The Future is Remanufacturing: Composites for Life

Lead Research Organisation: UNIVERSITY OF EXETER
Department Name: Engineering

Abstract

Composites based on continuous fibre prepreg sheet laminates are a mature technology - widely used in the aviation industry for key structural components, However, the future horizon for composite development now lies in providing lightweight thick-section composite parts aimed at replacing metal components predominantly within the automotive sector. High thermal tolerance, thick section composites that are tough and durable could now offer a viable metal replacement technology for an expanding range of sub-chassis applications, particularly wheels, suspension, braking systems gear casings, rotor shrouds and components within the engine compartment.
Historically, monolith-type, thick-section parts have typically been made from aluminium or steel, and exceptionally with thermoset composites - but these have fundamental drawbacks when used for thick-section moulding. Thermoplastic discontinuous fibre tapes offer a tantalising alternative to traditional thermosets. Thermoplastic composites (TPC) based on e.g. PEEK and high-performance Nylons have the potential to offer a viable lightweight aluminium replacement option, with superior toughness and fatigue performance - both critical considerations for both automotive and aviation applications. The excellent formability and high flow characteristics mean parts can be produced quickly and cheaply with part counts into the 100,000's, making this class of composites uniquely suited to the volume demanded by the automotive industry, whilst also being capable of being used in thick section mouldings .
The recent development of Polyether ether ketone (PEEK) carbon fibre moulding compounds at Exeter showed that this material achieves a bulk modulus of ~40GPa when hot-pressed, which, whilst short of the ~70GPa offered by aluminium, is a marked improvement over previous offerings. Recent advances in manufacturing approach pioneered by the University of Exeter have seen the achievable modulus reliably pushed above 70GPa - directly on par with Aluminium, and, most excitingly, a technique by which controlled, localised orientation might be achieved through the use of pre-consolidated charges, exploiting the high viscosity of the material during manufacture. This technique could revolutionise the TPC sector, allowing the simple manufacture of thick-section components with the optimised design properties previously found only in multiaxial ATL processes. The new "pre-charges" route being proposed, will simplify manufacture, and remove the barriers to rapid volume production, similar to the advent of prepregs and SMC in the 1970's, that made possible the controlled, mass-manufacture of high performance composites in the aviation and automotive industries.

A base line improvement in properties together with the removal of manufacturing barriers, could change the current emphasis on thermosets to thermoplastics, which is highly important environmentally. Recycling of most types of thermosets is not commercially viable, despite extensive research into the area. Thermoplastic based systems have the potential to solve the recycling issue, with the ability to melt and re-press components without performance implications greatly improving the recyclability of the material - a characteristic that has long eluded thermoset CFRP's. Moreover, this trait lends itself exceptionally well to in-situ repair and damage healing. The viability of remanufacture and remoulding of composites needs to be established for all of the most common TPC's available. The study will both consider the remanufacture of components (closed loop recycling), and also the viability of 'shape change' with TPC's, i.e. the extent to which materials can be reprocessed like metals through re-melting and reforming multiple times. The future vision is for manufacturers to include recycling/remanufacture instructions as part of standard materials datasheets.

