Thermochemical energy storage using a closed cycle (ThermoStore)
Lead Research Organisation:
University of Nottingham
Department Name: Faculty of Engineering
Abstract
As part of its effort to commit essentially net zero carbon emissions by 2050, the UK Government announced a new plan in March 2019 to ban gas boilers in new houses after 2025. This is based on a fact that residential buildings accounted for about 25% of total UK greenhouse gas emissions in 2012, of which 55% were directly from gas, according to the Committee on Climate Change. The Committee advised direct emission reductions of 36% by 2025 and 53% by 2030 from 2007 levels in buildings. This has led to an imminent demand for replacement low or zero carbon heating technologies.
Solar thermal technology appears a primary option to meet this demand, but possesses a common drawback, that is the temporal mismatch between solar heat production and heating demand in buildings. Seasonal storage of solar heat is an essential way to address the mismatch between heating demand in winter and solar heat production in summer. Of the three main technologies available, energy density of thermochemical energy storage is superior to conventional sensible and latent heat storage by several-fold factor and has a further advantage of negligible storage heat loss.
The proposed project is aimed to investigate a new solar driven thermochemical energy storage system using several innovative designs such as closed air loop, pressure control, embedded internal heating/cooling, hollow polymer fibre heat exchanger, and integrated dehumidification/evaporative cooling. The proposed system has been devised to address several drawbacks experienced by typical thermochemical energy storage systems and will also use low temperature solar heat to enhance the heat release discharging process by humidifying air flow at a slightly higher temperature. The project is built on our recent research on the design and fabrication of composite salt-in-matrix as thermochemical energy storage materials.
Development of the proposed system has the potential of reducing fossil energy usage in space heating and hot water. Implementation of such technology would allow the UK to greatly increase its utilisation of solar energy and achieve the target of decarbonisation in heating. This project will demonstrate to domestic consumers, house builders, industry and local authorities the practicality of heating buildings by renewable energy without increasing costs. The project will also provide an opportunity for UK industries to pioneer the development of a new advanced solar heat storage technology.
Solar thermal technology appears a primary option to meet this demand, but possesses a common drawback, that is the temporal mismatch between solar heat production and heating demand in buildings. Seasonal storage of solar heat is an essential way to address the mismatch between heating demand in winter and solar heat production in summer. Of the three main technologies available, energy density of thermochemical energy storage is superior to conventional sensible and latent heat storage by several-fold factor and has a further advantage of negligible storage heat loss.
The proposed project is aimed to investigate a new solar driven thermochemical energy storage system using several innovative designs such as closed air loop, pressure control, embedded internal heating/cooling, hollow polymer fibre heat exchanger, and integrated dehumidification/evaporative cooling. The proposed system has been devised to address several drawbacks experienced by typical thermochemical energy storage systems and will also use low temperature solar heat to enhance the heat release discharging process by humidifying air flow at a slightly higher temperature. The project is built on our recent research on the design and fabrication of composite salt-in-matrix as thermochemical energy storage materials.
Development of the proposed system has the potential of reducing fossil energy usage in space heating and hot water. Implementation of such technology would allow the UK to greatly increase its utilisation of solar energy and achieve the target of decarbonisation in heating. This project will demonstrate to domestic consumers, house builders, industry and local authorities the practicality of heating buildings by renewable energy without increasing costs. The project will also provide an opportunity for UK industries to pioneer the development of a new advanced solar heat storage technology.
Planned Impact
The proposed project is likely to produce a beneficial impact to the nation, industries, society and customers. This is specifically described as below.
There needs a significant improvement in energy storage technologies during next decades to contribute to the Government target of net zero carbon emissions by 2050. The proposed project will develop a new-type solar driven thermochemical energy storage system by investigating use of several innovative designs, in order to address some drawbacks experienced by typical thermochemical energy storage systems. Seasonal storage of solar heat is an essential way to address the mismatch between heating demand in winter and solar heat production in summer. This has been identified worldwide a promising 100% renewable energy solution for space heating and hot water in buildings. The innovative outcome from this project will enhance UK scientific excellence in seasonal energy storage.
