Single Molecule Plasmoelectronics
Lead Research Organisation:
Durham University
Department Name: Chemistry
Abstract
Continuing miniaturization of electronic components in computer chips will eventually lead to component sizes on the molecular scale. Conventional semiconductor nanostructures at these length scales will suffer from increased leakage currents due to tunnelling as well as increased thermal effects due to higher power densities. The need for developing alternative approaches has created over the last two decades the field of molecular electronics, in which electronic components are realized using single molecules. Numerous examples of prototypical devices such as diodes, memory elements and transistors employing individual molecules have been demonstrated.
One of the most important functions is the control of the current through a device with an external stimulus, i.e. gating. Stimuli which have been employed include electrostatic and electrochemical potentials, temperature, and light. Light is one of the most attractive options since it potentially allows coupling single-molecular devices with future optoelectronic circuitry, holding the promise of ultimate speed and miniaturization.
Efficient coupling of light with nanoscale objects can be achieved using plasmonic nanostructures that concentrate and focus light beyond the diffraction limit. In combination with electronic devices one speaks of plasmoelectronics. Such efficient and spatially confined coupling is a pre-requisite for the tight integration of optically gate-able molecular devices on the sub-100 nm scale. The proposed research aims at realizing single-molecular plasmoelectronic devices in which the current through a single molecule coupled to a plasmonic nanostructure is gated by external illumination. The envisaged device structures will take advantage of the plasmonic properties of noble metal nanoparticles that serve as the electrodes of the single-molecule junction. This research will open new opportunities for miniaturization, integration, and control of optoelectronic devices to the single-molecule level.
The research is interdisciplinary spanning physics, chemistry, molecular electronics and plasmonics. This is reflected in the research team which brings together expertise in organic synthesis of single-molecular conductors (Beeby, Durham), single-molecule conduction measurements (Nichols, Higgins, Liverpool), and nanoplasmonics (Jaeckel, Liverpool). This broad expertise will allow for a systematic approach varying the chemical nature of the molecular conductor and matching it with the plasmonic properties of the single-molecule junction. This will allow detailed characterization of parameters such as spectral overlap and electronic coupling in the junction and their relation to the optical gating effect in the device. The single-molecule approach will eliminate both ensemble averaging effects which can mask important effects in macroscopic measurements and sample heterogeneity which makes interpretation of results more complex. The project will deliver a fundamental understanding of plasmoelectronic single-molecule junctions and formulate design rules for future devices. The results will also open new opportunities in related research areas such photovoltaics, organic electronics, and catalysis.
One of the most important functions is the control of the current through a device with an external stimulus, i.e. gating. Stimuli which have been employed include electrostatic and electrochemical potentials, temperature, and light. Light is one of the most attractive options since it potentially allows coupling single-molecular devices with future optoelectronic circuitry, holding the promise of ultimate speed and miniaturization.
Efficient coupling of light with nanoscale objects can be achieved using plasmonic nanostructures that concentrate and focus light beyond the diffraction limit. In combination with electronic devices one speaks of plasmoelectronics. Such efficient and spatially confined coupling is a pre-requisite for the tight integration of optically gate-able molecular devices on the sub-100 nm scale. The proposed research aims at realizing single-molecular plasmoelectronic devices in which the current through a single molecule coupled to a plasmonic nanostructure is gated by external illumination. The envisaged device structures will take advantage of the plasmonic properties of noble metal nanoparticles that serve as the electrodes of the single-molecule junction. This research will open new opportunities for miniaturization, integration, and control of optoelectronic devices to the single-molecule level.
The research is interdisciplinary spanning physics, chemistry, molecular electronics and plasmonics. This is reflected in the research team which brings together expertise in organic synthesis of single-molecular conductors (Beeby, Durham), single-molecule conduction measurements (Nichols, Higgins, Liverpool), and nanoplasmonics (Jaeckel, Liverpool). This broad expertise will allow for a systematic approach varying the chemical nature of the molecular conductor and matching it with the plasmonic properties of the single-molecule junction. This will allow detailed characterization of parameters such as spectral overlap and electronic coupling in the junction and their relation to the optical gating effect in the device. The single-molecule approach will eliminate both ensemble averaging effects which can mask important effects in macroscopic measurements and sample heterogeneity which makes interpretation of results more complex. The project will deliver a fundamental understanding of plasmoelectronic single-molecule junctions and formulate design rules for future devices. The results will also open new opportunities in related research areas such photovoltaics, organic electronics, and catalysis.
People |
ORCID iD |
Andrew Beeby (Principal Investigator) |
Publications

Davidson R
(2017)
Exploring the Chemistry and Photophysics of Substituted Picolinates Positional Isomers in Iridium(III) Bisphenylpyridine Complexes
in Organometallics

Davidson R
(2018)
Emission Tuning of Ir(N ? C) 2 (pic)-Based Complexes via Torsional Twisting of Picolinate Substituents
in Organometallics

Davidson R
(2018)
Highly Linearized Twisted Iridium(III) Complexes.
in Inorganic chemistry

Davidson R
(2016)
The use of organolithium reagents for the synthesis of 4-aryl-2-phenylpyridines and their corresponding iridium(iii) complexes.
in Dalton transactions (Cambridge, England : 2003)

Davidson RJ
(2018)
Conductance of 'bare-bones' tripodal molecular wires.
in RSC advances

Herrer L
(2019)
Electrically transmissive alkyne-anchored monolayers on gold.
in Nanoscale

Liang J
(2016)
Electrochemically grafted single molecule junctions exploiting a chemical protection strategy
in Electrochimica Acta

Markin A
(2020)
Conductance Behavior of Tetraphenyl-Aza-BODIPYs
in The Journal of Physical Chemistry C

Planje IJ
(2021)
Selective Anchoring Groups for Molecular Electronic Junctions with ITO Electrodes.
in ACS sensors

Zhang W
(2016)
Single-Molecule Conductance of Viologen-Cucurbit[8]uril Host-Guest Complexes.
in ACS nano
Description | We have created a series of materials for evaluation as single molecule conductors, including multi-podal molecules. These have been investigated by our collaborators and their single-molecule conductance measured. Interestingly a study of a series of tripodal molecules show a systematic structure-conductance trend allowing in depth understanding of the conductance mechanism. The program is has now come to an end although some tests and measurements investigating materials and thier plasmonic effects are still ongoing at Liverpool. |
Exploitation Route | The work is creating important insights into the phenomenon of molecular wires. Our outputs are being used by and cited by workers in the field. |
Sectors | Electronics,Other |