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Engineered Diamond Technologies

Lead Research Organisation: University of Warwick
Department Name: Physics

Abstract

Increasingly conventional materials are not able to meet the performance levels required by new technologies. We need new materials with combinations of extraordinary properties that enable scientists and technologists to achieve the otherwise impossible. Diamond is one such super-material, which can be synthesized with ever-increasing control over the exploitable properties. The synthesis of diamond is currently an area where the UK leads the world. Examples of applications include exploitation of (i) ultra/isotopically pure diamond for quantum, photonic and electronic technologies including diamonds functionalised with ensembles of nitrogen-vacancy defects for magnetic imaging of living cells, magnetic navigation and solid-state masers; (ii) heavily boron-doped diamond for electrochemical sensing (in both hostile and biological environments) and water treatment; (iii) large diamond optical elements for next-generation lasers where diamond is an active intra-cavity element rather than just a window; (iv) polycrystalline diamond for acoustic and for thermal management applications ranging from power electronics to 5G communications.

Seizing the scientific and commercial opportunities of Diamond Science and Technology (DST) and staying ahead of stiff global competition, requires coordinated research at TRL 1-3, capture and protection of UK generated IP and researchers who can tackle multi-disciplinary challenges head-on. The proposed Prosperity Partnership would ensure that the UK's scientific and technological lead in DST is not eroded. The programme of research and collaboration is split into three work-packages (WPs). WP1 focusses on the synthesis, characterisation, and exploitation of perfect diamond in which the maximum exploitable properties are unleashed because deleterious impurities and defects which cause problematic strain are removed. Larger-area single crystal CVD diamond will be grown since diamond's immense potential is limited in many application areas by the small sizes currently available. Functionalised diamond will also be produced where the useful defects have been controllably introduced. WP2 concentrates on the development of processing, functionalisation, and integration technologies for diamond. Growing the diamond is not enough: we have to develop the tool kit that enables processing of diamond into the desired geometrical structure, integration with other materials and suitable packaging that in no way limits performance advantages. WP3 addresses the challenge of quality assurance such that end users know that the packaged material properties meet their requirements, and that the material can be reproducibly produced at a reasonable cost. Also, in WP3 we will produce proof of concept devices that show the potential and seed new product development. The project outcomes will include new materials with improved and tailored properties, new science enabled by enhanced intrinsic properties and the ability to manufacture innovative diamond devices. The significant impacts of the work will be in the new materials and processes demonstrated, increased confidence in others to exploit diamond because we have established a complete diamond supply chain (from production of the material to integration in devices, whilst still retaining the required properties) and the commercialisation of the breakthroughs by partner companies.

The new scientific understanding generated by the research will allow us to create innovative and disruptive technologies: we are focused on maximizing the impact of this research and technology development to the greatest benefit of our society. The deliverables of our research programme address many of the major challenges facing us today and we will, in collaboration with the Centre for Doctoral Training in DST, promote the impact of DST research (and STEM in general) via a number of outreach activities. We will actively embrace, at all levels, equality, diversity and inclusion.

Publications

10 25 50
 
Description Relevant examples of project benefits realisation include:
Ozone, dissolved in water, has applications including sterilisation and sanitisation, deodorisation, and decolourisation. Significantly enhanced ozone production using boron doped diamond (BDD) electrodes has been achieved via sp2 carbon content optimization on the electrode surface using laser micromachining. The technology developed has resulted in the supply of specifically optimised electrodes to companies specialising in electrochemically generated ozone for sanitisation applications, in semiconductors, healthcare, sanitaryware and "clean in place" technology providers.
Destroying and eliminating PFAS from water is an important global challenge. PFAS are synthetic fluorinated organic compounds, widely used in industry and consumer products, which do not naturally break down in the environment and cause serious health problems. Our PP research has developed a flow through reactor specifically for PFAS research and it has been used to show BDD electrodes break the C-F bond in short chain PFAS. This new capability in PFAS destruction has underpinned a new UoW (University of Warwick) collaboration with Severn Trent.

The reproducible and cost-effective production of thin (< few ?m) large area (> 20 mm2) diamond membranes are vital for a range of photonic and quantum technologies. A patent has been filed, building on our existing technology (WO2021176015A1) for an improved process for producing thin diamond membranes which is faster and more consistent than existing approaches. Electron-beam transparent BDD membranes (<100 nm thick) have also been shown to be invaluable for studies combining electrochemistry and transmission electron microscopy.

A broadband RF sensor was built using nitrogen-vacancy defects in diamond to demonstrate the potential of this quantum technology. The demonstrator was exhibited at the 2023 UK National Quantum Technologies Showcase.

Prof Gavin Morley and Stuart Graham (UoW PhD student) have secured £35k from the Innovate UK ICURe Explore program to investigate the potential for commercial application of diamond magnetometers for fusion power, cancer diagnostics, navigation and space missions. Additional funding for this research work has been secured from the UK Space Agency, ESA and STFC. UoW and E6 are partners in the UKRI Quantum Biomedical Sensing Research Hub. UoW is receiving funding for development of diamond nanopores with embedded quantum sensors for disease diagnosis (requires diamond membranes perfected in this project) and fabrication of nanodiamonds containing nitrogen-vacancy defects with optimised properties for sensing.
Exploitation Route New collaborations with partners to exploit technology are ongoing
Sectors Agriculture

Food and Drink

Chemicals

Environment

Healthcare

 
Description Transfer of Diamond Membrane Lift-Off Technology from UW to E6: Single crystal diamond membranes that have a thickness in the sub-micron range are of extreme importance in many applications e.g., as a materials platform for photonics, quantum sensing, N/MEMS etc. A time efficient electrochemical method of lifting off thin diamond films was developed by UW. Significantly higher throughput diamond membrane production is possible with this method.
First Year Of Impact 2022
Sector Manufacturing, including Industrial Biotechology,Other
Impact Types Economic

