High-Performance Smart Ceramic Coatings on Light Alloys
Lead Research Organisation:
University of Manchester
Department Name: Materials
Abstract
The application of surface treatments is a common practice to maximize the working life of light alloys used in transport. However, traditional passive coatings only act as a physical barrier against the environment and, once damaged, no longer provide protection. From this limitation, the concept of smart coatings was born, which are defined as materials capable of interacting with the environment by responding selectively to certain triggers, such as mechanical fracture, time, temperature or pH variations. Depending on the incorporated functionality, different properties can be achieved, e.g. specific corrosion inhibition, self-healing or damage indication.
The development of smart coatings is primarily a domain of organic-based materials since the high chemical reactivity of polymers promotes the incorporation of new functionalities. However, the applicability of such materials is limited to mild environments and medium loads. The scientific question proposed in this project is whether providing smart functionalities is feasible in ceramic-based coatings that have excellent performance in extremely corrosive and abrasive environments. The active functionalisation of ceramic coatings is quite challenging given the rigid and inert nature of inorganic matrices compared to organic materials.
The scientific approach proposed in this project to achieve the active functionalisation of ceramic coatings to tackle corrosion damage, is based on the incorporation of pH-sensitive nanocontainers loaded with corrosion inhibitors. These are released into the media when detecting pH changes arisen from electrochemical activity associated with corrosion initiation. The corrosion inhibitors will act locally inhibiting corrosion propagation, while the ceramic matrix will provide wear and abrasion protection simultaneously. This project focuses on the active and dynamic behaviour of the materials rather than in the passive properties of the coatings.
Two deposition techniques are used to manufacture the ceramic coatings, namely Plasma Electrolytic Oxidation (PEO) and Aerosol Deposition (AD) method. PEO is an electrolytic surface modification technique that derives from anodising. The interest for this technique arises from the current need to replace carcinogenic electrolytes used in anodising restricted by the EU (REACH). PEO is environmentally friendly and the resulting coatings are considerably superior in terms of corrosion and wear resistance to those obtained by conventional electrolytic techniques. However, PEO requires a high-energy consumption and this limits its applicability to niche components with excellent performance. Therefore, in order expand the range of applicability and increase the potential industry impact of this research, a more cost-effective and readily available technique is also proposed: the AD method-an extremely versatile room temperature spray coating technology. The deposition principle employed in AD is based on the generation of an aerosol using submicron powder particles from the precursor, which are sprayed at high velocity towards the substrate. It results in coatings with excellent high temperature and abrasion-resistant properties.
To achieve the active functionalisation of the ceramic coatings, two manufacturing processes are proposed. The single-step process will prove more challenging, but on the other hand, it would save processing times leading to reduced economical costs. Moreover, the single-step process is expected to produce a uniform functionalisation throughout the entire thickness of the coating, which would improve the active protection properties. The double-step process requires longer times, but it is more accessible.
Successful results would increase the lifetime of Al and Mg-based components used in the transport industry that would have a direct impact on energy efficiency and would contribute to the sustainable consumption of resources.
The development of smart coatings is primarily a domain of organic-based materials since the high chemical reactivity of polymers promotes the incorporation of new functionalities. However, the applicability of such materials is limited to mild environments and medium loads. The scientific question proposed in this project is whether providing smart functionalities is feasible in ceramic-based coatings that have excellent performance in extremely corrosive and abrasive environments. The active functionalisation of ceramic coatings is quite challenging given the rigid and inert nature of inorganic matrices compared to organic materials.
The scientific approach proposed in this project to achieve the active functionalisation of ceramic coatings to tackle corrosion damage, is based on the incorporation of pH-sensitive nanocontainers loaded with corrosion inhibitors. These are released into the media when detecting pH changes arisen from electrochemical activity associated with corrosion initiation. The corrosion inhibitors will act locally inhibiting corrosion propagation, while the ceramic matrix will provide wear and abrasion protection simultaneously. This project focuses on the active and dynamic behaviour of the materials rather than in the passive properties of the coatings.
Two deposition techniques are used to manufacture the ceramic coatings, namely Plasma Electrolytic Oxidation (PEO) and Aerosol Deposition (AD) method. PEO is an electrolytic surface modification technique that derives from anodising. The interest for this technique arises from the current need to replace carcinogenic electrolytes used in anodising restricted by the EU (REACH). PEO is environmentally friendly and the resulting coatings are considerably superior in terms of corrosion and wear resistance to those obtained by conventional electrolytic techniques. However, PEO requires a high-energy consumption and this limits its applicability to niche components with excellent performance. Therefore, in order expand the range of applicability and increase the potential industry impact of this research, a more cost-effective and readily available technique is also proposed: the AD method-an extremely versatile room temperature spray coating technology. The deposition principle employed in AD is based on the generation of an aerosol using submicron powder particles from the precursor, which are sprayed at high velocity towards the substrate. It results in coatings with excellent high temperature and abrasion-resistant properties.