Planned Impact

1) The Industrial partners: All partners will benefit directly by keeping abreast of the latest research on this class of composites, and continued links with the University. Each partner also stands also to benefit directly: Victrex plc are the world leading producers of PEEK. PEEK TPCs are a particular focus for the project, where Victrex stand to gain if the market and usage of TPCs grow through increased sales. Heightened appreciation of potential benefits of TPCs could bring about a paradigm shift in the composites industry, via a move away from non-recyclable non-reusable thermosets in favour of the more sustainable option of TPCs. Royal Tencate Composites are leading makers of TP moulding compounds and TP - coated tapes and would similarly benefit from the increased market. Meggitt plc are Tier 1 - 2 suppliers, predominantly to the aviation industry. Their position relies on technical excellence, and the ability to offer world beating products that are lighter, perform better, and are more sustainable than rival offerings. Meggitt recognises the rising importance of TPCs in previously unthought-of applications, such as wheels. Composites-For-Life will only strengthen this position. Boeing and Leonardo Helicopters as airframe makers can see the advantages and are exploring TPCs as candidate materials for potential metal/thermoset replacement. The advantages of lower weight, improved toughness, improved fatigue life and a far reduced requirement for post manufacture processing (shot-blasting, peening, anti- corrosion coating, anodization, or painting), make TPCs attractive in themselves, and in addition, offer an answer to the sustainability and disposal issue. Another very important advantage is the ability to "heal" components, a facet of interest to their military customers offering the prospect of fast turn-round repair. The National Composites Centre (NCC) recognise the growing importance of TPCs to their member organisations and wish to offer capability in the area, as evidenced by their recent investment in TPC technology. It is critical for the NCC to stay abreast of the latest science in the area (see support letter), where the NCC will directly benefit in this regard as a project partner.
2) The wider industrial and scientific communities: The flow of publications, presentations and seminars planned (see NCC support letter), will heighten awareness and provide new knowledge concerning the manufacture and recyclability of TPCs, and also the extent to which re-moulding and healing is possible, supported by scientific data. This will allow informed decisions to be made regarding materials selection, and create a foundation of research for a new, sustainable, manufacturing route for TP moulding compounds. Currently, only a few specialist manufacturers can process DFMCs. It is hoped that this programme will open up the field by making the manufacture and processing information available to all, for the first time.
3) Society: Environmental benefits include lower density than aluminium and steel, meaning, when used in automotive and aviation, reduced through-life fuel consumption and reduced CO2. Lightweighting is also critical to electric vehicles, increasing range and economy. As important are the toughness and fatigue properties of TPCs, being far tougher than thermosets, - a major drawback of these materials. TPCs can also be used to mould thick-sections - difficult or impossible with thermosets. TPCs can therefore access previously unattainable application areas for composites, offering further weight savings. Fatigue life is a x10 higher than aluminium, where TPCs do not suffer corrosion, further adding to overall safety and potentially reducing inspection and maintenance schedules. TPCs do not need any post-mould surface treatment, whereas Aluminium parts post-forging are machined, cleaned, shot peened and then glass bead overpeened to inhibit fatigue cracks it is then anodised, and painted with an epoxy.

Publications

10 25 50
 
Description We have utilised very high speed photography to film the fracture process occurring several different classes of commonly used composites - this has help illuminate a previously little considered mechanisium driving failure, where composite failure is almost always a matrix- dominated phenomenon. This is at odds with much of the text book models - which take a fibre-based based fracture mechanics approach. We have also discovered a clear relationship between composite strength and area of new surfaces created during failure - This presents an exciting possibilities in offfering a more straightforward approach to the modelling of composite mechanical behaviour - a field currently fraught with difficulties necessitating mathematically complex approaches. Several long-standing pillars of fibre based composite theory can now be open to challenge as a result of these new findings.
Exploitation Route If a simpler approach to modelling composites could be realised in full, where models were more accessible, universal and accurate, the academic community and composites industry could then utilise this work to make much needed improvements to the accuracy and utility of modelling software and allow composite structural designers to build more weight efficient-stronger structures with confidence, and remove superfluous weight and material.
Sectors Aerospace

Defence and Marine

Construction

Education

Energy

Environment

Leisure Activities

including Sports

Recreation and Tourism

Manufacturing

including Industrial Biotechology

Transport

 
Description Tribol braking Ltd is a University spin-out company set up to commercialise the outcomes of this and other funding initiatives targeting the use of composite systems in braking systems and automotive (Wheels, calipers, brake discs and brake pads). The work has resulted in several patent applications with the 1st granted and the 2nd at PCT stage. There is also a third currently in draft. Tribol has entered into several technology access agreements with leading teir brake component manufacturers and 3 car makers.
First Year Of Impact 2022
Sector Transport
Impact Types Societal

Economic

 
Description ICURe - FullStop Braking - Cohort #39, Team 06
Amount £300,000 (GBP)
Funding ID 10036634 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 09/2022 
End 09/2024
 
