Next generation white LEDs using hybrid inorganic/organic semiconductor nanostructures for general illumination and wireless communication

Lead Research Organisation: University of Sheffield
Department Name: Electronic and Electrical Engineering

Abstract

There is a significantly increasing demand for sustainable energy-efficient technologies due to the world energy crisis and climate change. The energy consumed due to general illumination accounts for about 29% of the world's total energy consumption, currently using rather inefficient technologies often containing toxic elements. It is therefore necessary to develop ultra energy-efficient solid-state lighting sources to replace these incandescent and fluorescent lights, for which the leading candidates are mainly based on white light emitting diodes (LEDs). Such white LEDs can be fabricated from inorganic or organic semiconductors, with the former leading the way for high brightness and efficiency. These are constructed from III-nitride semiconductors, which have direct bandgaps across their entire composition range, covering the complete visible spectrum and a major part of the ultraviolet. Fast modulation of the white LEDs, at speeds undetectable to the eye, allows them to also be utilised as optical transmitters for wireless data communication. This opens up the exciting possibility of white LEDs serving as lighting sources for simultaneous illumination and wireless communication. This is the emerging technology of visible light communication (VLC) and has a number of major advantages over the present-day radio frequency (RF) communication technology, such as increasing security, eliminating any RF-induced health concern, etc

However, the performance and cost of current white LEDs is not sufficiently impressive to allow replacement of conventional lighting sources at the moment. Furthermore, in terms of VLC applications, the bandwidth is currently limited to the MHz level, which is well below the practical requirements of current broadband WiFi systems. This is due to the long carrier recombination lifetime of current III-nitride based LEDs, which are conventionally grown in a "polar" orientation containing intense piezoelectric fields. These fields result in a reduced overlap between the electron and hole wavefunctions in the active regions of the LEDs, which then suffer from long radiative recombination lifetimes (10-100 ns) and also low internal quantum efficiency. In addition, the conventional phosphors used to convert the emission to white light have even longer decay times and presents an additional limitation on the available bandwidth.

The project will employ non-polar III-nitrides and integrate the two major semiconductor families (organic and inorganic semiconductors) using a novel nanofabrication technology in order to achieve ultra energy efficient LEDs with ultrafast modulation speeds for next generation III-nitride based white lighting. Structuring on a nanometre scale will be used in the growth of the III-nitride layers to achieve high quality non-polar GaN, thereby eliminating the piezoelectric fields to give faster, more efficient devices. The nanostructures will also be used to introduce extra nanocavity effects, further reducing the radiative recombination lifetime and increasing the optical efficiency. The target of the project is a novel hybrid nanostructure to achieve prototype white-LEDs with a modulation speed on a level of 10 GHz and a step change in energy efficiency compared with the current state-of-the-art. The devices will be fabricated using metal-organic vapour phase epitaxy and cleanroom processing and fully characterised using optical and electrical measurements. Each stage in the process will be optimised and close working with industry will ensure that the resulting methods are practical and scalable to high volumes.

Planned Impact

The proposed work should deliver major impact in many areas, including technology, society, economy and environment. It has been predicted that replacing all existing light bulbs with white LEDs would save 15% of electricity generated worldwide, 15% of the fuel used, and reduce carbon emission by 15%. This will make very significant contributions to achieving an 80% reduction in carbon-emission by 2050, the challenging target required for the UK by Kyoto protocol. It will greatly contribute to minimising climate-change, and thus improving our environment. Unlike the current lighting sources which contain toxic elements white LEDs are truly eco-friendly lighting sources. In addition the expected results will lead to a revolutionary change in the concept of wireless communication. This will contribute to elimination of health concerns associated with current wireless communication, allow for wireless communication in airplanes and underwater, and significantly improve security.

The project also involves development of new technologies in advanced nanofabrication, next generation wireless communication, III-nitrides and organic materials, which are all important frontiers of current scientific research. These all align extremely well to EPSRC priority areas, such as Manufacturing, Digital Economy, Energy and Healthcare as well as the priority themes and competences of the Technology Strategy Board (TSB). The vibrancy and importance of III-V activities in the UK are demonstrated by the report from the recent Road-mapping exercise in III-V semiconductors (2012). III-nitride LEDs were ranked as one of the highest priorities, with direct impact on 4 of the top 10 technologies. The proposed devices will also have significant impact on high data rate devices for telecoms, which came out top in the applications vs technology matrix. This research on III-nitrides will contribute to the development of a sustainable, energy-consumption-efficient world with very healthy and secure communication systems over the next 10-50 years.