The project is expected to produce some exploitable outcomes and provide a scientific foundation for UK industries to pioneer advanced thermochemical energy storage technologies and hence promote their competitiveness in market. The supporting industrial partners will get a direct experience through different stages of project by providing a technical support at the same time, which can set a good background for a fast exploitation. Commercialisation of the proposed technology will create job opportunities and encourage "green" economic development in the UK through the manufacturing of the system components notably thermochemical reactors, solar collectors and heat exchangers. The follow-on development of other applications of the thermal storage will create very large worldwide markets for the UK.
The project will demonstrate to domestic consumers, house builders, industry and local authorities the potential for the proposed system in the reduction of their heating costs, and hence improving their living standard. The expected key features, i.e., low cost, high efficiency, low maintenance, ease of production, will stimulate the market uptake for the proposed system by offering a renewable energy heating solution the sustainable development of the UK economy. The project dissemination activities will also help more broadly in enhancing public awareness that energy savings and reduction in GHG emissions is possible if technologies are properly developed.
The project will have a technical support from 3 industrial collaborators (EPS Ltd., Solar Ready Ltd., SG Biodrying Ltd.). The collaboration will encourage knowledge transfer between academia and industry based on the development and demonstration of the proposed novel technology. The project partners have the necessary skills/resources to fully deliver the identified tasks. The academic Applicants will benefit in terms of improved research collaboration profile and exposure to the commercialisation atmosphere. The project will provide an opportunity for the companies to advance their manufacturing capability in supporting this state-of-the-art development, so the companies can be prepared well in exploring additional aspects of the concept and into other UK sustainable energy projects.
There needs a significant improvement in energy storage technologies during next decades to contribute to the Government target of net zero carbon emissions by 2050. The proposed project will develop a new-type solar driven thermochemical energy storage system by investigating use of several innovative designs, in order to address some drawbacks experienced by typical thermochemical energy storage systems. Seasonal storage of solar heat is an essential way to address the mismatch between heating demand in winter and solar heat production in summer. This has been identified worldwide a promising 100% renewable energy solution for space heating and hot water in buildings. The innovative outcome from this project will enhance UK scientific excellence in seasonal energy storage.
The project is expected to produce some exploitable outcomes and provide a scientific foundation for UK industries to pioneer advanced thermochemical energy storage technologies and hence promote their competitiveness in market. The supporting industrial partners will get a direct experience through different stages of project by providing a technical support at the same time, which can set a good background for a fast exploitation. Commercialisation of the proposed technology will create job opportunities and encourage "green" economic development in the UK through the manufacturing of the system components notably thermochemical reactors, solar collectors and heat exchangers. The follow-on development of other applications of the thermal storage will create very large worldwide markets for the UK.
The project will demonstrate to domestic consumers, house builders, industry and local authorities the potential for the proposed system in the reduction of their heating costs, and hence improving their living standard. The expected key features, i.e., low cost, high efficiency, low maintenance, ease of production, will stimulate the market uptake for the proposed system by offering a renewable energy heating solution the sustainable development of the UK economy. The project dissemination activities will also help more broadly in enhancing public awareness that energy savings and reduction in GHG emissions is possible if technologies are properly developed.
The project will have a technical support from 3 industrial collaborators (EPS Ltd., Solar Ready Ltd., SG Biodrying Ltd.). The collaboration will encourage knowledge transfer between academia and industry based on the development and demonstration of the proposed novel technology. The project partners have the necessary skills/resources to fully deliver the identified tasks. The academic Applicants will benefit in terms of improved research collaboration profile and exposure to the commercialisation atmosphere. The project will provide an opportunity for the companies to advance their manufacturing capability in supporting this state-of-the-art development, so the companies can be prepared well in exploring additional aspects of the concept and into other UK sustainable energy projects.