Description EU Funding application partnership -PAEK-SKYLIGHT - A Thermoplastic wheel for the Electrical Environmental Control System 
Organisation Denroy Group Ltd
Department Denroy Plastics Ltd
Country United Kingdom 
Sector Private 
PI Contribution Exeter orchestrated a collaborative EU Funding to the "Clean Skys H2020 programme" entitled -PAEK-SKYLIGHT - A Thermoplastic wheel for the Electrical Environmental Control System. Exeter pulled together the consortium of collaborating companies which included Toray Advanced Composites, and The Thermoplastic Research Centre - both based in the Netherlands, Plus Denroy Plastics Ltd situated in NI. Exeter also was responsible for organising planning meetings and wrote and prepared the proposal on behalf of the consortium.
Collaborator Contribution Parters were: Toray Advanced Composites - supply of raw materials, expertise in composite material manufacture, and manufacture of bespoke grades of composite as required. The Thermoplastic Research Centre - Expert in injection over-moulding techniques, expertise in composite material - moulding compounds and PEEK based systems. Denroy Plastics Ltd - expertise in injection moulding, tool design and provision of route for the commercial exploitation of outcomes.
Impact Application successfully submittied to the EU "Clean Skys" H2020 programme
Start Year 2020
 
Description EU Funding application partnership -PAEK-SKYLIGHT - A Thermoplastic wheel for the Electrical Environmental Control System 
Organisation Tencate
Country Netherlands 
Sector Private 
PI Contribution Exeter orchestrated a collaborative EU Funding to the "Clean Skys H2020 programme" entitled -PAEK-SKYLIGHT - A Thermoplastic wheel for the Electrical Environmental Control System. Exeter pulled together the consortium of collaborating companies which included Toray Advanced Composites, and The Thermoplastic Research Centre - both based in the Netherlands, Plus Denroy Plastics Ltd situated in NI. Exeter also was responsible for organising planning meetings and wrote and prepared the proposal on behalf of the consortium.
Collaborator Contribution Parters were: Toray Advanced Composites - supply of raw materials, expertise in composite material manufacture, and manufacture of bespoke grades of composite as required. The Thermoplastic Research Centre - Expert in injection over-moulding techniques, expertise in composite material - moulding compounds and PEEK based systems. Denroy Plastics Ltd - expertise in injection moulding, tool design and provision of route for the commercial exploitation of outcomes.
Impact Application successfully submittied to the EU "Clean Skys" H2020 programme
Start Year 2020
 
Description EU Funding application partnership -PAEK-SKYLIGHT - A Thermoplastic wheel for the Electrical Environmental Control System 
Organisation University of Twente
Country Netherlands 
Sector Academic/University 
PI Contribution Exeter orchestrated a collaborative EU Funding to the "Clean Skys H2020 programme" entitled -PAEK-SKYLIGHT - A Thermoplastic wheel for the Electrical Environmental Control System. Exeter pulled together the consortium of collaborating companies which included Toray Advanced Composites, and The Thermoplastic Research Centre - both based in the Netherlands, Plus Denroy Plastics Ltd situated in NI. Exeter also was responsible for organising planning meetings and wrote and prepared the proposal on behalf of the consortium.
Collaborator Contribution Parters were: Toray Advanced Composites - supply of raw materials, expertise in composite material manufacture, and manufacture of bespoke grades of composite as required. The Thermoplastic Research Centre - Expert in injection over-moulding techniques, expertise in composite material - moulding compounds and PEEK based systems. Denroy Plastics Ltd - expertise in injection moulding, tool design and provision of route for the commercial exploitation of outcomes.
Impact Application successfully submittied to the EU "Clean Skys" H2020 programme
Start Year 2020
 