Both applicants have strong track records in collaboration with the semiconductor optoelectronics industry. Seren Photonics Ltd, the industrial partner of the project, was established on Professor Wang's research innovations. Both have established extensive formal and informal collaborations with the semiconductor industry in the UK and overseas, including IQE (Cardiff), Enfis (Swansea), Forge Europa Ltd (Cumbria), Zeta-control (Oxford), and Plessey semiconductor (Swindon/Plymouth), Osram (Germany), OptoGaN (Russian), etc. Exploitation opportunities of any Sheffield-IP generated will be carried out by the University's Research and Innovation Services (RIS), and commercialisation will be assisted by Fusion IP, an AIM-listed public company which has signed a longer term agreement with the University on commercialising university research.

Professor Martin has worked closely with the semiconductor industry, and has a number of patents in III-nitride technologies. He has recently competed industrial projects with SemiMetrics Ltd. and McCann Energy Ltd.. In addition to the valuable input from Strathclyde's Research Office the Physics Department is host to the KT Directorate of the Scottish Universities Physics Alliance (SUPA-KT) which provides excellent help in identifying commercial partners and opportunities. He is a lead partner in the Intelligent Lighting Centre within Strathclyde's £100 M Technology and Innovation Centre (TIC), where new laboratories for this work will be completed in early 2014, bringing together high numbers of academic and industrial researchers across a wide range of disciplines. A number of TIC partners offer high potential for engagement with the work in this project, for example, the Fraunhofer Centre for Applied Photonics.

Publications

10 25 50
 
Description 1. Develop a cost-effective epitaxial overgrowth method for semipolar GaN, leading to achieving high performance long-wavelength visible emitters with ultra fast response for both next generation solid state lighting and visible light communications
2. Develop a novel fabrication method to achieving hybrid organic/III-nitride emitters with ultra fast response and strong polarisation for next generation backlighting and solid state lighting
3. Understand the mechanism of defect reduction in overgrowing semipolar GaN on large lattice-mismatched substrates
4. Understand the mechanism of non-radiative energy transfer between inorganic and organic semiconductors
5. Demonstration of optically pumped white laser diodes with a record low threshold and ultra fast response
6. Demonstration of the first polarized white LED
7. We demonstrated the first electrical injection hybrid white LEDs with ultra-fast response for visible light communication
Exploitation Route The epitaxial growth method can be used in a wide range of areas, in particular, semiconductor industry and academy via a spin out company, and further large and disciplinary collaboration. The technologies developed through the project have been highlighted at Industrial event organized by Professor Tao Wang, on 10 January 2017, Sheffield, attracting more than 10 semiconductor companies across the UK, where the CEOs or technical directors attended. This findings have been highlighted by a number of semiconductor magazines and media world wide, such as
1)http://www.semiconductor-today.com/news_items/2016/jan/sheffield_200116.shtml
2)http://en.ofweek.com/news/LED-grown-on-semi-polar-GaN-emits-green-and-yellow-colors-39102
3)http://www.ednasia.com/ART_8800526735_1000005_NT_64e3b813.HTM
4)http://smart2zero.com/en/leds-grown-on-semi-polar-ingan-emit-green-and-amber-colors.html?cmp_id=7?ws_id=10006580#.Vscq2uaKTsA
The results on fast white light from hybrid III-nitride/organic LEDs for Li-Fi from the Sheffield team have published in ACS photonics (http://pubs.acs.org/doi/abs/10.1021/acsphotonics.7b01291). This technological breakthrough was then immediately highlighted on 1st December 2017 by eeNews Europe, one of the popular science and technology media (for details, please refer to http://www.eenewseurope.com/news/researchers-design-fast-white-light-hybridized-inorganicorganic-led
Sectors Digital/Communication/Information Technologies (including Software),Electronics,Energy,Environment,Healthcare,Manufacturing, including Industrial Biotechology