To achieve the active functionalisation of the ceramic coatings, two manufacturing processes are proposed. The single-step process will prove more challenging, but on the other hand, it would save processing times leading to reduced economical costs. Moreover, the single-step process is expected to produce a uniform functionalisation throughout the entire thickness of the coating, which would improve the active protection properties. The double-step process requires longer times, but it is more accessible.
Successful results would increase the lifetime of Al and Mg-based components used in the transport industry that would have a direct impact on energy efficiency and would contribute to the sustainable consumption of resources.
People |
ORCID iD |
Beatriz Mingo (Principal Investigator) |
Publications
Aliasghari S
(2023)
Abrasion resistance of a Nb3Sn magnetron-sputtered coating on copper substrates for radio frequency superconducting cavities
in Materials & Design
Guo Y
(2022)
Plasma electrolytic oxidation of magnesium by sawtooth pulse current
in Surface and Coatings Technology
Mingo B
(2022)
Magnesium Technology 2022
Mohedano M
(2021)
Effects of pre-anodizing and phosphates on energy consumption and corrosion performance of PEO coatings on AA6082
in Surface and Coatings Technology
Mohedano M
(2022)
Energy consumption, wear and corrosion of PEO coatings on preanodized Al alloy: the influence of current and frequency
in Journal of Materials Research and Technology
Pillado B
(2023)
LDH conversion films for active protection of AZ31 Mg alloy
in Journal of Magnesium and Alloys
Description | UK Talent Meeting |
Geographic Reach | National |
Policy Influence Type | Participation in a guidance/advisory committee |
Description | President's Doctoral Scholar Award |
Amount | £63,000 (GBP) |
Organisation | University of Manchester |
Sector | Academic/University |
Country | United Kingdom |
Start | 04/2023 |
End | 10/2026 |
Description | University of Manchester Interdisciplinary Research Grant |
Amount | £20,000 (GBP) |
Organisation | University of Manchester |
Sector | Academic/University |
Country | United Kingdom |
Start | 01/2022 |
End | 07/2023 |
Description | Collaboration with University of Aveiro |
Organisation | University of Aveiro |
Department | Aveiro Institute of Materials |
Country | Portugal |
Sector | Academic/University |
PI Contribution | This collaboration has led to two grant proposals which are still under review. - La Caixa Foundation Health research call - Dual action in trauma and bone disease: when smart biodegradability meets antibacterial action, 3 years (Total 791k EUR, 160k EUR for UoM). - Royal Society International exchanges - Multilevel strategies for corrosion control of magnesium-based biodegradable implants, 1 year (Total 6k GBP). The University of Manchester led the Royal Society international exchange application. If awarded researchers from both institutions will visit each other to learn complementary research techniques. |
Collaborator Contribution | The University of Aveiro led the La Caixa Foundation Health grant. They established the research consortium, wrote and submitted the proposal. |
Impact | This collaboration has resulted in two interdisciplinary grant applications. The topic of both grants is related to the development of smart surface treatments for temporal implants. Here we merged UoM's expertise in coating development and corrosion degradation with Aveiro's expertise in biomaterials and synthesis of nanocapsules for the smart release of antibiotics. |
Start Year | 2022 |
Description | Collaboration with the Department of Chemical Engineering, The University of Manchester |
Organisation | University of Manchester |
Country | United Kingdom |
Sector | Academic/University |
PI Contribution | This collaboration led to the award of the University of Manchester Interdisciplinary Research Institute grant which was written equally by both partners. The contribution of Dr Mingo's team to this collaboration was the synthesis of 2D nanoparticles to be used as fillers in polymeric based membranes for Electrochemical Energy Devices (EED). A member of Dr Mingo's group applied to an interdisciplinary hoping call funded by the University of Manchester (25k GBP) to spend 4 months at the collaborator's group to carry out a feasibility study. The proposal is still under review. |
Collaborator Contribution | The partner from the Chemical Engineering Department - Dr Perez-Page- was responsible for the development and testing of the membranes in Redox Flow Batteries. She was also responsible for writing and submitting an EPSRC grant which is still under review (Early career researcher international collaboration grant). |
Impact | The outputs of this collaboration are: - Award of the University of Manchester Interdisciplinary Research Institute grant, 20k GBP - Submission of EPSRC Early career researcher international collaboration grant, 200k GBP (under review) - Submission of the University of Manchester Research Institute Discipline Hopping Call, 25k GBP (under review) |