 
Description Development of boron doped diamond based transcutaneous blood gas sensors for improved patient ventilation status monitoring and control, Julie Macpherson, Tania Reed, Medical Research Council Translational Funding
Amount £379,901 (GBP)
Organisation Medical Research Council (MRC) 
Sector Public
Country United Kingdom
Start 09/2022 
End 09/2024
 
Description EPSRC Impact Acceleration Account University of Warwick
Amount £36,569 (GBP)
Organisation University of Warwick 
Sector Academic/University
Country United Kingdom
Start 01/2022 
End 06/2022
 
Description Destroying and eliminating PFAS from water 
Organisation Severn Trent Water
Country United Kingdom 
Sector Private 
PI Contribution Destroying and eliminating PFAS (synthetic fluorinated organic compounds, widely used in industry and consumer products, which do not naturally break down in the environment and cause serious health problems) from water is an important global challenge. PFAS are synthetic fluorinated organic compounds, widely used in industry and consumer products, which do not naturally break down in the environment and cause serious health problems. Our PP research has developed a flow through reactor specifically for PFAS research and it has been used to show BDD electrodes break the C-F bond in short chain PFAS. This new capability in PFAS destruction has underpinned a new UoW (University of Warwick) collaboration with Severn Trent.
Collaborator Contribution Research collaboration that benefits from real world data supplied by partner.
Impact Element Six boron doped diamond pilot scale reactor installed at Severn Trent's £100M new Witches Oak drinking water abstraction plant on the River Trent, UK to destroy PFAS waste streams that have been remediated from contaminated river water.
Start Year 2024
 
Description Element Six - Warwick Prosperity Partnership 
Organisation De Beers Group
Department Element Six
Country Luxembourg 
Sector Private 
PI Contribution The programme of research and collaboration is split into three workpackages (WPs). WP1 focusses on the synthesis, characterisation, and exploitation of perfect diamond in which the maximum exploitable properties are unleashed because deleterious impurities and defects which cause problematic strain are removed. Larger-area single crystal CVD diamond will be grown since diamond's immense potential is limited in many application areas by the small sizes currently available. Functionalised diamond will also be produced where the useful defects have been controllably introduced. WP2 concentrates on the development of processing, functionalisation, and integration technologies for diamond. Growing the diamond is not enough: we have to develop the tool kit that enables processing of diamond into the desired geometrical structure, integration with other materials and suitable packaging that in no way limits performance advantages. WP3 addresses the challenge of quality assurance such that end users know that the packaged material properties meet their requirements, and that the material can be reproducibly produced at a reasonable cost. Also, in WP3 we will produce proof of concept devices that show the potential and seed new product development. The project outcomes will include new materials with improved and tailored properties, new science enabled by enhanced intrinsic properties and the ability to manufacture innovative diamond devices. The significant impacts of the work will be in the new materials and processes demonstrated, increased confidence in others to exploit diamond because we have established a complete diamond supply chain (from production of the material to integration in devices, whilst still retaining the required properties) and the commercialisation of the breakthroughs by partner companies.
Collaborator Contribution This Prosperity Partnership between Element Six (E6) and the University of Warwick (UW) seeks to develop the next generation of technologies that are enabled through exploitation of the amazing combination of extraordinary properties that diamond offers. World-leading UK research in Diamond Science and Technology (DST), spearheaded by E6 and UW, has reached a pivotal point. The exciting potential of diamond in many areas has been established and the path to exploitation signposted. Improved perfection and single-crystal size of synthesised diamond materials will enable new science and together with new approaches to processing, functionalisation and integration, will ensure that impactful and innovative technologies emerge. E6 contributes expertise in diamond synthesis, materials processing and packaging and market/exploitation knowldge.
Impact New outputs include publications, patents and demonstrator devices (e.g. diamond electors and micro-electrochemical reactors, quantum diamond microwave/radiofrequency analysers). Multi-disciplinary: Materials, quantum technologies, electrochemistry, optics.
Start Year 2021
 
Title DIAMOND ELECTRODE WITH ABLATED SURFACE 
Description An electrode and a method of forming an electrode, the electrode being formed from boron doped diamond, the electrode having a total solution accessible electrode area that went through an ablative surface modification process and comprises at least 60% diamond stabilised non-diamond carbon. There is also disclosed an electrochemical cell the electrode. 
IP Reference WO2023025444 
Protection Patent / Patent application
Year Protection Granted 2023
Licensed No
 
Description 2022 National Quantum Technologies Showcase 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact Diamond based broadband radio and microwave frequency technology demonstrator: A diamond-based, broadband radio- and microwave-frequency demonstrator has been developed within the Prosperity Partnership. This device was demonstrated at the 2022 National Quantum Technologies Showcase where it was presented by Ben Green (UW), Matthew Markham (E6) and Raj Patel (formerly UW and now E6). Significant interest was shown particularly from members of the UK defence community. Follow-up meetings are being scheduled at interested parties' premises. A whitepaper (and subsequent academic paper) on the theoretical limits of such a device is forthcoming.
Year(s) Of Engagement Activity 2022
URL https://iuk.ktn-uk.org/events/uk-national-quantum-technologies-showcase-2022/
 
Description Participation in 2023 UK National Quantum Technologies Showcase 
Form Of Engagement Activity Participation in an activity, workshop or similar
Part Of Official Scheme? No
Geographic Reach National
Primary Audience Industry/Business
Results and Impact A broadband RF sensor was built using nitrogen-vacancy defects in diamond to demonstrate the potential of this quantum technology. The demonstrator was exhibited at the 2023 UK National Quantum Technologies Showcase.
Year(s) Of Engagement Activity 2023