Title Brake pad unit 
Description A brake pad unit 100, for a disc brake assembly, comprises a backing plate 200 and a friction pad 300. Backing plate 200 comprises a first side 202 and a second side 204 having a length L, a width W, and an edge wall which defines a thickness T of the backing plate. The first side defines an engagement surface 208 for engaging with the disc brake assembly. The second side defines a friction material mounting surface 210. The backing plate is formed from a composite material 214 comprising reinforcement fibres 212, wherein fibres extend throughout of the composite material 214. The backing plate comprises a layer 240 (250, fig 13) of reinforcement fibres which are provided as continuous fibres which extend from a first point on the edge wall 206 to a second point on the edge wall. The friction pad comprises a friction material 302 provided on the friction material mounting surface 210 of the backing plate. The continuous fibres may extend in different directions. Reference is made to a method of manufacturing a brake pad unit. 
IP Reference GB2608451 
Protection Patent / Patent application
Year Protection Granted 2023
Licensed Yes
Impact Patent licenced to University of Exeter spin-out company Tribol Braking Ltd, who is in the process of building a business
 
Title Composite Brake pad backing plate 2nd patent textured features 
Description A method of manufacturing a backing plate for carrying a friction material to form a brake pad unit of a disc brake assembly, the method comprising the use of a specialised composite type structure and make-up that can deliver the required mechanical and thermal properties required. The patent application protect the material make-up of the plate, the physical featuring of the mating surfaces and the manufacturing route. 
IP Reference WO 2023/275550 
Protection Patent / Patent application
Year Protection Granted 2023
Licensed Commercial In Confidence
Impact The patent application if granted will be licenced to Tribol braking Ltd, a University of Exeter spin-out company .. seeking to commercialise the invention
 
Title composite baking plate for a friction lining 
Description composite baking plate for a friction lining in place of traditionally used steel back plates - This development is targeted at the emerging electric vehicle market where our plates hold several advantages: Almost all the world's brake pads across every sector of automotive currently uses mild steel as a backing plate. The plate provides structural support for the friction lining material ("pad"). The Pad is hot pressed directly onto the steel plate. The conventional method of getting the pad to adhere to the plate is to use either glue and/or through mechanical keying of the pad material to the steel plate via a series of "spigot" holes. These methods are limited however, where high-temperature operation can cause bond failure, degrade the glue bond or shrink off the pad, presenting safety-critical concerns. Tribol plates are a polymeric composite composed of a high thermal stability polymeric resin reinforced with fibres (e.g. glass or carbon). The design is unique in employing a "sandwich" structure. The outer layers are formed from high content fibre layers, whilst the middle is formed from mouldable mid-fibre length grades, where this combination not only provides the required thermal and mechanical properties but also significantly reduces the cost. Tribol plates can be used in the same way as steel plates, where pre-moulded plates can be made to any pattern required, and feed directly into existing production lines, with no requirement for re-tooling. In addition, Tribol plates can also be co-moulded together with the pad material in one operation, with little modification to the process. Tribol plates also incorporate a 3D mechanical fixing technology, which retains a bond between the pad to the plate, even when glue has been thermally destroyed. 
Type Of Technology New Material/Compound 
Year Produced 2022 
Impact On-going R&D collaborations with several car companys (Bentley Motors, Polestar, AMG Mercedes) and tier brake manufacturers, TMD Friction UK Ltd, and EBC Brakes Ltd. 
 
Company Name Tribol Braking 
Description Tribol Braking manufactures carbon fibre composite braking components for the aerospace and automotive industries. 
Year Established 2022 
Impact The company was started in October 2022, so still in the process of establishing a market for its products
Website https://www.tribolbraking.com/
 
Description Exhibited prototypes at the Autosport International 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Public/other audiences
Results and Impact Autosport international is an international automotive trade show event that attracts Automotive experts , leading innovators and the general public - with an interest in automotive innovation. It is a great opportunity to showcase latest innovations that pertain to the auto industry .. with usually large representation from teir suppliers and car makers. Tribol braking Ltd (our University spin-out company) displayed our innovative composite products and engaged with experts and the general public over the three-day event. The purpose was to gauge interest in our product lines, where we were able to get a sense of the interest level in our products from car enthusiasts and engage with industry leaders (tirer suppliers and manufactuers and carmakers).
Year(s) Of Engagement Activity 2023