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Advanced ceramics from liquid feedstock for aerospace propulsion

Lead Research Organisation: University of Nottingham
Department Name: Faculty of Engineering

Abstract

Ceramics are an important group of materials and their processing into aerospace coatings and components requires specialist techniques. Current methodologies for new materials discovery and development are wasteful, energy inefficient, and not representative of the production scale environment. This Early Career Fellowship in the priority area of Advanced Materials Engineering will demonstrate that new ceramic compositions can be processed from liquids with a high power, high efficiency and high velocity three cathode plasma source with axial injection as the primary technique. My vision is to establish modelling tools and advanced materials processing techniques that will enable the design and manufacture of advanced ceramic coatings and components with tailored microstructure with thermal, electrical and environmental barrier properties fine-tuned to their desired applications. This will enable unique microstructure of ceramic coatings coupled with fine-tuned thermal, environmental and electrical properties for thermal barrier coatings in the aero gas turbines, environmental barrier coatings for ceramic matrix composites in those turbines, electrolytes for fuel cells and solar cells in auxiliary power generation for electric aircraft, dielectric coatings for aero electric motors, wear and high temperature oxidation and corrosion resistant coatings for various critical components in the aero-engine. To facilitate widespread industrial uptake, I will develop a new high throughput process with reduced waste and improved sustainability based on high power, high velocity plasma, enabling the production of tailored ceramic coatings and components of the required nanostructure and microstructure of the required pore architecture in large volumes at a fraction of a cost of current techniques. This will enable the manufacture of coatings with bespoke compositions and provide unprecedented control of pore size, shape, fraction and distribution which are essential for thermal, environmental and electrical properties of these coatings. The integrated approach to materials discovery and manufacture will lead to creation of products for the aerospace industry with improved properties, performances and reduced materials processing times, in line with the aims of the fellowship priority area.

Publications

10 25 50

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Akisin C (2023) Microstructural Study of Cold-Sprayed CoCrFeNiMn High Entropy Alloy in Journal of Thermal Spray Technology

 
Description - We have developed a machine learning protocol to develop new thermal barrier coatings and environmental barrier coatings with low thermal conductivity and range of environmental barrier coatings which are suitable for CMAS resistance
- The work has led to a significant no of high entropy compositions, which are suitable for the next generation of coating materials.
- Active learning is being developed as a tool for parameter development of plasma spray process.
- Our high throughput materials discovery lab is now equipped with a cobot that is resulting in delivering new compositions for the coatings community.
Exploitation Route Directly developing new coatings at a fraction of time (compared to several decades) for the aerospace and power generation industry. It cuts the development cycle from several decades to a couple of years.
Sectors Aerospace

Defence and Marine

URL https://www.nottingham.ac.uk/coatings/
 
Description Our research is well aligned with the industry, and most of our work directly impacts industrial products. The knowledge of new composition, artificial intelligence, new processes and coatings developed from this EPSRC fellowship have resulted in engine testing of components at Rolls-Royce engine test bed under several different programmes. The coatings developed with the tools and techniques from this fellowship are leading the way to be incorporated into commercial products worth hundreds of millions in value. The work on machine learning leading to a software that is ready to be licensed by the thermal spray operators (a USD 16 billion industry) as well as the composition development framework is influencing how to use more abundant materials to keep the earth habitable. The work has contributed to working with NASA on the development of the next generation of space coatings. We are being invited to the table for manufacturing national strategy level meetings to help shape the manufacturing agenda and the output is contributing at an international level. In addition, a spin-out company is going through the pipeline of the university and another spin-out on the battery sector is working with us to commercialise the output.
First Year Of Impact 2023
Sector Aerospace, Defence and Marine,Energy,Environment,Manufacturing, including Industrial Biotechology,Transport
Impact Types Economic

Policy & public services

 
Description Interaction with Indian State's governor, chief minister and minister of trade
Geographic Reach Asia 
Policy Influence Type Influenced training of practitioners or researchers
Impact This leads to sustainable materials for the country and awareness of harmful emissions in the processing. We were also keen to explore utilising non rare earth materials and repair technologies to improve the performance of the materials.
URL https://www.indtsa.org/ntsc-2025
 
Description EPSRC Centre for Doctoral Training in Digital Transformation of Metals Industry
Amount £7,420,613 (GBP)
Funding ID EP/Y035461/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 05/2024 
End 09/2032
 
Description Hot Section Lifing and Materials ( HOTLINE )
Amount £11,871,092 (GBP)
Funding ID 10101878 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 02/2024 
End 01/2028
 
Description IGNITE Network+: Innovation and Growth Needs Inclusion and engagement of all Talent in Energy research
Amount £1,020,388 (GBP)
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 08/2022 
End 08/2026
 
Description REFURBISHMENT AND ADDITIVE MANUFACTURING ACCOMPLISHED BY KINETIC DEPOSITION (RE-MAKE)
Amount £260,676 (GBP)
Funding ID EP/Y036093/1 
Organisation Engineering and Physical Sciences Research Council (EPSRC) 
Sector Public
Country United Kingdom
Start 09/2023 
End 09/2027
 
