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Infrared time-domain quantum optics (In-tempo)

Lead Research Organisation: University of Glasgow
Department Name: School of Engineering

Abstract

Spectral analysis provides a vital technique to fingerprint the vast array of chemicals, materials and biological matter we encounter on a daily basis. It is central to detecting the presence of noxious gasses or explosives, of contaminants in food, and vitally the correct chemical structure of medicines.

This fellowship will deliver a new technology outperforming the state of the art infrared detection, based on recent developments in quantum mechanics.

Infrared spectroscopy is far from being a well-established technology, mostly due to the limited sensitivity standard detectors have in the infrared part of the spectrum. A limited sensitivity, in turn, corresponds to a limit in the minimum detectable amount of the chemical compound under scrutiny, hindering the deployment of infrared spectroscopy.

This fellowship will address such problem combining two recently developed techniques: time-domain spectroscopy and quantum metrology.

Time-domain spectroscopy is an approach developed in the last two decades and relies on measuring a signal that arises from the nonlinear interaction between ultrashort pulses and the infrared field under investigation. In contrast to standard infrared spectroscopy, the measured quantity is not at infrared wavelengths but in the visible region, where detectors have better performances. The detection is therefore not bound to the limited sensitivity of infrared sensors. This technique too is affected by a limit in the sensitivity, which arises from the quantised nature of the radiation in the ultrashort probing pulse and is known as the standard quantum limit.

In-tempo will transform infrared spectroscopy, harnessing quantum metrology to overcome the standard quantum limit faced by time-domain spectrometers.

Quantum optical metrology studies ways to improve the sensitivity of measurements using quantum states of light, instead of conventional fields. Squeezed and NOON states are the main players in this discipline. Squeezed states have a lower quantum noise on one of their properties, such as the amplitude, in exchange for a higher noise in a conjugate characteristic, such as the phase. NOON states are non-classical wave packets acquiring twice the phase of their classical counterparts when used in interferometers. Twin beams are electromagnetic fields featuring intensity correlations at the quantum level, i.e. more equal than any replica obtained by classical means.

This fellowship will use squeezed, NOON and twin beam states instead of classic ultrashort pulses in a time-domain spectroscopy approach. This way it will overcome the standard quantum limit in infrared spectroscopy.

The new family of infrared-time domain spectrometers generated by this fellowship will be benchmarked against state-of-the-art traditional spectrometers. Potential market impact and routes to commercialisation will be investigated with the support of the engaged industrial partners.

Planned Impact

This fellowship aims at making a landmark contribution to the application of quantum technologies, by addressing the rapidly expanding field of infrared spectroscopy.
Infrared spectroscopy enables applications such as gas, pollutants, explosives and chemical weapons detection, medical diagnostics, such as lactic acid and glucose screening, and forensic, and is expected to be valued at USD 1.26 Billion by 2022. The standard approach to infrared spectroscopy is based on Fourier-Transform Infrared spectrometers, used for material characterisation, contaminants detection, quality inspection and others, by a range of players spanning from large companies such as 3M and Boeing to Governments worldwide.
The proposed research will address this market, providing novel and enhanced tools for infrared spectroscopy, powered by recently developed quantum technologies.
Quantum technologies are transforming our world providing ultimate security to communications, enhanced imaging, and increased sensitivity to test the fundamental laws of nature. One day, they might also power computers enabling to solve problems that are currently out of our reach. This is the primary driver for the multi-million pounds' investments in quantum-related researches by China, Canada, US, EU, Japan and for the 270 million pounds the UK Government has devoted to quantum technologies research via the UK National Quantum Technologies Programme.
The technology proposed in this fellowship will have a transformative impact in the several areas dealing with security, quality monitoring and control.
-Knowledge. The fellowship will deliver new tools for enhanced detection in the infrared, which will have an impact on the study of fundamental aspects of light-matter interaction. Also, it will boost the development of quantum metrology.
-Economy. This fellowship aims at delivering demonstrators for a novel technology that will transform the current approach to infrared spectroscopy. The economic impact stems from the enabling capabilities of this technology such as detection of gasses or contaminant with higher sensitivity and distance resolution. The applicant aims at delivering the economic impact by engaging with the relevant industries and technology providers, such as Teraview, QMC, Optocap and the Fraunhofer in the UK, and other abroad (Zurich Instruments, Voxtel, TeTechS). The applicant is supported by Chromacity, Covesion and the QuantIC Quantum Hub in this challenge. The first two will provide the resources (lasers and crystals) that are required to build commercial demonstrators, as well as studies on the routes to commercialisation and economic impact. QuantIC will also advise on the best way to deliver economic impact and support with the identification of possible industrial partners. Once the supply-chain will be adequately established and the market investigated, a spin-out company dedicated to commercialising the proposed infrared spectrometer will also be considered. Such a product will have an impact on fields spanning the pharmaceutical, security, and research markets.
-People. This fellowship will provide training for the applicant, the research assistant and PhDs beyond scientific research. The ability to understand and build a business case, to successfully protect the IP and to license a technology will all be aspects of this training. Working in close collaboration with industrial partners will provide training to the applicant on the issues and possibilities offered by a University Spin-off, which could eventually be the solution to maximise the impact of the proposed research program.
-Society. Outreach and public engagement activities are also considered, with the aim of educating the public on basic concepts of quantum mechanics and the role they will play in the future technology. The support provided by the QuantIC Public Engagement and Communication Officer and the training requested will help to maximise the impact on society.
 