Start Year | 2021 |
Description | Corrosion Awareness Day Photo Competition |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Undergraduate students |
Results and Impact | Dr Mingo's research group organised a competition to raise awareness of corrosion across industries and society. The competition was open to students in the UK to submit corrosion images ranging from photography to technical research images. The prize was a one-year membership to IOM3 and a £100 Amazon voucher. The pictures were published on social media. The European Federation of Corrosion highlighted this activity on their website. |
Year(s) Of Engagement Activity | 2021,2022,2023 |
URL | https://www.linkedin.com/posts/beatriz-mingo-rom%C3%A1n-0698b69b_corrosionawarenessday-theuniversity... |
Description | International day of women and girls in science |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Schools |
Results and Impact | Dr Mingo (2021, 2022 and 2023) and Dr Aliasghari (2023) gave a talk at Colegio Berriz Secondary School (Spain) and discussed the importance of representation and diversity in science. We also discussed our research topics and the steps to follow to become a scientist. We also talk about the University of Manchester history, courses and entry requirements. |
Year(s) Of Engagement Activity | 2021,2022,2023 |
Description | Podcast Interview |
Form Of Engagement Activity | A broadcast e.g. TV/radio/film/podcast (other than news/press) |
Part Of Official Scheme? | No |
Geographic Reach | International |
Primary Audience | Media (as a channel to the public) |
Results and Impact | Dr Mingo was invited to the Research Beat, a science Podcast powered by Audemic, where she had the chance to share her latest progress in her research |
Year(s) Of Engagement Activity | 2022 |
URL | https://audemic.io/the-research-beat/ |
Description | Press release RAEng Award |
Form Of Engagement Activity | A press release, press conference or response to a media enquiry/interview |
Part Of Official Scheme? | No |
Geographic Reach | National |
Primary Audience | Public/other audiences |
Results and Impact | After the award press release several people contacted me to engage in new collaborations. |
Year(s) Of Engagement Activity | 2022 |
URL | https://www.royce.ac.uk/news/beatriz-mingo-named-amongst-royal-academy-of-engineerings-five-young-en... |
Description | School visit, Springfield Primary School |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Schools |
Results and Impact | Dr Mingo visited Springfield Primary school during British Science Week. She gave three talks to pupils in Year 1 (approximately 90 pupils). We talked about the different types of materials that we could spot around us and how we choose specific materials to make objects. It was a very interactive talk and the children had the chance to see and touch different materials (glass, wood, metals, plastics, etc). We also talked about the origin of materials (natural or man-made). At the end of the talk, we did an experiment to show how nappies work. The children had many questions about it. |
Year(s) Of Engagement Activity | 2023 |
Description | Women in Engineering Day - Seminar at the Henry Royce Institute |
Form Of Engagement Activity | A talk or presentation |
Part Of Official Scheme? | No |
Geographic Reach | Local |
Primary Audience | Postgraduate students |
Results and Impact | Dr Mingo gave a talk on the occasion of Women in Engineering Day at the Henry Royce Institute. There were around 20 attendees. She talked about her journey to a career in light alloys - challenge, opportunity and achievements (professionally and personally). After the talk, the discussion focused on the main challenges faced by researchers with caring responsibilities and the support available in the university for them. |
Year(s) Of Engagement Activity | 2022 |
Description | Women in STEM conference 2022 |
Form Of Engagement Activity | Participation in an activity, workshop or similar |
Part Of Official Scheme? | No |
Geographic Reach | Regional |
Primary Audience | Undergraduate students |
Results and Impact | The Women in STEM Conference was a 2-day event held at The University of Manchester, whose aim was to showcase successful and inspirational women working in STEM that could serve as role models for students considering their career options. It was aimed at undergraduates, graduates, and industry experts. We secured a speaker schedule with representation from leading tech companies, CEOs of medical enterprises, IP attorneys and academics. The event was a great success with 251 registrations for the main event. It also included a commercialisation workshop, a networking event, and an exhibition with industrial partners. Sponsorship was provided from bp-ICAM, Royce and EPSRC. |
Year(s) Of Engagement Activity | 2022 |
URL | https://www.eventbrite.co.uk/e/women-in-stem-tickets-388548909247?aff=ebdsoporgprofile |