Description REINSTATE: Repair, Enhanced Inspection, and Novel Sensing Techniques for increased Availability and reduced Through life Expense
Amount £10,442,163 (GBP)
Funding ID 51689 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 08/2020 
End 12/2024
 
Description REPLENISH: Repair and Evaluation of aerospace Products LinE side, Near wing, and In SHop
Amount £19,870,397 (GBP)
Funding ID 10112182 
Organisation Innovate UK 
Sector Public
Country United Kingdom
Start 05/2024 
End 12/2027
 
Description ARCI, Hyderabad 
Organisation International Advanced Research Centre for Powder Metallurgy and New Materials
Country India 
Sector Public 
PI Contribution Access to their state of the art - SAXS measurements - HVAF spray - Their proprietary cold spray - Nanoindentation mapping
Collaborator Contribution Provide access and technical input to unique spray and characterisation facility only available in India. Knowhow and technical expertise from Indian industrial experience.
Impact Samples and papers in progress
Start Year 2023
 
Description American University in Cairo 
Organisation American University in Cairo
Country Egypt 
Sector Academic/University 
PI Contribution We have provided processing route for carbon nanotube incorporated aluminium alloy powders using high pressure cold spray, developed coatings from them, examined using EIS and other complimentary techniques.
Collaborator Contribution They made carbon nanotube with aluminium alloy and perfected the method of incorporation. On top of that they have developed how to characterise all these in advanced electron microscopy.
Impact Three journal papers, relationship with working with Egypt on cutting edge technologies.
Start Year 2024
 
Description CSIR-IMMT 
Organisation Institute of Minerals and Materials Technology
Country India 
Sector Public 
PI Contribution Dr Sisir Mantry, a senior researcher, was hosted at the University of Nottingham for 6 months on a prestigious Raman Research Fellowship. We have helped develop new suspension and solution precursor thermal spray for thermal barrier coatings for their applications and
Collaborator Contribution The collaboration started on developing new thermal barrier coatings for the aviation industry. He brought over a range of suspensions, including 2D materials like Maxene and various other materials like a dental implant. They have examined and studied all the coatings and explored their processing-microstructure-properties relationships.
Impact Two journal papers on suspension thermal spray have been submitted for publications to two journals.
Start Year 2023
 
Title THERMAL SPRAY SYSTEM AND COATING 
Description A method do spray SiC from a precursor salt 
IP Reference EP4448186 
Protection Patent / Patent application
Year Protection Granted 2024
Licensed No
 
Title THERMAL SPRAY SYSTEM AND COATING 
Description A novel way to deposit SiC from suspension thermal spray 
IP Reference DJC125924P.GBA 
Protection Patent / Patent application
Year Protection Granted 2023
Licensed No
Impact A novel way to deposit SiC from suspension thermal spray
 
Title Machine learning tool to predict spray parameters 
Description The software can predict processing conditions based on the spray parameters 
Type Of Technology Software 
Year Produced 2025 
Impact The software was developed by two researchers and it will eventually lead to a licensing route for the university. 
 
Description 11th RIPT (Les Recontres Internationales de la Projection Thermique), 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Suspension Plasma Spray parameter development of EBC (Y1.5Yb0.5Si2O7) & SPS TBC (YSZ) to capture the latest output from the EPSRC funded work to help shape the narrative in the sector.
Year(s) Of Engagement Activity 2024
URL https://www.fz-juelich.de/en/imd/imd-2/news/news/11-ript-2024-conference
 
Description 2nd National Thermal Spray Conference 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Indian National Thermal Spray event received a welcome address from the President of India, Governor and Chief Minister of the state of Odisha and the industry minister for trade and industry opened the expo. The talk was a keynote talk to update the whole community on the direction of travel.
Year(s) Of Engagement Activity 2025
URL https://www.indtsa.org/ntsc-2025
 
Description 50th International Conference on Metallurgical Coatings and Thin Films (ICMCTF 2024), 
Form Of Engagement Activity A talk or presentation
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Invited talk on the Next generation of Compositions & Microstructure for Netzero & Sustainable aviation,
Year(s) Of Engagement Activity 2024
URL https://icmctf2024.avs.org/
 
Description Navigating a Greener Sky: Symposium on Advances in Thermal Spray and PVD Coatings for the Aerospace Industries 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Professional Practitioners
Results and Impact Navigating a Greener Sky: Symposium on Advances in Thermal Spray and PVD Coatings for the Aerospace Industries by ASM is an initiative to bring EU, UK, USA and Canadian researchers together. We delivered a keynote on Clearance coatings in lower emission aviation gas turbines :Ytterbium disilicate abradable coatings spraying and steam-CMAS performance.
Year(s) Of Engagement Activity 2023,2024
URL https://www.asminternational.org/tss-topical-event-france/
 
Description Outreach for school children 
Form Of Engagement Activity Participation in an open day or visit at my research institution
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Schools
Results and Impact A school group with 71 students came over to see the facilities. It was very well received by everyone involved.
Year(s) Of Engagement Activity 2023
 
Description TSSEA conference 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach International
Primary Audience Postgraduate students
Results and Impact Thermal Spray and Surface Engineering Conference
Year(s) Of Engagement Activity 2024
URL https://sustainability2024.tssea.org/