Solar Powered Thermochemical Energy Storage

Lead Research Organisation: University of Nottingham
Department Name: Faculty of Engineering

Abstract

As considerable energy is consumed by UK buildings, not surprisingly, the Government targets for reducing carbon emissions require an 80% energy reduction in this area by 2050. Thermochemical (i.e. water sorption-based) heat storage (THS) can play a pivotal role in synchronizing energy demand and supply in buildings. Transformation of the existing British building stock towards net zero energy buildings requires effective integration and full use of the potential yield of renewable energy. Thermal storage is a key priority to make such a step, particularly for the energy renovation of the existing stock, where compact building level solutions are required. Thermal energy storage can be accomplished using sensible heat storage (SHS), latent heat storage (LHS) or THS. Over these methods THS has approximately 6-10 times higher storage density than SHS, and two times higher than LHS materials when compared on a like for like storage volume basis. In THS, thermochemical energy can be stored independent of the time without any heat loss, permitting solar energy storage during the summer to meet heating demand in winter. Achieving this by other heat storage methods is both complex and expensive. The proposed project will deliver an advanced solar powered THS system, which has stable long term performance in multi-cyclic seasonal use of at least 20 years. The system will contain environmental friendly and safe materials and will be compact, enabling installation in the limited space available in the existing housing stock and as well in the new buildings. Although seasonal storage of solar energy is intended within the proposed project (e.g. V=3-4 m3), it is also possible to design it as short term storage (3-4 days) only with resizing the THS reactor (e.g. V=0.1-0.2 m3). The proposed thermal storage system will lead to significant energy savings (greater than 50%) and CO2 emissions reduction, with a maximum payback of 5 years compared to the current state-of-the-art.

The project integrates multiple units of THS with solar air collectors to optimise the performance of these technologies providing seasonal heat storage in both the new and existing UK buildings that has: (a) low cost; (b) higher performance; (c) higher availability; (d) higher durability; (e) improved on-site health and safety; (f) efficient sorption and desorption processes (g) high solar contribution and (f) implementation of the computer design tools. The target is the development of an innovative, highly efficient thermochemical energy storage system with the following technical advantages:
* The theory and methodology of the THS reactor incorporating multiple sorption beds with hollow fibre membranes in a unique design that increases efficiency and reliability, thereby improving the current technologies and increasing system energy performance. Fundamental heat/mass transfer formulation and model for membrane fibre/reactor system.
* Theory and methodology for the novel evaporative humidifier integrated with heat pipe model for utilizing ground energy to ease evaporation of water and enhancing energy input to the system.
* Theory and methodology for the highly efficient solar air collectors to drive the system and achieve efficient sorption and desorption processes.
* The characterisation and adaptation of new and safety improved nano-composite sorbents, reducing barriers associated with new energy storage concepts.
* The theory and methodology for the advanced ICT optimized control, data/performance monitoring and energy management system

The project provides an opportunity for UK industries to pioneer the development of a new advanced energy storage technology. It will deliver a sustainable, environmental and cost-effective solution to significantly reduce energy consumption and CO2/GHG emissions. The project will contribute to UK excellence in terms of addressing fuel poverty and improving the quality of life for its citizens.

Planned Impact

The domestic sector in the UK currently accounts for about 30% of national energy consumption and around 25% of greenhouse gas (GHG) emissions, as a result of dependency on fossil fuels particularly for space and water heating. In centrally heated homes natural gas provides 85% of the heating load with only 8% coming from electricity (7% from others). In non-centrally heated homes 50% is provided by natrual gas and 40% by electricity. Solar thermal systems, one of the most established renewable energy technologies, could help reduce UK space heating associated GHG emissions. Solar thermal is already well establlished in the UK with more than 100k units installed to date but this is still significantly lower than in countries such as Germany, which has over 1 million units in operation. Seasonal THS systems, integrated to solar thermal systems have the potential for the UK to increase its utilisation of solar energy, with an increased scale of manufacture reducing the cost of such systems and enabling them to penetrate into more price sensitive markets.

Thermochemical heat storage (THS) is a progressive technology for storing thermal energy that can alleviate environmental influences and contribute to producing more efficient and cleaner energy systems. The proposed project aims to develop a cost-effective solar powered thermochemical heat storage (SPTHS) system having: low cost, high efficiency, ease of production and installation. The outcomes of the project will provide a good combination of energy efficiency, cost and environmental sustainability involving fossil fuel energy saving, carbon emission reduction, as well as pollutant (haze) control. It will also contribute to the growth in the nations' industrial economy, accessing the UK's building and energy technology market, thus creating more employment opportunities and improving its strategic role in UK economy. Meanwhile, it will also foster multi-disciplinary research which will raise the nations' standard in the global context. The proposed research matches well with the EPSRC's research portfolio of boosting energy efficiency and reducing energy demand in cities
(http://www.epsrc.ac.uk/research/ourportfolio/researchareas/energyefficiency/).