Description IN-TEMPO supported a large number of research outputs. The key findings are better divided into topics:
1) Integrated photonics. While trying to find a suitable integrated source for infrared quantum states of light, we have achieved high fundamental to second harmonic conversion efficiency in AlGaA-OI waveguides and optimised the dispersion for supercontinuum generation - reporting also large and controllable supercontinuum generation. This research line is still ongoing and is mainly performed in collaboration with Prof Sorel's group, at the University of Glasgow.

2) Time-varying media. Time-domain effects require a material with suitably fast and controllable changes in the properties, e.g., refractive index and conductivity. We have investigated transparent conductive oxides obtaining significant insights on the effects responsible for the time-dependent material properties. This line of investigation has proved very successful, also thanks to the collaboration with excellent scientists worldwide. We have now clarified what effects underpin the ultrafast and strong response of transparent conductive oxides at the wavelength where the real part of the material permittivity is close two zero. We have further investigated the temporal dynamics associated with such an enhanced material response and its impact on reshaping the radiation transmitted and reflected by the material

3) Terahertz science: We have further investigated time-dependent nonlinear effects involving both visible/near-infrared radiation and far-infrared (THz) waves. We have now, and for the first time, recorded a THz electric field transient in a pump-and-probe experiment where the probe is at the single-photon level. This was a great technical challenge and we believe the results will open the path to further investigation into quantum-enhanced infrared metrology

4) Infrared quantum optics. We have demonstrated entanglement in the 2um spectral region-the first demonstration of our ability to extend near-infrared technologies into the mid-infrared. More recently, we have proven that the degree of entanglement of our 2um source is sufficient to result in a positive secure key rate in a quantum key distribution setting. Further work will consolidate this new line of research, including entanglement delivery via hollow-core fibres at 2um.
Exploitation Route The publications associated with this award are highly cited and are shaping the landscape of research in the field. At this stage, this is the most direct metric of impact.
Sectors Aerospace

Defence and Marine

Digital/Communication/Information Technologies (including Software)

Other

URL http://www.mclerici.com
 
Description There are no updates from the preaviously submitted summary
First Year Of Impact 2019
Sector Education
Impact Types Cultural

 
Description A packaged source of multiplexed entangled photons
Amount £458,195 (GBP)
Funding ID 10031438 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 11/2022 
End 05/2024
 
Description Biotrack
Amount £157,350 (GBP)
Funding ID DSTLX-1000144632 
Organisation Defence Science & Technology Laboratory (DSTL) 
Sector Public
Country United Kingdom
Start 02/2020 
End 01/2024
 
Description Few-cycle pulses for air-plasma physics
Amount £19,972 (GBP)
Funding ID RGS\R1\201365 
Organisation The Royal Society 
Sector Charity/Non Profit
Country United Kingdom
Start 03/2020 
End 03/2022
 
Description High Quantum Efficiency Detectors
Amount £424,188 (GBP)
Funding ID 10001572 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 05/2021 
End 12/2022
 
Description Quantum-enhanced multiphoton fluorescence microscopy
Amount £234,672 (GBP)
Organisation Quantum Imaging 
Sector Private
Country United Kingdom
Start 03/2021 
End 08/2022
 
Title Adiabatic frequency shifting in epsilon near zero materials: The role of group velocity 
Description Data relevant to the publication, including all the published figures. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL http://researchdata.gla.ac.uk/id/eprint/954
 
