those relating to dual-mode OLED/LCD operation. The work includes both experimental and theoretical analysis of sub-diffractive gratings, characterisation of the surface anchoring on new photopolymers, and studying novel materials (synthesised at York Chemistry department) as high flexoelectric (ie low voltage) additives.
Collaborator Contribution Displaydata provide constant advise and materials for progressing this work, including photopolymers, surfactants, ITO coated glass, alignment layers, spacers, liquid crystals, polarisers and other optical layers.
Impact Oral presentations at: BLCS Germany (2017), ECLC Moscow (2017).
Start Year 2016
 
Description Non Display Applications of Liquid Crystals 
Organisation Merck
Department Merck UK
Country United Kingdom 
Sector Private 
PI Contribution Merck have chosen Leeds Soft Matter to invest £1M over five years in Postdoctoral researchers and PhD studentships. This is based on three academics who comprise the Liquid Crystal Group, including J Cliff Jones. A major attraction was the fabrication laboratories set up by JCJones at Leeds as part of this Fellowship. The work will concentrate on novel liquid crystal devices, as a direct result of the research done on this Fellowship on novel manufacturing methods.
Collaborator Contribution In addition to the studentships and postdoctoral researchers, Merck will contribute their wealth of experience in liquid crystal materials, including in kind access to their world leading portfolio of materials. Importantly, the collaboration will target problems that directly arise from commercial customers to Merck. Through access to these relationships, real economic impact from the research is envisaged. Each 6 months, Merck's requirements are reviewed and projects chosen. These are either for 6 months duration for completion by the postdoctoral associate (Dr. Markus Wahle) or 3 - 4 year projects for the studentships. The choice of project is heavily weighted to those which a customer of Merck (usually an LCD manufacturer or enduser) has declared actual interest in.
Impact In the 9 months that the project has run so far, JCJones has won 2 projects for the Postdoctoral worker. These have been considered very successful by the company, and has lead to a patent application being in the process of filing. Two studentships have also been won by Prof Jones, one joint with Merck on the SOFI CDT (starting April 2018), and the other a second CASE award (Started Oct 2017).
Start Year 2017
 
Title A control system for a switchable lens 
Description A dynamically switchable contact lens, 2000, operable to switch between first and second focal states, each focal state having a different optical property (e.g. focusing power), the lens having: a power source, 2006, (e.g. a super capacitor or a sugar-based rechargeable battery); a controller, 2005, for controlling the operation of the lens; a transceiver, 2004, for communicating with a second lens and/or an external controller; wherein the lens is paired with the second lens by means of the external controller. The lens may comprise a liquid crystal material disposed in a cavity and the may be altered according to an electrical field applied to the liquid crystal material. The first and second lenses may be paired by the external controller such that they are later operable in a standalone mode independent of the external controller. The lenses may determine that a change in focal state is required based on a ciliary muscle sensor, 2007, or the user may trigger the change with wink or blink of a certain length. 
IP Reference GB2557935 
Protection Patent application published
Year Protection Granted 2018
Licensed Yes
Impact Used as IPR in forming of the spin-out company Dynamic Vision Systems.
 
Title Improvements in and relating to optical elements 
Description Embossing of orthogonal aligned Reactive Mesogen optical structures to impart polarisation independent operation on contacting liquid crystal. 
IP Reference WO 2020/002930 A1 
Protection Patent application published
Year Protection Granted 2018
Licensed No
Impact The project has created interest at Merck Ltd, who include it as a topic for further research in the joint Leeds and Merck Partnership project. THe patent was transferred to Merck at second filing, and they are continuing to manage it.
 
Company Name Dynamic Vision Systems 
Description Spinout company with license to IPR from University of Manchester. 
Year Established 2015 
Impact Novel contact lens system developed enabling the correction of presbyopia for the ageing population. Raised grub round £50k to begin business plan development. Working closely with the Impact Acceleration Account funding (CLIP) from the University of Leeds to produce demonstrator capable of raising significant first funding round in 2017.
 