Publications
Zhang Y
(2024)
Exploring a novel tubular-type modular reactor for solar-driven thermochemical energy storage
in Renewable Energy
Zhang Y
(2022)
Investigation on a Vermiculite-Based Solar Thermochemical Heat Storage System for Building Applications
in Future Cities and Environment
Zhang Y
(2024)
Performance study of a thermochemical energy storage reactor embedded with a microchannel tube heat exchanger for water heating
in Journal of Energy Storage
Zhang Y
(2023)
Modelling analysis of a solar-driven thermochemical energy storage unit combined with heat recovery
in Renewable Energy
| Description | During the project duration, we investigated various host porous materials and salt hydrates in order to fabricate the property-enhanced composite salt-in-matrix thermochemical materials. We improved the conventional dry impregnation method by optimising different impregnation parameters. The synthesis methods include the conventional single impregnation method, multi-step impregnation technique, vacuum impregnation method, high-pressure impregnation method, and high-temperature concentration impregnation method. We employed several different techniques to characterise the composite samples' properties (e.g., structural characteristics, salt content, hydration and dehydration capacities, energy storage density, cyclic stability, and energy consumption during synthesis). Multi-step impregnation yielded vermiculite-CaCl2 composite with higher salt. Notably, the vermiculite-CaCl2 composite prepared by vacuum impregnation exhibited the highest energy storage density and better cyclic performance. We have also conducted numerical studies on the thermochemical energy storage (TCES) reactor, investigating the impacts of different design and operational parameters on the TCES system. We established COMSOL models of a tubular-type modular reactor which proved to reduce pressure drop and improve thermal efficiency. Previous research has shown that, in typical salt hydrate based open TCES systems, the hot exhaust air during the charging phase is not well-utilised but directly dissipated to the ambient. If this exhaust heat can be partly recovered to pre-heat the inlet ambient air, the performance of the TCES system can be enhanced. Therefore, we numerically investigated a solar PV/T-powered TES system integrating a heat exchanger to demonstrate the benefit resulting from this heat recovery scheme. Moreover, existing air-based open TCES systems face practical challenges in integrating with central water heating systems and controlling the supply temperature. To overcome these limitations, we investigated a water-based TCES system design, which integrates a water-to-air microchannel tube heat exchanger and an air-to-air heat recovery unit. A comprehensive evaluation was conducted numerically using a COMSOL model, including a comparative assessment for different TCES system configurations. For all numerical studies, experimental work has been also conducted to validate the numerical modelling and investigate the feasibility and energy storage performance of the proposed TCES system designs. Overall, most of the award objectives have been completed. We have successfully published six journal papers with the research findings of the ThermoStore project. |
| Exploitation Route | The project outcome is being explored via our participation in an ongoing Horizon Europe funded project "Efficient Compact Modular Thermal Energy Storage System" (https://echo-euproject.eu/), which will demonstrate the developed technologies in several European countries of different climatic conditions. |
| Sectors | Energy |
| Title | Raw data of reactor performance testing using vermiculite-based composite |
| Description | A small chamber was built for materials test/analysis. Composite (vermiculite with MgSO4 and CaCl2) was selected for the reactor performance test. Contains raw data of the air conditions at the inlet and outlet of the reactor. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2022 |
| Provided To Others? | No |
| Impact | This research dataset will be used for a journal paper publication on the thermochemical material characterisation for the ThermoStore project. |
| Title | SDT-Q600 raw data of vermiculite-based composite material characterisation |
| Description | TGA analysis raw data of vermiculite-based composite material characterisation using SDT-Q600 |
| Type Of Material | Database/Collection of data |
| Year Produced | 2022 |
| Provided To Others? | No |
| Impact | The dataset will be used for a journal paper publication on the thermochemical material investigations for the ThermoStore project. |
| Title | Scanning Electron Microscope (SEM) raw data of vermiculite-based composite materials |
| Description | Scanning Electron Microscope (SEM) photos for vermiculite-based composite materials to visualise the salt inside of the matrix of a composite. The resolution produced is better than one nanometre. This can be used to make sure that the salt is binding uniformly inside the matrix and therefore maximising surface area and potential for mass and heat transfer. |