This project, focused on numerical modelling, laboratory testing of system components and field trial of the full scale SPTHS prototype, will bring about substantial benefits (impact) to the government, industries and end users in the UK. The Government will benefit from the increased economy, decreasing GHG emissions to prevent environmental pollution, as well as enhanced investment. Industries (especially those in the HVAC, construction and heat storage sectors) will contribute to improving market competitiveness, growing business opportunities and increased profits. The new technology will offer valuable teaching and learning education materials for undergraduate and postgraduate students. Moreover, researchers and postgraduate students will participate in the project by means of assessing, modelling and testing the developed prototype experimental unit at the laboratories of the Sustainable Research Building at the UNOTT.
 
Description As considerable energy is consumed by UK buildings, not surprisingly, the government targets for reducing carbon emissions require an 80% energy reduction in this area by 2050. Thermochemical Heat Storage (THS) can play a pivotal role in synchronizing energy demand and supply in buildings. Transformation of the existing British building stock towards net zero energy buildings requires effective integration and full use of the potential yield of renewable energy. Thermal storage is a key priority to make such a step, particularly for the energy renovation of the existing stock, where compact building level solutions are required. Thermal energy storage can be accomplished using sensible heat storage (SHS), latent heat storage (LHS) or THS. Over these methods THS has approximately 6-10 times higher storage density than SHS, and two times higher than LHS materials when compared on a like for like storage volume basis. In THS, thermochemical energy can be stored independent of the time without any heat loss, permitting solar energy storage during the summer to meet heating demand in winter. Achieving this by other heat storage methods is both complex and expensive. The current project developed an advanced solar powered THS system, which has stable long term performance in multi-cyclic seasonal use of at least 20 years. The developed system integrates multiple THS units with solar air collectors to optimise the performance of these technologies, providing seasonal heat storage in both the new and existing UK buildings. The system contained environmental friendly and safe materials and is compact, enabling installation in limited space available in the existing housing stock as well in the new buildings. Although seasonal storage of solar energy is intended within the current project (e.g. V=3-4 m3), it is also possible to design it as short term storage (3-4 days) only with resizing the THS reactor (e.g. V=0.1-0.2 m3). The developed thermal storage system will lead to significant energy savings (greater than 50%) and CO2 emissions reduction, with a maximum payback of 5 years compared to the current state-of-the-art. Literature review and patent search have concluded that the developed system is the first of its kind, integrated modular thermochemical energy storage/solar collector technology utilising novel composite sorbent materials and for space heating and hot water production in buildings. The use of new techniques for synthesis of novel sorbents with higher energy storage density, utilisation of cores, fibre membrane capillaries and mesh tubes for enhancement of heat/mass transfer in the reaction chamber are other innovative aspects of the project. The key findings of this project represent a significant advancement in energy storage.
Exploitation Route The project provides an opportunity for UK and European industries to pioneer the development of this new advanced energy storage technology. This will lead to a commercial product which strengthens competitiveness and growth of SMEs in the UK and Europe. The project offers new business, market and job opportunities across a wide range of manufacturing/energy/construction industries in the UK and worldwide. The growth in sales of renewable energy systems is expected to develop significantly in many areas due to the current concern on the energy demand reduction and environment issues. This offers access to growth markets for the uptake and implementation of the proposed technology, furthermore, the wider uptake of any developing technology will drive down price. The project will deliver a sustainable environmental and cost-effective solution to significantly reduce energy consumption and CO2 emissions. The project will contribute to UK excellence in terms of addressing fuel poverty and improving the quality of life of its citizens. It will strengthen the UK by building stronger collaboration between industry and academia with special complementary skills as well as training of young researchers.
Sectors Construction,Education,Energy,Environment,Manufacturing, including Industrial Biotechology