Description 50th Anniversary of the LCD Meeting 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact A one day conference conceived and organised by myself to celebrate the 50th anniversary of the first announcement of the LCD by RCA. Invited speakers included Cyril Hislum, Martin Schadt, Peter Raynes and Phil Bos, together with a host of other experts exploring the past, present and future of the LCD. The event was held at the RAEng.
Year(s) Of Engagement Activity 2018
URL https://www.tandfonline.com/doi/full/10.1080/1358314X.2018.1529129
 
Description For Your Viewing Pleasure 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact As part of inauguration to the position of President of Engineering for the British Science Association 2019, I was invited to speak at the Festival of Science. I gave a talk on the history of Liquid Crystal Displays, the role played in Yorkshire and the UK, and a little on the process of innovation.
Year(s) Of Engagement Activity 2018
URL https://www.britishsciencefestival.org/event/for-your-viewing-pleasure/
 
Description Inaugural Lecture at Leeds 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Undergraduate students
Results and Impact Lecturing to a largely university audience (academics and students) about the skills required for forming and running a small technology company. Several instances of follow up contact associated with people wishing to pursue their own entrepreneurial ambitions.
Year(s) Of Engagement Activity 2016
 
Description Interview by ITV Yorkshire News 
Form Of Engagement Activity A broadcast e.g. TV/radio/film/podcast (other than news/press)
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact Interview associated with the Festival of Science. Appeared on Calendar News, 11th September 2018. I spoke about the use of liquid crystals in contact lenses, and how Yorkshire had a long history of success in this field. The broadcast was aimed at increasing the audience to the event, which went very well, and I was commended on my interview.
Year(s) Of Engagement Activity 2018
 
Description Living in the Materials World (Pint of Science 2019) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Undergraduate students
Results and Impact Pint of Science holds an annual festival in Leeds. One of the occasions in 2019 was on the Impact of Materials in Society, and I gave a talk on Soft Matter and Liquid Crystals
Year(s) Of Engagement Activity 2019
URL https://pintofscience.co.uk/event/living-in-a-material-world-
 
Description School Physicist of the Year Award, 2018. Ogden Trust and the University of Leeds 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact Presenter of Awards to School children aged between 14-16 and awarded best physicists in their areas. Schools from across Yorkshire and NE were represented. After completion of the Awards, I gave a speech on what a great career you can have as a physicist, and in particular how it can lead to fame, fortune and happiness. I was contacted after the event by email by one of the parents that reported that the event had had a profound effect on his child, who had been enthused by my speech and was now committed to physics.
Year(s) Of Engagement Activity 2018
URL https://physicalsciences.leeds.ac.uk/news/article/37/school-of-physics-and-astronomy/190/school-phys...
 
Description Society of Information Display - Student Meeting 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Postgraduate students
Results and Impact Invitation to headline a discussion session at the RAE sponsored by SID on how to be an Entrepreneur. Students from London to Manchester attended and created much interest. Several have made contact afterwards, and one in particular is following up with advice on forming her own company to commercialise a technology she has developed.
Year(s) Of Engagement Activity 2016
 
Description TEDx Malvern 2019 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Public/other audiences
Results and Impact A well attended talk was given to the annual TEDx conference held in Malvern. The talk described the history of the LCD, Malvern's role in its invention and the current status and societal impact of the technology.
Year(s) Of Engagement Activity 2019
URL http://tedxmalvern.co.uk/cliff-jones-2019/
 
Description TEDx Online 
Form Of Engagement Activity A broadcast e.g. TV/radio/film/podcast (other than news/press)
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Public/other audiences
Results and Impact Video of TEDx talk on Youtube. Garnered 180 views between 24th April 2019 and 13th February 2020.
Year(s) Of Engagement Activity 2018,2019
URL http://tedxmalvern.co.uk/cliff-jones-2019/