Title An all-dielectric metasurface polarimeter 
Description The data in this set are organised into the following folders: Figure 2 folder: This contains the data plotted in Figure 2 (a) - (i) of the manuscript. The simulation data are provided in *.mat format and the experimental data is provided in *.asc format. This is the data for the experimental diffraction patterns and finite-difference time-domain (FDTD) simulations for the degenerate polarization states. Figure 3 folder: This contains the data plotted in Figure 3 (a) - (d) of the manuscript. The data is provided in Excel *.xlsx format. This is the data generated from using the intensity of the diffracted spots to extract the Stokes parameters and comparing with analytical Stokes' values. 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
Impact research 
URL http://researchdata.gla.ac.uk/id/eprint/1347
 
Title Broad frequency shift of parametric processes in epsilon-near-zero time-varying media 
Description Data relevant to the publication, including all the published figures. 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
URL http://researchdata.gla.ac.uk/id/eprint/937
 
Title Near-maximal two-photon entanglement for optical quantum communication at 2.1 µm 
Description data underpinning the publication 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
Impact research 
URL http://researchdata.gla.ac.uk/id/eprint/1205
 
Title Second Harmonic Generation in AlGaAs-On-Insulator Waveguides 
Description  
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Single-cycle THz-field electro-optical sampling with single-photon detectors 
Description Experimental data for paper submission 
Type Of Material Database/Collection of data 
Year Produced 2022 
Provided To Others? Yes  
Impact research 
URL http://researchdata.gla.ac.uk/id/eprint/1330
 
Title Supercontinuum generation in dispersion engineered AlGaAs-on-insulator waveguides 
Description data 
Type Of Material Database/Collection of data 
Year Produced 2020 
Provided To Others? Yes  
Impact research 
URL http://researchdata.gla.ac.uk/id/eprint/1105
 
Title Temporal Dynamics of Strongly Coupled Epsilon Near-Zero Systems 
Description data for the publication 
Type Of Material Database/Collection of data 
Year Produced 2021 
Provided To Others? Yes  
Impact research 
URL http://researchdata.gla.ac.uk/id/eprint/1198
 
Title Terahertz control of air lasing 
Description The dataset includes all the raw data that are analysed and presented in the related publication. 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
 
Title Two-photon Quantum Interference and Entanglement at 2.1 µm 
Description This data set contains the data related to the manuscript titled "Two-photon Quantum Interference and Entanglement at 2.1 µm" 
Type Of Material Database/Collection of data 
Year Produced 2019 
Provided To Others? Yes  
URL http://researchdata.gla.ac.uk/id/eprint/882
 
Title Ultra-broadband terahertz coherent detection via silicon nitride-based deep sub-wavelength metallic slit 
Description We present a novel class of CMOS-compatible devices aimed to operate the solid-state-biased coherent detection of ultrashort terahertz pulses, i.e. featuring gap-free bandwidth at least two decades-wide. Such a structure relies on 1-?m-wide slit aperture between two parallel aluminum pads and embedded in a 1-?m-thick layer of silicon nitride, deposited on a quartz substrate. We show that such a device can detect ultra-broadband terahertz pulses by employing unprecedented low optical probe energies of only a few tens of nanojoule, due to the more than one order of magnitude higher nonlinear coefficient of silicon nitride with respect to silica, which was employed in the previous generations. In addition, very high static electric fields can be generated within the slit by applying extremely low external bias voltages (in the order of few tens of volts), which strongly enhance the dynamic range of the detected THz waveforms. Finally, we show how this new device potentially enables to operate the solidstate- biased technique with a homodyne scheme, in a similar manner to electro-optic sampling. These results pave the way to the integration of the solid-state ultra-broadband detection in compact and miniaturized terahertz systems fed by high repetitionrate laser oscillators and low-noise, low-voltage generators. 
Type Of Material Database/Collection of data 
Year Produced 2018 
Provided To Others? Yes  
 
Description Collaboration Strathclyde Caspani 
Organisation University of Strathclyde
Country United Kingdom 
Sector Academic/University 
PI Contribution contribution to design and build of quantum fluorescence microscope
Collaborator Contribution Contribution to theory and experiments with quantum sources.
Impact S. Prabhakar, T. Shields, A. C. Dada, M. Ebrahim, G. G. Taylor, D. Morozov, K. Erotokritou, S. Miki, M. Yabuno, H. Terai, C. Gawith, M. Kues, L. Caspani, R. H. Hadfield and M. Clerici1, "Two-photon quantum interference and entanglement at 2.1 µm", Science Advances 6, eaay5195 (2020). J. B. Khurgin, M, Clerici, V. Bruno, L. Caspani, C. DeVault, J. Kim, A. Shaltout, A. Boltasseva, V. M. Shalaev, M. Ferrera, D. Faccio, and N. Kinsey, "Adiabatic frequency shifting in epsilon-near-zero materials: the role of group velocity", Optica 7, 226 (2020).
Start Year 2019
 