 
Description Part of the technologies have been transferred to a spinout company, Seren Photonic Ltd. Seren has been awarded 2015 Royal Society Emerging Technology Award due to a major technological breakthrough in developing a cost effective method for semipolar GaN overgrowth. Part of the results have contributed to Seren Photonics Ltd's latest funds-raise and a few grant applications. The results on developing the 1st electrical injection hybrid white LEDs for both general illumination and wireless communication has been immediately highlighted on 1st December 2017 by eeNews Europe, one of the popular science and technology media (for details, please refer to http://www.eenewseurope.com/news/researchers-design-fast-white-light-hybridized-inorganicorganic-led. Hopefully, it will draw attention from industry soon. Part of the technologies and the results developed via the project stimulated a new idea for an early-career academic staff member, who submitted his first grant application. Furthermore, part of the technologies and the results developed via the project stimulated a new idea, leading to a new IP which was filed in October 2018. This patented technology will potentially leads to a setup of a new spin-out, which is under preparation.
First Year Of Impact 2012
Sector Digital/Communication/Information Technologies (including Software),Electronics,Energy,Environment,Manufacturing, including Industrial Biotechology
Impact Types Economic

 
Title LED arrays 
Description A new method for the growth of micro-LED arrays 
IP Reference GB1816455.8 
Protection Patent application published
Year Protection Granted 2018
Licensed Commercial In Confidence
Impact Major impact on developing III-nitride based microLEDs for micro-display, Ultra-fast visible light communications, AR/VR
 
Description 2019 Industrial open day 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact It aims to establish new collaboration with industry and further strengthen existing collaboration with industry, and to support the UK advanced manufacturing.
Year(s) Of Engagement Activity 2019
 
Description BJ: 2019 UKNC Conference, Glasgow, UK, 9-10th January 2019 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Postgraduate students
Results and Impact Present the latest results on developing Nonpolar a-plane (11-20) InGaN-based light-emitting diodes grown on micro-rod templates
Year(s) Of Engagement Activity 2019
 
Description JB: UKNC Annual Conference 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Poster presentation outlined the latest progress that we have achieved. This results generates a new direction for using GaN semipolar opto-electronics. It is expected to draw strong attention from industry and academic areas
Year(s) Of Engagement Activity 2017
 
Description LJ: 2019 UKNC Conference, Glasgow, UK, 9-10th January 2019 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Postgraduate students
Results and Impact present latest report on developing Monolithic multiple colour emission from InGaN grown on patterned non-polar GaN
Year(s) Of Engagement Activity 2019
 
Description NP: 12th international conference on nitride semiconductors 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact The presentation report on design and then fabrication of single chip white LEDs. The results provided a new direction to move forward developing a new prototype white LED. It is expected to draw strong attention from industry.
Year(s) Of Engagement Activity 2017
 
Description NP: UKNC Annual Conference 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact The presentation reported our new progress on developing a single chip with multiple colors for a white LEDs using our semi-polar GaN templates. This represents a new advantages of employing semi-polar GaN for the fabrication of a single chip devices with multiple colors for ultra-fast Li-Fi applications.
Year(s) Of Engagement Activity 2017
 
Description TW: 2017 industrial event/open day 
Form Of Engagement Activity A formal working group, expert panel or dialogue
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact The event has attracted more than 10 CEOs from the UK industrial companies. All the new technological breakthroughs developed through the projects have been presented. It is expected that it will make major impact on industry.
Year(s) Of Engagement Activity 2017
 
Description XY: 2019 UKNC Conference, Glasgow, UK, 9-10th January 2019 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Postgraduate students
Results and Impact Present latest report on developing semi-polar (11-22) GaN for green emitters on Si substrates
Year(s) Of Engagement Activity 2019
 
Description YPG: 2018 UKNC winter Conference 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact The presentations reported a new prototype of white LEDs using our patterned non-polar GaN. It is expected that this type of white LEDs will draw attention from both industry and academia.
Year(s) Of Engagement Activity 2018
 
Description YZ: 12th international conference on nitride semiconductors 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact The presentation reported on our new progress on developing semipolar GaN on patterned substrates. This approach is generic, and can be used for a wide range of applications including LEDs and LDs and also nanodevices such as nanolasers. It is expected to draw strong attention from industry.
Year(s) Of Engagement Activity 2017