| Type Of Material | Database/Collection of data |
| Year Produced | 2022 |
| Provided To Others? | No |
| Impact | This research dataset will be used for a journal paper publication on the thermochemical material characterisation for the ThermoStore project. |
| Description | Decarbonising Heating and Cooling Knowledge Share and Networking |
| Form Of Engagement Activity | A formal working group, expert panel or dialogue |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Professional Practitioners |
| Results and Impact | This network is a platform for knowledge exchange between those researchers of EPSRC funded projects in their Decarbonising Heating and Cooling programme. This event is recorded and available to the public, particularly practice professionals. |
| Year(s) Of Engagement Activity | 2021 |
| URL | https://net-zero-research.co.uk/heating-cooling-network/funded-projects/ |
| Description | Heat Pumps for Delivering Net Zero |
| Form Of Engagement Activity | Participation in an activity, workshop or similar |
| Part Of Official Scheme? | No |
| Geographic Reach | Regional |
| Primary Audience | Professional Practitioners |
| Results and Impact | A brief introduction on this event website (https://www.eventbrite.co.uk/e/heat-pumps-for-delivering-net-zero-tickets-203747543387#): "UK Government has set a target of 600,000 heat pump installations per year by 2028 (stated in Net Zero Strategy 2021). Heat pumps will play an important role in the reduction of carbon emissions from heating and will support the transition to net zero. This free webinar will provide an introduction to the technology, explore why heat pumps are important for a net-zero UK and provide examples of real-life installations. This online webinar is brought to you by the University of Nottingham's Energy Innovation and Collaboration team." |
| Year(s) Of Engagement Activity | 2021 |
| URL | https://www.eventbrite.co.uk/e/heat-pumps-for-delivering-net-zero-tickets-203747543387# |
| Description | Newsletter Article in World Society of Sustainable Energy Technology |
| Form Of Engagement Activity | A magazine, newsletter or online publication |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Media (as a channel to the public) |
| Results and Impact | A short article on the topic of the proposed ThermoStore concept was prepared and submitted to the newsletter of the World Society of Sustainable Energy Technology (WSSET). With nearly 2000 members, the WSSET newsletter provides a great opportunity to publicise new ideas, technologies, or products. |
| Year(s) Of Engagement Activity | 2022 |
| URL | https://www.wsset.org/news-events/newsletters |
| Description | Presented research in EPSRC NETWORK+ DECARBONISATION OF HEATING AND COOLING ANNUAL CONFERENCE |
| Form Of Engagement Activity | Participation in an activity, workshop or similar |
| Part Of Official Scheme? | No |
| Geographic Reach | National |
| Primary Audience | Professional Practitioners |
| Results and Impact | A presentation has been delivered on EPSRC NETWORK+ DECARBONISATION OF HEATING AND COOLING ANNUAL CONFERENCE, which was held in London, 19/20TH SEPTEMBER 2023. The two day event included more than 20 presentations on the Deconcrbiation of Heating and Cooling topic, with more than 40 attendees from various national institutions and companies. |
| Year(s) Of Engagement Activity | 2023 |
| Description | Presented research in an international conference- 19th International Conference on Sustainable Energy Technologies(SET22) |
| Form Of Engagement Activity | A talk or presentation |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Postgraduate students |
| Results and Impact | Two conference papers were submitted to the 19th International Conference on Sustainable Energy Technologies(SET22), which was held in Turkey from the 16th to the 18th of August 2022. Both oral and poster presentations were made, with a number of attendees from different nations and backgrounds. The audiences impressed with their interest in the research field. |
| Year(s) Of Engagement Activity | 2022 |
| URL | https://set2022.org/ |
| Description | Presented research in an international conference- 20th International Conference on Sustainable Energy Technologies(SET23) |
| Form Of Engagement Activity | A talk or presentation |
| Part Of Official Scheme? | No |
| Geographic Reach | International |
| Primary Audience | Professional Practitioners |
| Results and Impact | A conference paper was submitted to the 20th International Conference on Sustainable Energy Technologies(SET23), which was held in Nottingham from the 15th to the 17th of August 2023. Poster presentation was made, with a number of attendees from different nations and backgrounds. The audience was impressed with their interest in the research field. |
| Year(s) Of Engagement Activity | 2023 |
| URL | https://set2023.org/ |