 
Description The project developed and investigated a novel solar powered seasonal THS system which has the potential to reduce the built environment fossil energy usage in space heating and hot water production, thus achieving the following impacts: (1) reducing fossil fuel energy use and CO2 emissions for heating in the UK, enabling energy affordability and security; (2) tackling the technological and socio-technical challenges remaining within the heat storage applications; (3) Increasing the solar share in domestic heating applications by utilising THS materials for seasonal storage and (4) helping the transition of the UK into a country with a considerable quantity of low carbon cities. The project outcomes and expertise generated are relevant to other areas, e.g. materials science, environmental studies and process development. Although the project was focused on thermal heat storage, the work carried out is also relevant to solar-driven air conditioning systems, heat pump and evaporative humidifier design, including aspects of both their modelling, design and construction. The outcomes of the project (e.g. theoretical models, experimental methods) will be beneficial for many researchers working in the field of thermal sciences. The project results have been disseminated through both international publications and presented at international conferences. These have facilitated knowledge exchange with external technical and academic audience and delivered wider impact in both technical and academic societies. The project has strong potential for future international collaboration as the technology is applicable in other countries. The project results will lead into new commercial IP/patent applications.
First Year Of Impact 2018
Sector Chemicals,Construction,Education,Energy,Environment,Manufacturing, including Industrial Biotechology
Impact Types Societal,Economic

 
Description Newton Fund, Institutional Links
Amount £96,751 (GBP)
Funding ID 216229499 
Organisation British Council 
Sector Charity/Non Profit
Country United Kingdom
Start 04/2016 
End 03/2018
 
Title Thermochemical energy storage composite SEM photos analysis 
Description Scanning Electron Microscopes (SEM) can be used to visualise the salt inside of the matrix of a SIM composite. The resolution produced is better than one nanometre. This can be used to make sure that the salt is binding uniformly inside the matrix and therefore maximising surface area and potential for mass and heat transfer. Material characterization allows the SIM samples to be compared for the best overall material in an open-loop system can be determined. The increase in porosity of samples after impregnation shows the potential of salt impregnation of host matrices in open cycle THS systems (from SEM photos). 
Type Of Material Data analysis technique 
Year Produced 2018 
Provided To Others? No  
Impact In the SEM analysis, salts can increase the porosity of vermiculite, then we mix three salts (MgSO4, LiNO3, MgCl2) which show very good performance, together to see if there is any better performance shown. Because of these characteristics, V-MgSO4-CaCl2 is the optimal material that can be selected. 
 
Title Thermochemical energy storage materials in SDT-Q600 TA-instrument analysis 
Description In the SDT-Q600 energy density analysis, water spray was supplied 2 hours before testing to make it become moisture with relative humidity at about 95%. 40-60mg samples were cut into very small pieces for energy density testing. For each sample, each material has been taken tests twice. 
Type Of Material Data analysis technique 
Year Produced 2018 
Provided To Others? No  
Impact According to the TA analysis (SDT-Q600 results analysis software) results for SDT-Q600 test, for the thermochemical heating storage materials, V-MgSO4-CaCl2 showed the highest energy density (1173.5 kJ/kg) and lowest regeneration temperature (63 °C). 
 
Title Thermochemical heat storage composites sorption test 
Description A sorption test is used to observe the mass of water a sample (TES composites) can adsorb in a set period under differing humidity. In the set-up below four cases are used to create four atmospheres, each with different relative humidity. These atmospheres are created using solutions of KNO3 (92%), MgSO4 (75%), MgCl2 (40%) and LiCl (17%) at the bottom of each case. However, before a sample can undergo sorption testing it must be made sure that is thoroughly dehydrated, as the SIMs tend to adsorb a certain level of moisture from the atmosphere. To do this it is placed in an oven at a temperature specific to the material (normally 200°C) for 24 hours since different materials require different temperatures to dehydrate fully. The temperature required for each sample is stated on the sample list above. 
Type Of Material Data analysis technique 
Year Produced 2017 
Provided To Others? No  
Impact The results show the minimum humidity for complete hydration of each salt in a time period that can be set as required. 
 
Description Seminar on Thermochemical Energy Storage, held at the University of Nottingham, UK 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Industry/Business
Results and Impact A workshop/seminar on Thermochemical Energy Storage systems was held in the UK, hosted by the British project partner 'University of Nottingham'. The seminar was attended by research teams from the University of Nottingham, UK and Istanbul Gedik University, Turkey. A series of presentations on the Solar-Store project works and results were held by presenters from both UK and Turkey, in addition to presentations delivered by other academic and industrial seminar participants. The seminar was targeted at businesses in the energy storage sector, and academic audience, students, as well as the general public, and has helped to showcase and disseminate the project outcomes, including progress made in the development of the novel Solar-Store energy storage system.
Year(s) Of Engagement Activity 2008
 
Description World Renewable Energy Congress Bahrain 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Other audiences
Results and Impact As the invited speaker for one of the conference sessions, a special Q&A session was held. A few questions were raised particularly by those who are interested in this field of research.
Year(s) Of Engagement Activity 2016