Description Collaboration with Hadfield 
Organisation University of Glasgow
Country United Kingdom 
Sector Academic/University 
PI Contribution We established a collaboration to expand quantum technologies in the infrared part of the spectrum. Our group will focus on the sources, measurements and data analysis.
Collaborator Contribution Hadfield's group will focus on superconducting detectors.
Impact S. Prabhakar, T. Shields, A. C. Dada, M. Ebrahim, G. G. Taylor, D. Morozov, K. Erotokritou, S. Miki, M. Yabuno, H. Terai, C. Gawith, M. Kues, L. Caspani, R. H. Hadfield and M. Clerici1, "Two-photon quantum interference and entanglement at 2.1 µm", Science Advances 6, eaay5195 (2020).
Start Year 2019
 
Description Collaboration with ORC 
Organisation University of Southampton
Department Optical Research Centre
Country United Kingdom 
Sector Academic/University 
PI Contribution Our team contributes with know-how on quantum optics, with entangled sources and single-photon detectors.
Collaborator Contribution The ORC team contributes with know-how on pulse propagation in fibres and with hollow-core fibres.
Impact not yet
Start Year 2021
 
Description Collaboration with Prof. Tie-Jun Wang 
Organisation Chinese Academy of Sciences
Country China 
Sector Public 
PI Contribution Prof. Tie-Jun Wang -National Academy of Science, Shanghai China (tiejunwang@siom.ac.cn)- visited my research group for two months. My research group provided know-how on quantum optics.
Collaborator Contribution Prof. Wang is epert on THZ time-domain processes and he contributed with his knowledge to the In-Tempo research.
Impact Output pending
Start Year 2019
 
Description Partnership with Bay Photonics, RedWave, and CPI 
Organisation Bay Photonics
Country United Kingdom 
Sector Private 
PI Contribution We have been working together to develop detectors suitable to measure continuous variable quantum states, as initiated by InTempo research. Our (academic) team designed the optoelectronic devices and the quantum sources and tested the former and the partner products.
Collaborator Contribution The parters built and tested a balanced detector for the measurement of quantum states of light. Funded by InnovateUK.
Impact Electro-Optical Sampling of Single-Cycle THz Fields with Single-Photon Detectors, Sensors 2022, 22(23), 9432; https://doi.org/10.3390/s22239432. A follow up from this collaboration is another InnovateUK grant (PADME).
Start Year 2021
 
Description Partnership with Bay Photonics, RedWave, and CPI 
Organisation Centre for Process Innovation (CPI)
Country United Kingdom 
Sector Private 
PI Contribution We have been working together to develop detectors suitable to measure continuous variable quantum states, as initiated by InTempo research. Our (academic) team designed the optoelectronic devices and the quantum sources and tested the former and the partner products.
Collaborator Contribution The parters built and tested a balanced detector for the measurement of quantum states of light. Funded by InnovateUK.
Impact Electro-Optical Sampling of Single-Cycle THz Fields with Single-Photon Detectors, Sensors 2022, 22(23), 9432; https://doi.org/10.3390/s22239432. A follow up from this collaboration is another InnovateUK grant (PADME).
Start Year 2021
 
Description Partnership with Bay Photonics, RedWave, and CPI 
Organisation RedWave Labs Ltd
Country United Kingdom 
Sector Private 
PI Contribution We have been working together to develop detectors suitable to measure continuous variable quantum states, as initiated by InTempo research. Our (academic) team designed the optoelectronic devices and the quantum sources and tested the former and the partner products.
Collaborator Contribution The parters built and tested a balanced detector for the measurement of quantum states of light. Funded by InnovateUK.
Impact Electro-Optical Sampling of Single-Cycle THz Fields with Single-Photon Detectors, Sensors 2022, 22(23), 9432; https://doi.org/10.3390/s22239432. A follow up from this collaboration is another InnovateUK grant (PADME).
Start Year 2021
 
Description Glasgow Quantum Summer School 2020 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact Presentation to schools of Quantum concepts
Year(s) Of Engagement Activity 2020
 
Description university of Glasgow quantum technology summer school 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach Regional
Primary Audience Schools
Results and Impact Nearly 80 pupils from secondary schools attended a summer school dedicated to presenting concepts of quantum optics from a physical and engineering perspective. The pupils were engaged in thematic workshops and experiments. The workshops stimulated discussion on the role and impact of quantum mechanics in current and future technologies.
Year(s) Of Engagement Activity 2018,2019