Correlative Raman, SEM and EDX for operando electrochemistry research

Lead Research Organisation: University of Southampton
Department Name: Sch of Chemistry

Abstract

The expansion in the use of renewable energy resources is not only of paramount importance, it is also urgent. Fossil fuels are limited in supply and their use entails devastating environmental consequences such as atmospheric pollution and climate change. Fortunately, major advances have been achieved in the generation of energy from renewable resources including sun and wind, but unfortunately, the energy is not generated when and where it is needed. This issue could be easily solved with batteries to store the energy, but unfortunately, batteries do not last long enough and they are too expensive. Batteries are also too heavy and bulky, and this is particularly problematic for zero-emission electric vehicles. It is clear that developing better batteries is crucial for the future.
We propose to set up a new capability that will revolutionize the tools we have to understand and design better batteries. The new capability will enable the characterisation of the chemistry, elemental composition and structure/morphology of batteries and battery components on a scale far below the diameter of a human hair. This will be achieved with an integrated instrument that uses an intelligent positioning system to precisely spatially correlate the morphological characterisation (done with an electron microscope), the elemental composition (done with a special element-sensitive detector) and the chemical structure (done with a Raman microscope). By bringing together these three techniques we will greatly improve our understanding of the complex and spatially heterogeneous reactivity of real battery materials. This will generate unique insights at the forefront of research worldwide for the design of new strategies to build better batteries.
We will establish an inclusive and collaborative research community around this new capability, binging together researchers in industry and university, and fostering innovative approaches and new research projects and directions. The new capability will facilitating cooperation, team work and scientific discussions among researchers with different backgrounds and areas of expertise.

Publications

10 25 50
 
Description This grant has supported the acquisition of novel instrumentation that can be used to characterise the composition, structure and properties of materials and devices on the nanoscale by combining Raman mapping and elemental mapping with scanning electron microscopy imaging. The instrumentation is now fully installed and functioning. It is being used to advance research in a number of fields including electronic devices, medical diagnostics, catalysts, and batteries. In all of these areas the ability to identify and characterise the different components that make up the active device structure on the nanoscale provides crucial insight and guides future research.
Exploitation Route Through collaborative research to apply this instrumentation to new problems.
Sectors Aerospace

Defence and Marine

Chemicals

Digital/Communication/Information Technologies (including Software)

Electronics

Energy

Healthcare

Manufacturing

including Industrial Biotechology

Culture

Heritage

Museums and Collections

Pharmaceuticals and Medical Biotechnology

URL https://www.southampton.ac.uk/research/facilities/chemical-nanoanalysis-scanning-electron-microscope
 
Description The results of our work using this instrument have been reported through presentations and posters at a number of conferences and publications that make use of the instrumentation are not appearing. This has caused an increasing interest in the unique capabilities of the instrumentation and interest in its possible wides applications.
First Year Of Impact 2023
Sector Chemicals,Electronics,Energy
 
Description Roll-2-Roll (R2R) Manufacture Of Multilayer Solid-state Batteries
Amount £1,250,000 (GBP)
Funding ID EP/Y008278/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 02/2024 
End 01/2027
 
Description Electrochemistry Northwest 2022 meeting, Liverpool (UK), 14th July 2022 (plenary lecture) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact N. Garcia-Araez "Fundamental developments of next generation of batteries and lithium production methods" Electrochemistry Northwest 2022 meeting, Liverpool (UK), 14th July 2022 (plenary lecture)
Year(s) Of Engagement Activity 2022
 
Description Faraday Institution Conference 2020 (online event), 25-26 November 2020 (oral presentation) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Nuria Garcia-Araez, "Correlative SEM, EDX and Raman characterisation of batteries" Faraday Institution Conference 2020 (online event), 25-26 November 2020 (oral presentation).
Year(s) Of Engagement Activity 2022
 
Description ISE annual meeting 2023- talk by Nuria Garcia-Araez 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact An invited talk by Nuria Garcia-Araez titled 'Disentangling individual electrode's reactions and cross-talk effects in graphite/NMC cells with operando gas analysis measurements combined with advanced NMR characterization', given at the 74th Annual Meeting of the International Society of Electrochemistry, Lyon (France), 3-8 September 2023
Year(s) Of Engagement Activity 2023
URL https://annual74.ise-online.org/
 
Description QinetiQ Tech Talk, 16th August 2022 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach Local
Primary Audience Industry/Business
Results and Impact QinetiQ Tech Talk, 16th August 2022 "New materials and characterisation techniques for battery development"
Year(s) Of Engagement Activity 2022
 
Description Royal Microscopical Society 2022 SEMT meeting 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact Presetation on the new capabilities of the combined SEM and Raman instrument in electrochemistry
Year(s) Of Engagement Activity 2022
URL https://www.rms.org.uk/rms-event-calendar/semt-meeting-2022.html
 
Description Royce Battery Suite Opening & Symposium- talk by Nuria Garcia-Araez 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Professional Practitioners
Results and Impact An invited talk by Nuria Garcia-Araez titled 'Approaches towards safer batteries', given at the Royce Battery Suite Opening & Symposium, Cambridge, 31 October 2023
Year(s) Of Engagement Activity 2023
 
Description SPIE conference, Henry Royce Institute, Manchester 7-8th September 2022 (invited talk) 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Policymakers/politicians
Results and Impact Nuria Garcia-Araez "Fundamental developments of next generation of batteries and lithium production methods" SPIE conference, Henry Royce Institute, Manchester 7-8th September 2022 (invited talk)
Year(s) Of Engagement Activity 2022